2,2-Bis(4-hydroxy-3-methylphenyl)propane
- CAS No.
- 79-97-0
- Chemical Name:
- 2,2-Bis(4-hydroxy-3-methylphenyl)propane
- Synonyms
- nonoxdcp;Nonox DCP;Bisphenlo c;Bis-o-cresol A;Dicresylolpropane;3,3’-dimethyldian;3,3'-Dimethyldian;Bisphenol C Solution;3,3’-dimethylbisphenola;3,3'-Dimethylbisphenol A
- CBNumber:
- CB3282153
- Molecular Formula:
- C17H20O2
- Molecular Weight:
- 256.34
- MDL Number:
- MFCD00002232
- MOL File:
- 79-97-0.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2,2-Bis(4-hydroxy-3-methylphenyl)propane 97% | B45712 | 25g | $147 |
| Bisphenol C analytical standard | 68118 | 100mg | $62.8 |
| 2,2-Bis(4-hydroxy-3-methylphenyl)propane >98.0%(GC) | B1567 | 25g | $38 |
| 2,2-Bis(4-hydroxy-3-methylphenyl)propane >98.0%(GC) | B1567 | 100g | $100 |
| 2,2-Bis(4-hydroxy-3-methylphenyl)propane >98.0%(GC) | B1567 | 500g | $325 |
| More product size | |||
| Melting point | 138-140 °C(lit.) |
|---|---|
| Boiling point | 238-240 °C12 mm Hg(lit.) |
| Density | 1.0421 (rough estimate) |
| vapor pressure | 0Pa at 25℃ |
| refractive index | 1.5000 (estimate) |
| solubility | almost transparency in Methanol |
| pka | 10.45±0.10(Predicted) |
| form | solid |
| form | solid |
| color | White to Almost white |
| Water Solubility | 22mg/L at 20℃ |
| Stability | Hygroscopic |
| InChI | 1S/C17H20O2/c1-11-9-13(5-7-15(11)18)17(3,4)14-6-8-16(19)12(2)10-14/h5-10,18-19H,1-4H3 |
| InChIKey | YMTYZTXUZLQUSF-UHFFFAOYSA-N |
| SMILES | Cc1cc(ccc1O)C(C)(C)c2ccc(O)c(C)c2 |
| LogP | 4.11 at 20℃ |
| CAS DataBase Reference | 79-97-0(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 98817I7XJ2 |
| NIST Chemistry Reference | Phenol, 4,4'-(1-methylethylidene)bis[2-methyl-(79-97-0) |
| EPA Substance Registry System | Phenol, 4,4'-(1-methylethylidene)bis[2-methyl- (79-97-0) |
| UNSPSC Code | 85151701 |
| NACRES | NA.24 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | GP1750000 | |||||||||
| TSCA | TSCA listed | |||||||||
| HS Code | 29072990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| Hazardous Substances Data | 79-97-0(Hazardous Substances Data) | |||||||||
| NFPA 704 |
|
2,2-Bis(4-hydroxy-3-methylphenyl)propane price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | B45712 | 2,2-Bis(4-hydroxy-3-methylphenyl)propane 97% | 79-97-0 | 25g | $147 | 2025-07-31 | Buy |
| Sigma-Aldrich | 68118 | Bisphenol C analytical standard | 79-97-0 | 100mg | $62.8 | 2022-05-15 | Buy |
| TCI Chemical | B1567 | 2,2-Bis(4-hydroxy-3-methylphenyl)propane >98.0%(GC) | 79-97-0 | 25g | $38 | 2025-07-31 | Buy |
| TCI Chemical | B1567 | 2,2-Bis(4-hydroxy-3-methylphenyl)propane >98.0%(GC) | 79-97-0 | 100g | $100 | 2025-07-31 | Buy |
| TCI Chemical | B1567 | 2,2-Bis(4-hydroxy-3-methylphenyl)propane >98.0%(GC) | 79-97-0 | 500g | $325 | 2025-07-31 | Buy |
2,2-Bis(4-hydroxy-3-methylphenyl)propane Chemical Properties,Uses,Production
Description
2,2-Bis(4-hydroxy-3-methylphenyl)propane is a monomer of polycarbonate and bisphenol A. It has been used as a reaction solution for sodium salt and calcium stearate. The product contains hydrogen chloride and hydrochloric acid as byproducts. This product also reacts with fatty acids to produce aromatic hydrocarbons.
Chemical Properties
Powder or crystalline or crystalline powder or chunks
Uses
Used as a color-developer in thermosensitive recording materials.
Definition
ChEBI: 3,3'-Dimethylbisphenol A is a bisphenol.
Preparation
The preparation of 2,2-Bis(4-hydroxy-3-methylphenyl)propane is as follows:In a full-jacket type 1 L separable flask equipped with a thermometer, a stirrer, and a 100 mL dropping funnel, 26.1 g (0.4 mol) of isopropyl alcohol was added under a nitrogen atmosphere, and then 58.3 g (0.5 mol) of 90% by weight sulfuric acid was slowly added thereto. Thereafter, 54.5 g of toluene, 191.5 g (1.8 mol) of ortho-cresol, and 5.5 g (0.03 mol) of dodecanethiol were added thereto, followed by setting the temperature in the separable flask to 40° C. In the dropping funnel, 42.5 g (0.7 mol) of acetone was placed, and it was slowly fed dropwise to the separable flask for 30 minutes. After completion of the dropwise addition of acetone, the reaction was allowed to proceed at 40° C. for 2 hours. After completion of the reaction, 100.0 g of toluene and 100.0 g of demineralized water were fed, and the temperature was increased to 80° C. After the temperature reached 80° C., the reaction liquid was left to stand to confirm that the precipitates generated during the reaction were dissolved into the organic phase and the aqueous phase. This was followed by extraction of the aqueous phase in the lower layer. Thereafter, saturated sodium hydrogen carbonate solution was added to the obtained organic phase to allow neutralization, followed by confirming that the pH of the aqueous phase in the lower layer, became not less than 9. After extraction of the aqueous phase in the lower layer, demineralized water was added to the obtained organic phase, and the resulting mixture was stirred for 10 minutes. Thereafter, the mixture was left to stand, and the aqueous phase was extracted. Part of the obtained organic phase was removed, and subjected to high-performance liquid chromatography to analyze the amount of bisphenol C produced. As a result, the reaction yield in terms of acetone was found to be 84 mol %.
Flammability and Explosibility
Not classified
Synthesis
95-48-7
67-64-1
79-97-0
Under nitrogen protection, 5 g (0.16 mol) of methanol and 191 g (1.77 mol) of o-cresol were added to a detachable flask. 100 g of 80 wt% sulfuric acid was slowly added through a dropping funnel, followed by 50 g (0.86 mol) of acetone, 221 g of toluene, and 7.5 g of dodecyl mercaptan, which was mixed well to form a reaction solution. The same procedure as in Example 1 was followed. A portion of the organic phase was sampled and the amount of 4,4'-(1-methylethylidene)bis(2-methylphenol) (bisphenol C) generated was confirmed by high performance liquid chromatography (HPLC) analysis. The results showed a reaction yield of 85 mol% based on acetone. In addition, the amount of isopropylidene acetone in the reaction solution for bisphenol C formation was analyzed by gas chromatography (GC) based on bisphenol C of 0.02 area%, as well as a residue of dodecyl mercaptan of 44%.
References
[1] Patent: JP2018/145178, 2018, A. Location in patent: Paragraph 0049; 0050; 0051; 0054; 0055; 0058
[2] Patent: JP2018/145177, 2018, A. Location in patent: Paragraph 0051-0052
[3] Journal of the Indian Chemical Society, 1989, vol. 66, # 2, p. 85 - 90
[4] Journal of the Indian Chemical Society, 1989, vol. 66, # 2, p. 85 - 90
[5] Journal of the Indian Chemical Society, 1989, vol. 66, # 2, p. 85 - 90
2,2-Bis(4-hydroxy-3-methylphenyl)propane Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jiangsu Ever Galaxy Chemical Co.,Ltd | +86-0527-81083685; +8618602515822 | info@egchemical.com | China | 78 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 43339 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20129 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13620 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21599 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29795 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23541 | 58 |
View Lastest Price from 2,2-Bis(4-hydroxy-3-methylphenyl)propane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-12-29 | 2,2-Bis(4-hydroxy-3-methylphenyl)propane
79-97-0
|
US $0.00 / kg | 1kg | 99% | According to customer requirements | Changzhou waston chemical technology Co.,Ltd | |
 |
2025-09-25 | 4,4'-Propane-2,2-diylbis(2-methylphenol)
79-97-0
|
US $8.00-0.60 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2025-09-25 | 4,4'-Propane-2,2-diylbis(2-methylphenol)
79-97-0
|
US $8.00-0.60 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
-
- 2,2-Bis(4-hydroxy-3-methylphenyl)propane
79-97-0
- US $0.00 / kg
- 99%
- Changzhou waston chemical technology Co.,Ltd
-
- 4,4'-Propane-2,2-diylbis(2-methylphenol)
79-97-0
- US $8.00-0.60 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 4,4'-Propane-2,2-diylbis(2-methylphenol)
79-97-0
- US $8.00-0.60 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
