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Bromoxynil

CAS No.
1689-84-5
Chemical Name:
Bromoxynil
Synonyms
3,5-DIBROMO-4-HYDROXYBENZONITRILE;Torch;s2132;Bucril;terset;EMBLEM;KALEIS;BROMOX;toplan;Brittox
CBNumber:
CB3351156
Molecular Formula:
C7H3Br2NO
Molecular Weight:
276.91
MDL Number:
MFCD00002153
MOL File:
1689-84-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-10 10:27:12
Product description Number Pack Size Price
Bromoxynil certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland CRM45355 50 mg $87.8
Bromoxynil PESTANAL 45355 250mg $36.4
Bromoxynil certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland CRM45355 1 unit $81.9
Bromoxynil min. 98.0 % D4103 5G $76
Bromoxynil min. 98.0 % D4103 25G $246
More product size

Bromoxynil Properties

Melting point 189-191 °C(lit.)
Boiling point 265.6±40.0 °C(Predicted)
Density 2.0926 (rough estimate)
refractive index 1.6400 (estimate)
storage temp. 0-6°C
solubility DMSO (Slightly), Methanol (Slightly)
form Solid
pka 4.06(at 25℃)
color Buff, Creamy
Water Solubility 0.13 G/L (25 ºC)
Merck 13,1426
BRN 2364039
Henry's Law Constant 7.4×102 mol/(m3Pa) at 25℃, Mackay et al. (2006)
Major Application agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care
InChI 1S/C7H3Br2NO/c8-5-1-4(3-10)2-6(9)7(5)11/h1-2,11H
InChIKey UPMXNNIRAGDFEH-UHFFFAOYSA-N
SMILES Oc1c(Br)cc(cc1Br)C#N
CAS DataBase Reference 1689-84-5(CAS DataBase Reference)
FDA UNII J46EK95K0P
NIST Chemistry Reference Benzonitrile, 3,5-dibromo-4-hydroxy-(1689-84-5)
Pesticides Freedom of Information Act (FOIA) Bromoxynil phenol
EPA Substance Registry System Bromoxynil (1689-84-5)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H317-H330-H361d-H410
Precautionary statements  P202-P260-P273-P280-P302+P352-P304+P340+P310
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes  T+,N
Risk Statements  25-26-43-50/53-63
Safety Statements  27/28-36/37-45-60-61-63-28A-28-27
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
RTECS  DI3150000
HazardClass  6.1(b)
PackingGroup  III
Storage Class 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 1 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Repr. 2
Skin Sens. 1
Hazardous Substances Data 1689-84-5(Hazardous Substances Data)
Toxicity LD50 orally in mice: 111 mg/kg (Carpenter, 1964)
NFPA 704
1
3 0

Bromoxynil price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich CRM45355 Bromoxynil certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland 1689-84-5 50 mg $87.8 2026-03-19 Buy
Sigma-Aldrich 45355 Bromoxynil PESTANAL 1689-84-5 250mg $36.4 2026-03-19 Buy
Sigma-Aldrich CRM45355 Bromoxynil certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland 1689-84-5 1 unit $81.9 2025-07-31 Buy
TCI Chemical D4103 Bromoxynil min. 98.0 % 1689-84-5 5G $76 2026-03-19 Buy
TCI Chemical D4103 Bromoxynil min. 98.0 % 1689-84-5 25G $246 2026-03-19 Buy
Product number Packaging Price Buy
CRM45355 50 mg $87.8 Buy
45355 250mg $36.4 Buy
CRM45355 1 unit $81.9 Buy
D4103 5G $76 Buy
D4103 25G $246 Buy

Bromoxynil Chemical Properties,Uses,Production

Chemical Properties

Off-white to salmon crystalline powder

Chemical Properties

Bromoxynil is a colorless to white crystalline solid or tan powder. Odorless (pure).

Uses

Bromoxynil is a nitrile herbicide. Bromoxynil is effective in post-emergent control of broad leaf weeds in cereal, corn, sorghum, onions, flax, mint, turf, and on non-cropland.

Uses

Selective contact foliage-applied herbicide used to control many broad-leaved weeds in cereals.

Definition

ChEBI: A dibromobenzene that is 2,6-dibromophenol substituted by a cyano group at position 4.

General Description

Colorless solid. Melting point 382-384°F (194-195°C). Sublimes at 275°F (135°C) under pressure of 0.15 mm Hg. Used as a herbicide.

Reactivity Profile

Bromoxynil is a weak acid.

Hazard

Toxic.

Agricultural Uses

Herbicide: A U.S. EPA restricted Use Pesticide (RUP). For post-emergent control of broadleaf weeds. Used on alfalfa, garlic, corn, sorghum, flax, cereals, turf and on pasture and rangelands.

Trade name

BRIOTRIL®; BRUCIL®; BRITTOX®; BROMINAL®; BROMINEX®; BROMINAL®; BROMINAL ME-4®; BROMINIL®; BROMILIL PLUS®; Bromox 2E; BROMOTRIL®; BROMOXYNIL NITRILE HERBICIDE®; BRONATE®; BROXYNIL®; BUCTRIL® Bromoxynil; BUCTRIL® GEL HERBICIDE (octanoate); BUCTRIL® 4EC GEL (mixture of bromoxynil octanoate + bromoxynil heptanoate); BUCTRIL INDUSTRIAL®; CHIPCO BUCTRIL®; CHIPCO CRAB-KLEEN®; FLAGON®, 400 EC; HOBANE®; LABUCTRIL®; LITAROL®; M&B 10064®; MB 10064®; MB 10731® (octanoate); M&B 10731®; ME4 BROMINAL®; MERIT®; MEXTROL-BIOX®; MOXY 2E®; NCR CE EE DOV7® (octanoate); NU-LAWN WEEDER®; OXYTRIL M®; PARDNER®; SABRE®; TORCH®

Potential Exposure

Bromoxynil is a hydroxybenzonitrile herbicide used for postemergent control of broadleaf weeds; on alfalfa, garlic, corn, sorghum, flax, cereals, turf and on pasture and rangelands. A United States Environmental Protection Agency RUP.

Environmental Fate

Biological. Duke et al. (1991) reported that bromoxynil can be converted to 3,5- dibromo-4-hydroxybenzoic acid by a microbial nitrolase.
Soil. In soils, Klebsiella pneumoniae metabolized bromoxynil to 3,5-dibromo-4- hydroxybenzoic acid and ammonia (McBride et al., 1986). In soil, bromoxynil undergoes nitrile and then amide hydrolysis yielding 3,5-dibromo-4-hydroxybenzoic acid and
Nitrification in soils is inhibited when bromacil is applied at a concentration of <50 ppm (Debona and Audus, 1970). The half-life in soil is approximately 10 days (Hartley and Kidd, 1987).
Plant. In plants, the cyano group is hydrolyzed to an amido group which is subsequently oxidized to a carboxylic acid. Hydrolyzes to hydroxybenzoic acid (Hartley and Kidd, 1987). In plants, bromoxynil may hydrolyze to a benzoic acid (Humburg et al., 1989). Bromoxynil-resistant cotton was recently developed by inserting a bxn gene cloned from the soil bacterium Klebsiella ozaenae. This gene, which encodes a specific nitrolase, converted bromoxynil to its primary metabolite 3,5-dibromo-4-hydroxybenzoic acid (Stalker et al., 1988).
Chemical/Physical. Emits toxic fumes of nitrogen oxides and bromine when heated to decomposition (Sax and Lewis, 1987). Reacts with bases forming water-soluble salts (Worthing and Hance, 1991). Bromacil is stable to UV light (Hartley and Kidd, 19

Shipping

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.

Incompatibilities

A weak acid; keep away from bases and alkalies. React with boranes, alkalies, aliphatic amines, amides, nitric acid, sulfuric acid. Keep away from oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.) and strong acids.

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Incineration with effluent gas scrubbing is recommended. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. If allowed, Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

767-00-0
1689-84-5
Synthesis of Bromoxynil from 4-Cyanophenol
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View Lastest Price from Bromoxynil manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bromoxynil pictures 2019-07-06 Bromoxynil
1689-84-5
US $1.00 / kg 1kg 99% Customized Career Henan Chemical Co
  • Bromoxynil pictures
  • Bromoxynil
    1689-84-5
  • US $1.00 / kg
  • 99%
  • Career Henan Chemical Co
4-HYDROXY-3,5-DIBROMOBENZONITRILE 3,5-DIBROMO-4-HYDROXYBENZONITRILE 3,5-DIBROMO-4-HYDROXYPHENYL CYANIDE 3,5-dibromo-4-hydroxy-benzonitril 3,5-dibromo-4-hydroxybenzonitril(acn) 4-Cyano-2,6-dibromophenol Brittox brominalindustrial brominalm brominalplus brominaltriple Brominex Brominil bromoxynil(acn) bromoxynilphenol bronate Broxynil Bucril Buctril industrial buctrilindustrial buctrilm Butilchlorofos butilchorofos Certrol B certrolb Chipco buctril Chipco crab-kleen chipcobuctril chipcocrab-kleen chiprobuctril crusaders ENT 20852 ent20852 Labuctril Labuctril 25 labuctril25 Litarol litarolm M&B 10731 m&b10731 ME4 BROMINAL me4brominal novacorn Nu-lawn weeder nu-lawnweeder Oxytril M oxytrilm Pardner s2132 terset 3,5-DibroMo-4-hydroxybenzonitrile, 95+% 2,6-Dibromo-4-cyanophenol Bormoxynil Bromoxynil Solution, 1000ppm MB 10064 EMBLEM KALEIS BUCTRIL