5-FLUORO-2-MERCAPTOBENZOTHIAZOLE
- CAS No.
- 155559-81-2
- Chemical Name:
- 5-FLUORO-2-MERCAPTOBENZOTHIAZOLE
- Synonyms
- BUTTPARK 74\02-36;5-Fluoro-benzothiazole-2-thiol;5-Fluorobenzo[d]thiazole-2-thiol;5-FLUORO-2-MERCAPTOBENZOTHIAZOLE;2-Mercapto-5-fluorobenzothiazole;5-Fluoro-2(3h)-benzothiazolethione;5-Fluoro-1,3-benzothiazole-2-thiol;2(3H)-Benzothiazolethione, 5-fluoro-;5-fluoro-3H-1,3-benzothiazole-2-thione
- CBNumber:
- CB3349856
- Molecular Formula:
- C7H4FNS2
- Molecular Weight:
- 185.24
- MDL Number:
- MFCD02181177
- MOL File:
- Mol file
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 5-Fluoro-2-mercaptobenzothiazole | TRC-F597005-250MG | 250mg | $72 |
| 5-Fluoro-2-mercaptobenzothiazole 98% | PC9090 | 1g | $101 |
| 5-Fluoro-2-mercaptobenzothiazole 98% | PC9090 | 1g | $101 |
| 5-Fluorobenzo[d]thiazole-2-thiol 98% | F44439 | 100mg | $39 |
| 5-Fluorobenzo[d]thiazole-2-thiol 98% | F44439 | 250mg | $43 |
| More product size | |||
| Melting point | 189-191 °C(Solv: chloroform (67-66-3); ligroine (8032-32-4)) |
|---|---|
| Boiling point | 295.7±42.0 °C(Predicted) |
| Density | 1.55±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | DMSO (Slightly), Ethyl Acetate (Slightly) |
| form | Solid |
| pka | 8.96±0.20(Predicted) |
| color | Pale Brown to Light Brown |
| Sensitive | Stench |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| Hazard Codes | Xi |
| Hazard Note | Irritant/Stench |
| HS Code | 2934208090 |
5-FLUORO-2-MERCAPTOBENZOTHIAZOLE price More Price(42)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | TRC-F597005-250MG | 5-Fluoro-2-mercaptobenzothiazole | 155559-81-2 | 250mg | $72 | 2026-06-03 | Buy |
| Apolloscientific | PC9090 | 5-Fluoro-2-mercaptobenzothiazole 98% | 155559-81-2 | 1g | $101 | 2026-06-04 | Buy |
| Apolloscientific | PC9090 | 5-Fluoro-2-mercaptobenzothiazole 98% | 155559-81-2 | 1g | $101 | 2026-06-04 | Buy |
| Synthonix | F44439 | 5-Fluorobenzo[d]thiazole-2-thiol 98% | 155559-81-2 | 100mg | $39 | 2026-05-06 | Buy |
| Synthonix | F44439 | 5-Fluorobenzo[d]thiazole-2-thiol 98% | 155559-81-2 | 250mg | $43 | 2026-05-06 | Buy |
5-FLUORO-2-MERCAPTOBENZOTHIAZOLE Chemical Properties,Uses,Production
Chemical Properties
Gray solid
Uses
5-Fluoro-2-mercaptobenzothiazole is used as a reagent in the synthesis of [[(benzothiazolyl)thio]methyl]phenyl]furanone derivatives with agrochemical fungicidal activities.
Synthesis
367-30-6
140-89-6
155559-81-2
Step 1) Synthesis of 5-fluorobenzo[d]thiazole-2-thiol: 2,5-difluoroaniline (1.00 g, 7.75 mmol) and potassium ethylxanthate (2.73 g, 17.05 mmol) were dissolved in N,N-dimethylformamide (50 mL). The reaction mixture was heated to 120 °C for 10 hours. After completion of the reaction, the mixture was cooled to room temperature and diluted with deionized water (100 mL). The pH of the mixture was adjusted to 4-5 with 1 M hydrochloric acid, at which point a solid precipitated. The solid was collected by diafiltration and dried at 50 °C. Ultimately, 5-fluoro-2-mercaptobenzothiazole was obtained as a white solid (1.11 g, 76.5% yield) under vacuum. Mass spectrum (ESI, cation mode) m/z: 185.00 [M + H]+; 1H NMR (DMSO-d6, 600 MHz) δ (ppm): 13.98 (s, 1H), 7.55 (d, J = 8.2 Hz, 1H), 7.36-7.31 (m, 2H).
References
[1] Synthetic Communications, 2007, vol. 37, # 3, p. 369 - 376
[2] Patent: WO2017/88759, 2017, A1. Location in patent: Paragraph 00232
[3] Patent: WO2011/143366, 2011, A1. Location in patent: Page/Page column 57
[4] Bioorganic and Medicinal Chemistry, 2015, vol. 23, # 24, p. 7661 - 7670
5-FLUORO-2-MERCAPTOBENZOTHIAZOLE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | 52513593@qq.com | CHINA | 2972 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| CR Corporation Limited | +8613062833949 | fred.wen@crcorporation.cn | China | 8645 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 43333 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52923 | 58 | |
| Allfluoro pharmaceutical co. ltd. | +86-400-0216110 +86-15958047586 | sales@allfluoro.com | China | 11385 | 58 |
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53803 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44802 | 61 |
View Lastest Price from 5-FLUORO-2-MERCAPTOBENZOTHIAZOLE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-01-15 | 5-fluoro-2-mercaptobenzothiazole
155559-81-2
|
1KG | 98.1% | 100 tons | Honest Joy Holdings Limited | ||
 |
2020-01-13 | 5-FLUORO-2-MERCAPTOBENZOTHIAZOLE
155559-81-2
|
$1.00 | 1g | 99% | 10000KGS | Career Henan Chemical Co |
-
- 5-fluoro-2-mercaptobenzothiazole
155559-81-2
- $0.00
- 98.1%
- Honest Joy Holdings Limited
-
- 5-FLUORO-2-MERCAPTOBENZOTHIAZOLE
155559-81-2
- $1.00
- 99%
- Career Henan Chemical Co
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