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4-Iodobenzyl bromide

CAS No.
16004-15-2
Chemical Name:
4-Iodobenzyl bromide
Synonyms
SKL242;EGFR-1(18-;R-Protopanoxadiol;p-odobenzyl bromide;P-IODOBENZYL BROMIDE;4-IODOBENZYL BROMIDE;à-bromo-4-iodotoluene;α-broMo-4-iodotoluene;4-IodobenzylBromide>4-Iodobenzyl bromide,97%
CBNumber:
CB3421989
Molecular Formula:
C7H6BrI
Molecular Weight:
296.93
MDL Number:
MFCD00209656
MOL File:
16004-15-2.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:43

4-Iodobenzyl bromide Properties

Melting point 78-82 °C(lit.)
Boiling point 140°C 15mm
Density 2.0672 (rough estimate)
refractive index 1.6500 (estimate)
Flash point 140°C/15mm
storage temp. 2-8°C
form Adhering Crystalline Powder
color Light yellow
Water Solubility Insoluble in water.
Sensitive Light Sensitive/Lachrymatory
BRN 2325160
InChI InChI=1S/C7H6BrI/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
InChIKey BQTRMYJYYNQQGK-UHFFFAOYSA-N
SMILES C1(CBr)=CC=C(I)C=C1
CAS DataBase Reference 16004-15-2(CAS DataBase Reference)
FDA UNII 5452CN8QMZ
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C,T
Risk Statements  34-63-42/43-36/37/38
Safety Statements  26-36/37/39-45-23
RIDADR  UN 3261 8/PG 2
WGK Germany  3
Hazard Note  Corrosive/Lachrymatory/Light Sensitive
HazardClass  IRRITANT
HazardClass  8
PackingGroup 
HS Code  29039990
NFPA 704
1
3 1

4-Iodobenzyl bromide price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 515604 4-Iodobenzyl bromide 95% 16004-15-2 1g $34.8 2025-07-31 Buy
Sigma-Aldrich 515604 4-Iodobenzyl bromide 95% 16004-15-2 5g $103.94 2025-07-31 Buy
TCI Chemical I0571 4-Iodobenzyl Bromide 16004-15-2 5G $62 2025-07-31 Buy
TCI Chemical I0571 4-Iodobenzyl Bromide 16004-15-2 25G $277 2025-07-31 Buy
TRC I737248 4-Iodobenzyl Bromide 16004-15-2 2.5g $75 2021-12-16 Buy
Product number Packaging Price Buy
515604 1g $34.8 Buy
515604 5g $103.94 Buy
I0571 5G $62 Buy
I0571 25G $277 Buy
I737248 2.5g $75 Buy

4-Iodobenzyl bromide Chemical Properties,Uses,Production

Chemical Properties

light yellow adhering crystalline powder

Uses

4-Iodobenzyl bromide is used as an organic chemical synthesis intermediate.

Synthesis

4-Iodotoluene

624-31-7

4-Iodobenzyl bromide

16004-15-2

4-Iodotoluene (Compound 1C, 25 g) was added with N-bromosuccinimide (23.5 g) and benzoyl peroxide (375 mg) in carbon tetrachloride (375 ml) and heated to reflux for 7 hours under light conditions. After completion of the reaction, the mixture was stirred at room temperature overnight. Subsequently, the insoluble material was removed by filtration and the filtrate was concentrated under reduced pressure. The concentrated residue was recrystallized with ethyl acetate and hexane to afford the target product 4-iodobenzyl bromide (Compound 1D) in 60.3% yield. [0027] NMR hydrogen spectral data (CDCl3, with TMS as internal standard): δ 7.72 (d, 2H), 7.14 (d, 2H), 4.39 (s, 2H).

References

[1] Macromolecules, 2013, vol. 46, # 12, p. 4754 - 4763
[2] Acta Crystallographica Section C: Crystal Structure Communications, 2003, vol. 59, # 4, p. o216-o218
[3] Journal of Materials Chemistry C, 2015, vol. 3, # 4, p. 734 - 741
[4] Chemistry - An Asian Journal, 2017, vol. 12, # 6, p. 690 - 697
[5] Journal of Organic Chemistry, 2014, vol. 79, # 1, p. 223 - 229

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View Lastest Price from 4-Iodobenzyl bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Iodobenzyl bromide pictures 2025-08-08 4-Iodobenzyl bromide
16004-15-2
US $10.00 / KG 1KG 99% 5000000kg Hebei Mujin Biotechnology Co.,Ltd
4-Iodobenzyl bromide pictures 2025-06-24 4-Iodobenzyl bromide
16004-15-2
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
4-Iodobenzyl bromide pictures 2023-12-26 4-Iodobenzyl bromide
16004-15-2
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
4-IODOBENZYL BROMIDE ALPHA-BROMO-4-IODOTOLUENE 1-BROMOMETHYL-4-IODO-BENZENE P-IODOBENZYL BROMIDE 4-Iodobenzyl Bromide p-Iodobenzyl Bromide à-bromo-4-iodotoluene 4-Iodobenzyl bromide 97% p-odobenzyl bromide 4-Iodobenzyl bromide,97% R-Protopanoxadiol α-broMo-4-iodotoluene [(4-iodophenyl)Methyl]broManuide 1-(Bromomethyl)-4-iodobenzene, alpha-Bromo-4-iodotoluene 4-IodobenzylBromide> Benzene, 1-(bromomethyl)-4-iodo- EGFR-1(18- 4-Iodobenzyl bromide ISO 9001:2015 REACH SKL242 16004-15-2 IC6H4CH2Br C7 Aryl Building Blocks Halogenated Hydrocarbons Organic Building Blocks CMLLYL Methyl Halides Phenyls & Phenyl-Het Halogenated Hydrocarbons Aryl C7 Aromatic Halides (substituted) Methyl Halides Phenyls & Phenyl-Het Fluorobenzene