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[Ir{dFCF3ppy}2(bpy)]PF6

CAS No.
1092775-62-6
Chemical Name:
[Ir{dFCF3ppy}2(bpy)]PF6
Synonyms
uoro-2-[5-trifL;[Ir{dFCF3ppy}2(bpy)]PF6;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;[Ir{dFCF3ppy}2(bpy)]PF6;2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
CBNumber:
CB33150909
Molecular Formula:
C34H18F16IrN4P
Molecular Weight:
1009.6987322
MDL Number:
MFCD28987331
MOL File:
1092775-62-6.mol
Last updated:2025-09-25 19:16:21
Product description Number Pack Size Price
[Ir{dFCF3ppy}2(bpy)]PF6 804215 50mg $99.4
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate B6161 200MG $170
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate B6161 1G $510
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95% 77-0220 50mg $66
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95% 77-0220 250mg $262

[Ir{dFCF3ppy}2(bpy)]PF6 Properties

storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Powder
color yellow
Sensitive air sensitive
InChIKey ZCNUFCYLERNPGN-UHFFFAOYSA-N
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338

[Ir{dFCF3ppy}2(bpy)]PF6 price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 804215 [Ir{dFCF3ppy}2(bpy)]PF6 1092775-62-6 50mg $99.4 2025-07-31 Buy
TCI Chemical B6161 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate 1092775-62-6 200MG $170 2025-07-31 Buy
TCI Chemical B6161 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate 1092775-62-6 1G $510 2025-07-31 Buy
Strem Chemicals 77-0220 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95% 1092775-62-6 50mg $66 2024-03-01 Buy
Strem Chemicals 77-0220 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95% 1092775-62-6 250mg $262 2024-03-01 Buy
Product number Packaging Price Buy
804215 50mg $99.4 Buy
B6161 200MG $170 Buy
B6161 1G $510 Buy
77-0220 50mg $66 Buy
77-0220 250mg $262 Buy

[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties,Uses,Production

Reaction

  1. Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
  2. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
  3. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
  4. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
  5. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
  6. Photocatalyst used in the cross-coupling of trifluoroalkylboranes.
Reactions of 1092775-62-6_1
Reactions of 1092775-62-6_2

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

[Ir{dFCF3ppy}2(bpy)]PF6 Suppliers

Global( 64)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 13456 58
Career Henan Chemica Co
+86-0371-86658258 +8613203830695 laboratory@coreychem.com China 30229 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 8398 58
Hunan russell chemicals technology co ltd
731-88557738 +8613739093081 sales01@russellchem.com CHINA 291 58
HANGZHOU LEAP CHEM CO., LTD.
+86-571-87711850 market18@leapchem.com China 24727 58
Xian confluore Biological Technology Co., Ltd.
+86-15680926068 1924344760@confluore.cn China 2997 58
Aladdin Scientific
tp@aladdinsci.com United States 57505 58
Wuhan Fortuna Chemical Co.,Ltd
+86-2759207851; +8618007136271 hk@fortunachem.com China 5991 58
Tianjin Kailiqi Biotechnology Co., Ltd. 15076683720 klq@cw-bio.com China 6771 55
Beijing HwrkChemical Technology Co., Ltd 18515581800 18501085097 sales.bj@hwrkchemical.com China 9398 55

View Lastest Price from [Ir{dFCF3ppy}2(bpy)]PF6 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Ir[dFCF3ppy]2(bpy))PF6 pictures 2025-06-07 (Ir[dFCF3ppy]2(bpy))PF6
1092775-62-6
US $0.00 / g 1g >99.00% 1g Xian confluore Biological Technology Co., Ltd.
[Ir{dFCF3ppy}2(bpy)]PF6 Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate (2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE Ir[dF(CF3)2ppy]2(bpy)]PF6 (2,2'-Bipyridine)bis[3,5-difL uoro-2-[5-trifL (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate 2,2'-bipyridine, bis({3,5-difluoro-2-[5-(trifluoromethyl)pyridin-2-yl]phenyl})iridiumylium, hexafluoro-lambda5-phosphanuide 2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine Ir{dFCF3ppy}2(bpy)]PF6,(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate (2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate [Ir{dFCF3ppy}2(bpy)]PF6 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate 1092775-62-6 C34H18F16IrN4P