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METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE structure

CAS No.: 78471-43-9

Chemical Name:: METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE

Synonyms: 4-BroMo-2-broMoMethyl-benzoic acid Methyl ester;4-bromo-2-bromethyl benzoate;Methyl 2-bromomethyl-4-bromobenzoate;METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE;Methyl4-bromo-2-(bromomethyl)benzoate,96%;1-(4-BROMO-2-(BROMOMETHYL)PHENYL)ETHANONE;Benzoic acid, 4-broMo-2-(broMoMethyl)-, Methyl ester

CBNumber:: CB3276633

Molecular Formula:: C9H8Br2O2

Molecular Weight:: 307.97

MDL Number:: MFCD04114319

MOL File:: 78471-43-9.mol

Last updated:2025-09-25 17:15:13

Product description	Number	Pack Size	Price
Methyl 4-Bromo-2-(bromomethyl)benzoate >97.0%(GC)	M2941	200mg	$41
Methyl 4-Bromo-2-(bromomethyl)benzoate >97.0%(GC)	M2941	1g	$155
Methyl 4-Bromo-2-(bromomethyl)benzoate	M295948	500mg	$70
Methyl 4-Bromo-2-(bromomethyl)benzoate	M295948	250mg	$45
Methyl 4-Bromo-2-(bromomethyl)benzoate	OR400314	1g	$53
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METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE Properties

Melting point	76-78℃
Boiling point	364.3±32.0 °C(Predicted)
Density	1.780±0.06 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	powder to crystal
color	White to Light yellow to Light orange
Water Solubility	Slightly soluble in water.
InChI	InChI=1S/C9H8Br2O2/c1-13-9(12)8-3-2-7(11)4-6(8)5-10/h2-4H,5H2,1H3
InChIKey	SGFACFBLUAWICV-UHFFFAOYSA-N
SMILES	C(OC)(=O)C1=CC=C(Br)C=C1CBr

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H335-H315-H319

Precautionary statements

P261-P271-P280

RIDADR

UN 3261 8/PG III

HazardClass

PackingGroup

III

HS Code

2916310090

Limited Quantities

1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

NFPA 704

	1
0		0

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE price More Price(41)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	M2941	Methyl 4-Bromo-2-(bromomethyl)benzoate >97.0%(GC)	78471-43-9	200mg	$41	2025-07-31	Buy
TCI Chemical	M2941	Methyl 4-Bromo-2-(bromomethyl)benzoate >97.0%(GC)	78471-43-9	1g	$155	2025-07-31	Buy
TRC	M295948	Methyl 4-Bromo-2-(bromomethyl)benzoate	78471-43-9	500mg	$70	2021-12-16	Buy
TRC	M295948	Methyl 4-Bromo-2-(bromomethyl)benzoate	78471-43-9	250mg	$45	2021-12-16	Buy
Apolloscientific	OR400314	Methyl 4-Bromo-2-(bromomethyl)benzoate	78471-43-9	1g	$53	2021-12-16	Buy

Product number	Packaging	Price	Buy
M2941	200mg	$41	Buy
M2941	1g	$155	Buy
M295948	500mg	$70	Buy
M295948	250mg	$45	Buy
OR400314	1g	$53	Buy

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE Chemical Properties,Uses,Production

Uses

Methyl 4-bromo-2-(bromomethyl)benzoate is used as pharmaceutical intermediate.

Synthesis

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

99548-55-7

78471-43-9

General procedure for the synthesis of methyl 4-bromo-2-bromomethylbenzoate from methyl 4-bromo-2-methylbenzoate: a mixture of methyl 4-bromo-2-methylbenzoate (1 g, 4.4 mmol), N-bromosuccinimide (NBS, 0.80 g, 4.4 mmol), benzoyl peroxide (BPO, 56 mg, 0.23 mmol) and carbon tetrachloride (CCl4 , 20 mL) mixture was stirred and reacted at 85°C for 2 hours. Upon completion of the reaction, the mixture was filtered through a silica gel pad and the filtrate was subsequently concentrated to afford the target product methyl 4-bromo-2-bromomethylbenzoate (1.3 g, 97% yield).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2015, vol. 25, # 6, p. 1324 - 1328
[2] Patent: WO2018/68017, 2018, A1. Location in patent: Page/Page column 126
[3] Patent: WO2007/339, 2007, A1. Location in patent: Page/Page column 35-36
[4] Patent: US2010/222363, 2010, A1. Location in patent: Page/Page column 13
[5] Patent: WO2007/337, 2007, A1. Location in patent: Page/Page column 30

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE synthesis

Synthesis of METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE from BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE Preparation Products And Raw materials

Raw materials

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Carbon tetrachloride 4-Bromo-2-methylbenzoic acid Benzoyl peroxide Tungsten

N-Bromosuccinimide

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Preparation Products

2,6-Piperidinedione, 3-[5-(aminomethyl)-1,3-dihydro-1-oxo-2H-isoindol-2-yl]- 5-Bromo-2-ethylisoindolin-1-one 5-Bromo-2-(2-methoxy-ethyl)-2,3-dihydro-isoindol-1-one 5-BROMO-2,3-DIHYDRO-ISOINDOL-1-ONE

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE Suppliers

Global( 246)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29735	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10405	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29795	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Changzhou Ansciep Chemical Co., Ltd.	58
Shenzhen Nexconn Pharmatechs Ltd	58
Jinan Carbotang Biotech Co.,Ltd.	58
Accela ChemBio Inc.	58
Alchem Pharmtech,Inc.	58
career henan chemical co	58
Jinan Liheng Biotechnology Co., Ltd.	58
Fuxin Pharmaceutical	58

View Lastest Price from METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-04-04	METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE 78471-43-9	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.
2022-01-04	Methyl 2-bromomethyl-4-bromobenzoate 78471-43-9	US $0.00-0.00 / KG	1g	98%min	500kgs/month	Shanghai Rlavie Technology Co ltd
2020-01-09	METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE 78471-43-9	US $1.00 / KG	1KG	99%	10000KGS	Career Henan Chemical Co

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE
78471-43-9
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

Methyl 2-bromomethyl-4-bromobenzoate
78471-43-9
US $0.00-0.00 / KG
98%min
Shanghai Rlavie Technology Co ltd

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE
78471-43-9
US $1.00 / KG
99%
Career Henan Chemical Co

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE Spectrum

METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE(78471-43-9)¹HNMR METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE(78471-43-9)FT-IR

78471-43-9(METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE)Related Search:

METHYL 4-CHLORO-3-METHYLBENZOATE METHYL 4-[(4-METHYLPIPERAZIN-1-YL)METHYL]BENZOATE METHYL 4-(TRIFLUOROMETHYL)NICOTINATE METHYL 4-AMINO-6-INDOLECARBOXYLATE 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER 2-(Bromomethyl)benzoic acid METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE Methyl 2-bromomethylbenzoate

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METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE Benzoic acid, 4-broMo-2-(broMoMethyl)-, Methyl ester Methyl 2-bromomethyl-4-bromobenzoate 1-(4-BROMO-2-(BROMOMETHYL)PHENYL)ETHANONE 4-BroMo-2-broMoMethyl-benzoic acid Methyl ester Methyl4-bromo-2-(bromomethyl)benzoate,96% 4-bromo-2-bromethyl benzoate 78471-43-9