(PHENYLTHIOMETHYL)TRIMETHYLSILANE
- CAS No.
- 17873-08-4
- Chemical Name:
- (PHENYLTHIOMETHYL)TRIMETHYLSILANE
- Synonyms
- PHENYLTHIO(TRIMETHYLSILYL)METHANE;(PHENYLTHIOMETHYL)TRIMETHYLSILANE;TRIMETHYL(PHENYLTHIOMETHYL)SILANE;PHENYL TRIMETHYLSILYLMETHYL SULFIDE;(Phenylthiomethyl)trimethylsilane>Silane, trimethyl(phenylthio)methyl-;[[(Trimethylsilyl)methyl]thio]benzene;[(Trimethylsilyl)methyl]phenyl sulfide;Benzene, [[(trimethylsilyl)methyl]thio]-;Phenylthio(trimethylsilyl)methane Phenyl Trimethylsilylmethyl Sulfide Trimethyl(phenylthiomethyl)silane
- CBNumber:
- CB3462685
- Molecular Formula:
- C10H16SSi
- Molecular Weight:
- 196.38
- MDL Number:
- MFCD00009838
- MOL File:
- 17873-08-4.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Trimethyl(phenylthiomethyl)silane 99% | 268585 | 25g | $160 |
| (Phenylthiomethyl)trimethylsilane >98.0%(GC) | P1172 | 5mL | $457 |
| (Phenylthiomethyl)trimethylsilane Asreported | 288450 | 2g | $329 |
| (Phenylthiomethyl)trimethylsilane Asreported | 288450 | 5g | $480 |
| (Phenylthiomethyl)trimethylsilane Asreported | 288450 | 10g | $664 |
| More product size | |||
| Boiling point | 158-159 °C52 mm Hg(lit.) |
|---|---|
| Density | 0.967 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 103 °F |
| solubility | sol most common organic solvents. |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.97 |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| BRN | 1932375 |
| InChI | 1S/C10H16SSi/c1-12(2,3)9-11-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3 |
| InChIKey | UOQDIMYVQSHALM-UHFFFAOYSA-N |
| SMILES | C[Si](C)(C)CSc1ccccc1 |
| NIST Chemistry Reference | Silane, trimethyl[(phenylthio)methyl]-(17873-08-4) |
| UNSPSC Code | 12352103 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H226 | |||||||||
| Precautionary statements | P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20-38 | |||||||||
| Safety Statements | 23-28 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 2931.90.6000 | |||||||||
| HazardClass | 3.2 | |||||||||
| PackingGroup | III | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Acute Tox. 4 Inhalation Flam. Liq. 3 Skin Irrit. 2 |
|||||||||
| NFPA 704 |
|
(PHENYLTHIOMETHYL)TRIMETHYLSILANE price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 268585 | Trimethyl(phenylthiomethyl)silane 99% | 17873-08-4 | 25g | $160 | 2023-01-07 | Buy |
| TCI Chemical | P1172 | (Phenylthiomethyl)trimethylsilane >98.0%(GC) | 17873-08-4 | 5mL | $457 | 2026-04-30 | Buy |
| Usbiological | 288450 | (Phenylthiomethyl)trimethylsilane Asreported | 17873-08-4 | 2g | $329 | 2026-06-03 | Buy |
| Usbiological | 288450 | (Phenylthiomethyl)trimethylsilane Asreported | 17873-08-4 | 5g | $480 | 2026-06-03 | Buy |
| Usbiological | 288450 | (Phenylthiomethyl)trimethylsilane Asreported | 17873-08-4 | 10g | $664 | 2026-06-03 | Buy |
(PHENYLTHIOMETHYL)TRIMETHYLSILANE Chemical Properties,Uses,Production
Physical properties
bp 158–159 °C/52 mmHg; d20 0.967 g cm3; n20 D 1.5390.
Uses
lithio derivative is a one-carbon homologating agent leading to aldehydes via sila-Pummerer rearrangement, vinyl sulfides via Peterson alkenation, and vinylsilanes from silyl epoxides.
Preparation
(Phenylthiomethyl)trimethylsilane is abtained by reaction of Phenylthiomethyllithium with Chlorotrimethylsilane.[1]
storage
(Phenylthiomethyl)trimethylsilane is irriting; foul smelling; use in a fume hood.
Purification Methods
If the sample is suspect, then add H2O, wash it with 10% aqueous NaOH, H2O again, dry (anhydrous CaCl2) and fractionally distil it through a 2ft column packed with glass helices. [Cooper J Am Chem Soc 76 3713 1954.]
References
1. (a) Gilman, H.; Webb, F. J. JACS 1940, 62, 987. (b) Cooper, G. D. JACS 1954, 76, 3713. (c) Carey, F. A.; Court, A. S. JOC 1972, 37, 939.
(PHENYLTHIOMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13901 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Win-Win Chemical CO., Limited | 0086-577-64498589 | sales@win-winchemical.com | CHINA | 998 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
| Alfa Chemistry | +1-5166625404; | Info@alfa-chemistry.com | United States | 20405 | 58 |
| Zhengzhou Gecko Scientific Inc. | +8613938510057 | 1974496791@qq.com | China | 283 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Chemwill Asia Co.,Ltd. | 86-21-51086038 | chemwill_asia@126.com | CHINA | 23912 | 58 |
View Lastest Price from (PHENYLTHIOMETHYL)TRIMETHYLSILANE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2022-09-28 | [[(Trimethylsilyl)methyl]thio]benzene
17873-08-4
|
10g | 100% | 10kg | Zhengzhou Gecko Scientific Inc. | ||
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2020-01-09 | (PHENYLTHIOMETHYL)TRIMETHYLSILANE
17873-08-4
|
$9.80 | 1g | ≥99% | 100kg | Career Henan Chemical Co |
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![[[(Trimethylsilyl)methyl]thio]benzene pictures](/ProductImageEN/2022-09/Small/5c60bb5b-d022-4e86-8422-0733da68a94d.png)
- [[(Trimethylsilyl)methyl]thio]benzene
17873-08-4
- 100%
- Zhengzhou Gecko Scientific Inc.
-

- (PHENYLTHIOMETHYL)TRIMETHYLSILANE
17873-08-4
- $9.80
- ≥99%
- Career Henan Chemical Co






