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3-Nitrobenzyl bromide

3-Nitrobenzyl bromide structure

CAS No.: 3958-57-4

Chemical Name:: 3-Nitrobenzyl bromide

Synonyms: 1-(Bromomethyl)-3-nitrobenzene;NSC 66499;3-Nitrobromobenzyl;3-Nitrobenzyl bromid;M-NITROBENZYL BROMIDE;3-NITROBENZYL BROMIDE;α-Bromo-3-nitrotoluene;A-BROMO-M-NITROTOLUENE;a-Bromo-3-nitrotoluene;à-bromo-3-nitrotoluene

CBNumber:: CB3402571

Molecular Formula:: C7H6BrNO2

Molecular Weight:: 216.03

MDL Number:: MFCD00007271

MOL File:: 3958-57-4.mol

MSDS File:: SDS

Last updated:2026-01-13 11:19:19

Product description	Number	Pack Size	Price
3-Nitrobenzyl bromide 98%	222518	5g	$45.9
3-Nitrobenzyl Bromide >98.0%(GC)	N0625	10g	$17
3-Nitrobenzyl Bromide >98.0%(GC)	N0625	25g	$24
1-(Bromomethyl)-3-nitrobenzene 98%	B45333	1g	$25
1-(Bromomethyl)-3-nitrobenzene 98%	B45333	5g	$40
More product size

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3-Nitrobenzyl bromide Properties

Melting point	58-59 °C(lit.)
Boiling point	153-154 °C (7 mmHg)
Density	1.6841 (rough estimate)
refractive index	1.6120 (estimate)
Flash point	153-154°C/7mm
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
solubility	Dichloromethane, Hot Ethanol
form	Crystalline Powder or Crystals
color	Yellow to light brown
Water Solubility	insoluble
BRN	742795
InChI	1S/C7H6BrNO2/c8-5-6-2-1-3-7(4-6)9(10)11/h1-4H,5H2
InChIKey	LNWXALCHPJANMJ-UHFFFAOYSA-N
SMILES	[O-][N+](=O)c1cccc(CBr)c1
CAS DataBase Reference	3958-57-4(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-(bromomethyl)-3-nitro-(3958-57-4)
EPA Substance Registry System	Benzene, 1-(bromomethyl)-3-nitro- (3958-57-4)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H314-H335

Precautionary statements

P260-P271-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338

target organs

Respiratory system

PPE

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Codes

Risk Statements

34-36/37

Safety Statements

26-27-28-36/37/39-45

RIDADR

UN 3261 8/PG 2

WGK Germany

TSCA

TSCA listed

HazardClass

PackingGroup

HS Code

29049090

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Eye Dam. 1
Skin Corr. 1B
STOT SE 3

Limited Quantities

1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

NFPA 704

	1
3		0

3-Nitrobenzyl bromide price More Price(22)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	222518	3-Nitrobenzyl bromide 98%	3958-57-4	5g	$45.9	2026-04-30	Buy
TCI Chemical	N0625	3-Nitrobenzyl Bromide >98.0%(GC)	3958-57-4	10g	$17	2026-04-30	Buy
TCI Chemical	N0625	3-Nitrobenzyl Bromide >98.0%(GC)	3958-57-4	25g	$24	2026-04-30	Buy
Synthonix	B45333	1-(Bromomethyl)-3-nitrobenzene 98%	3958-57-4	1g	$25	2026-05-06	Buy
Synthonix	B45333	1-(Bromomethyl)-3-nitrobenzene 98%	3958-57-4	5g	$40	2026-05-06	Buy

Product number	Packaging	Price	Buy
222518	5g	$45.9	Buy
N0625	10g	$17	Buy
N0625	25g	$24	Buy
B45333	1g	$25	Buy
B45333	5g	$40	Buy

3-Nitrobenzyl bromide Chemical Properties,Uses,Production

Chemical Properties

Pale Yellow Crystalline Solid

Uses

3-Nitrobenzyl bromide was used in the synthesis of 1,4-disubstituted imidazoles.

Synthesis

619-25-0

3958-57-4

General procedure for the synthesis of 3-nitrobenzyl bromide from 3-nitrobenzyl alcohol: Powdered 3-nitrobenzyl alcohol (0.5 mmol) was mixed with halosilanes (0.55 mmol) in a 4 mL screw-capped vial and stirred or heated at room temperature. The reaction mixture was kept at 70-75 °C for 0.5-24 h, during which the reaction progress was monitored by TLC. Upon completion of the reaction, the crude product was cooled to room temperature and the volatile by-product (TMS) was removed by evaporation under reduced pressure (30-35 °C).2O. The residue was confirmed by 1H NMR analysis. If necessary, the pure 3-nitrobenzyl bromide was purified by column chromatography on dry silica to obtain pure 3-nitrobenzyl bromide. Detailed experimental data, including isolated yields, spectral and other characterization data, are given in the Final Product Characterization section of the Supporting Information.

References

[1] Tetrahedron Letters, 2016, vol. 57, # 22, p. 2430 - 2433
[2] Organic Process Research and Development, 2002, vol. 6, # 2, p. 190 - 191
[3] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 1397 - 1405
[4] Patent: WO2014/151871, 2014, A2. Location in patent: Page/Page column 59; 60
[5] Journal of the American Chemical Society, 1949, vol. 71, p. 2137,2138,2140

3-Nitrobenzyl bromide synthesis

Synthesis of 3-Nitrobenzyl bromide from 3-Nitrobenzyl alcohol

3-Nitrobenzyl bromide Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Carbon tetrachloride 3-Nitrotoluene 3-Nitrobenzyl alcohol

Bromotrimethylsilane

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Preparation Products

3-NITROPHENYLACETIC ACID 3-NITROBENZYLAMINE Benzenemethanamine, N-butyl-3-nitro- Methyl 3-nitrophenylacetate 3-AMINO-N,N-DIMETHYLBENZYLAMINE

Benzenemethanamine, N-(1,1-dimethylethyl)-3-nitro- [1-(4-NITRO-BENZYL)-PIPERIDIN-4-YL]-CARBAMIC ACID TERT-BUTYL ESTER 3-(4-fluorophenoxymethyl)aniline 1-[4-[(3-aminophenyl)methyl]-1-piperazinyl]ethanone Ethyl-(3-nitro-benzyl)-aMine

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3-Nitrobenzyl bromide Suppliers

Global( 289)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Xi'an Yutbon Pharmaceutical Technology Co., Ltd	029-81140587 +8618717328141	sales@yutbon.com	China	454	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29816	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10821	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14304	58

Supplier	Advantage
Xi'an Yutbon Pharmaceutical Technology Co., Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Fuxin Pharmaceutical	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Win-Win chemical CO., Limited	58

View Lastest Price from 3-Nitrobenzyl bromide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-04-04	3-Nitrobenzyl bromide 3958-57-4	US $0.00-0.00 / KG	1KG	98%	1ton	Henan Aochuang Chemical Co.,Ltd.
2020-09-29	3-Nitrobenzyl bromide 3958-57-4	US $0.00 / KG	1KG	98%	200kgs	Xi'an Yutbon Pharmaceutical Technology Co., Ltd
2019-09-02	3-Nitrobenzyl bromide 3958-57-4	US $1.00 / KG	1KG	≥98%	200kg	Career Henan Chemical Co

3-Nitrobenzyl bromide
3958-57-4
US $0.00-0.00 / KG
98%
Henan Aochuang Chemical Co.,Ltd.

3-Nitrobenzyl bromide
3958-57-4
US $0.00 / KG
98%
Xi'an Yutbon Pharmaceutical Technology Co., Ltd

3-Nitrobenzyl bromide
3958-57-4
US $1.00 / KG
≥98%
Career Henan Chemical Co

3-Nitrobenzyl bromide Spectrum

3-Nitrobenzyl bromide(3958-57-4)MS 3-Nitrobenzyl bromide(3958-57-4)¹HNMR 3-Nitrobenzyl bromide(3958-57-4)¹³CNMR 3-Nitrobenzyl bromide(3958-57-4)IR1 3-Nitrobenzyl bromide(3958-57-4)IR2 3-Nitrobenzyl bromide(3958-57-4)Raman

3958-57-4(3-Nitrobenzyl bromide)Related Search:

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3-FLUORO-4-NITROBENZYL BROMIDE 4-Nitrobenzyl bromide 3-Nitrotoluene

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3-(BroMoMethyl)-1-nitrobenzene NSC 66499 3-Nitrobenzyl bromid α-Bromo-3-nitrotoluene 3-Nitrobenzyl bromide,99% A-BROMO-M-NITROTOLUENE ALPHA-BROMO-3-NITROTOLUENE ALPHA-BROMO-M-NITROTOLUENE 3-NITROBENZYL BROMIDE M-NITROBENZYL BROMIDE 1-(bromomethyl)-3-nitro-benzen m-(Bromomethyl)nitrobenzene m-Nitro-alpha-bromotoluene Toluene, alpha-bromo-m-nitro- a-Bromo-3-nitrotoluene 3-Nitrobenzyl bromide, 98+% à-bromo-3-nitrotoluene α-bromo-m-nitrotoluene 3-(Bromomethyl)nitrobenzene m-Nitro-a-bromotoluene 3-Nitro-1-(bromomethyl)benzene 3-NitrobenzylBromide> 3-Nitrobenzyl bromide, 98%, for synthesis Benzene, 1-(bromomethyl)-3-nitro- Rizatriptan Impurity 14 3-Nitrobromobenzyl Rizatriptan EP Impurity4 1-(Bromomethyl)-3-nitrobenzene 3958-57-4 Organic Building Blocks Nitrogen Compounds Nitro Compounds Building Blocks Aromatics Compounds Aromatics Halides Aromatic Halides (substituted)