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(PHENYLTHIOMETHYL)TRIMETHYLSILANE

CAS No.
17873-08-4
Chemical Name:
(PHENYLTHIOMETHYL)TRIMETHYLSILANE
Synonyms
PHENYLTHIO(TRIMETHYLSILYL)METHANE;(PHENYLTHIOMETHYL)TRIMETHYLSILANE;TRIMETHYL(PHENYLTHIOMETHYL)SILANE;PHENYL TRIMETHYLSILYLMETHYL SULFIDE;(Phenylthiomethyl)trimethylsilane>Silane, trimethyl(phenylthio)methyl-;[[(Trimethylsilyl)methyl]thio]benzene;[(Trimethylsilyl)methyl]phenyl sulfide;Benzene, [[(trimethylsilyl)methyl]thio]-;Phenylthio(trimethylsilyl)methane Phenyl Trimethylsilylmethyl Sulfide Trimethyl(phenylthiomethyl)silane
CBNumber:
CB3462685
Molecular Formula:
C10H16SSi
Molecular Weight:
196.38
MDL Number:
MFCD00009838
MOL File:
17873-08-4.mol
MSDS File:
SDS
Last updated:2026-05-28 06:32:27
Product description Number Pack Size Price
Trimethyl(phenylthiomethyl)silane 99% 268585 25g $160
(Phenylthiomethyl)trimethylsilane >98.0%(GC) P1172 5mL $457
(Phenylthiomethyl)trimethylsilane Asreported 288450 2g $329
(Phenylthiomethyl)trimethylsilane Asreported 288450 5g $480
(Phenylthiomethyl)trimethylsilane Asreported 288450 10g $664
More product size

(PHENYLTHIOMETHYL)TRIMETHYLSILANE Properties

Boiling point 158-159 °C52 mm Hg(lit.)
Density 0.967 g/mL at 25 °C(lit.)
refractive index n20/D 1.539(lit.)
Flash point 103 °F
solubility sol most common organic solvents.
form clear liquid
color Colorless to Almost colorless
Specific Gravity 0.97
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 1932375
InChI 1S/C10H16SSi/c1-12(2,3)9-11-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3
InChIKey UOQDIMYVQSHALM-UHFFFAOYSA-N
SMILES C[Si](C)(C)CSc1ccccc1
NIST Chemistry Reference Silane, trimethyl[(phenylthio)methyl]-(17873-08-4)
UNSPSC Code 12352103

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Warning
Hazard statements  H315-H319-H226
Precautionary statements  P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xn
Risk Statements  20-38
Safety Statements  23-28
RIDADR  UN 1993 3/PG 3
WGK Germany  3
HS Code  2931.90.6000
HazardClass  3.2
PackingGroup  III
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Inhalation
Flam. Liq. 3
Skin Irrit. 2
NFPA 704
2
0 0

(PHENYLTHIOMETHYL)TRIMETHYLSILANE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 268585 Trimethyl(phenylthiomethyl)silane 99% 17873-08-4 25g $160 2023-01-07 Buy
TCI Chemical P1172 (Phenylthiomethyl)trimethylsilane >98.0%(GC) 17873-08-4 5mL $457 2026-04-30 Buy
Usbiological 288450 (Phenylthiomethyl)trimethylsilane Asreported 17873-08-4 2g $329 2026-06-03 Buy
Usbiological 288450 (Phenylthiomethyl)trimethylsilane Asreported 17873-08-4 5g $480 2026-06-03 Buy
Usbiological 288450 (Phenylthiomethyl)trimethylsilane Asreported 17873-08-4 10g $664 2026-06-03 Buy
Product number Packaging Price Buy
268585 25g $160 Buy
P1172 5mL $457 Buy
288450 2g $329 Buy
288450 5g $480 Buy
288450 10g $664 Buy

(PHENYLTHIOMETHYL)TRIMETHYLSILANE Chemical Properties,Uses,Production

Physical properties

bp 158–159 °C/52 mmHg; d20 0.967 g cm3; n20 D 1.5390.

Uses

lithio derivative is a one-carbon homologating agent leading to aldehydes via sila-Pummerer rearrangement, vinyl sulfides via Peterson alkenation, and vinylsilanes from silyl epoxides.

Preparation

(Phenylthiomethyl)trimethylsilane is abtained by reaction of Phenylthiomethyllithium with Chlorotrimethylsilane.[1]

storage

(Phenylthiomethyl)trimethylsilane is irriting; foul smelling; use in a fume hood.

Purification Methods

If the sample is suspect, then add H2O, wash it with 10% aqueous NaOH, H2O again, dry (anhydrous CaCl2) and fractionally distil it through a 2ft column packed with glass helices. [Cooper J Am Chem Soc 76 3713 1954.]

References

1. (a) Gilman, H.; Webb, F. J. JACS 1940, 62, 987. (b) Cooper, G. D. JACS 1954, 76, 3713. (c) Carey, F. A.; Court, A. S. JOC 1972, 37, 939.

(PHENYLTHIOMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 71)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 13901 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Win-Win Chemical CO., Limited
0086-577-64498589 sales@win-winchemical.com CHINA 998 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49979 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29792 58
Win-Win chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14304 58
Alfa Chemistry
+1-5166625404; Info@alfa-chemistry.com United States 20405 58
Zhengzhou Gecko Scientific Inc.
+8613938510057 1974496791@qq.com China 283 58
Aladdin Scientific
tp@aladdinsci.com United States 57505 58
Chemwill Asia Co.,Ltd. 86-21-51086038 chemwill_asia@126.com CHINA 23912 58

View Lastest Price from (PHENYLTHIOMETHYL)TRIMETHYLSILANE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[[(Trimethylsilyl)methyl]thio]benzene pictures 2022-09-28 [[(Trimethylsilyl)methyl]thio]benzene
17873-08-4
10g 100% 10kg Zhengzhou Gecko Scientific Inc.
(PHENYLTHIOMETHYL)TRIMETHYLSILANE pictures 2020-01-09 (PHENYLTHIOMETHYL)TRIMETHYLSILANE
17873-08-4
$9.80 1g ≥99% 100kg Career Henan Chemical Co
(PHENYLTHIOMETHYL)TRIMETHYLSILANE PHENYLTHIO(TRIMETHYLSILYL)METHANE PHENYL TRIMETHYLSILYLMETHYL SULFIDE TRIMETHYL(PHENYLTHIOMETHYL)SILANE [(Trimethylsilyl)methyl]phenyl sulfide [[(Trimethylsilyl)methyl]thio]benzene Phenylthio(trimethylsilyl)methane Phenyl Trimethylsilylmethyl Sulfide Trimethyl(phenylthiomethyl)silane Silane, trimethyl(phenylthio)methyl- (Phenylthiomethyl)trimethylsilane, (Trimethylsilyl)methyl phenyl sulfide, Phenyl (trimethylsilyl)methyl sulfide (Phenylthiomethyl)trimethylsilane> Benzene, [[(trimethylsilyl)methyl]thio]- 17873-08-4 C6H5SCH2SiCH33 Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Sulfur Compounds (for Synthesis) Si-(C)4 Compounds Organometallic Reagents Others Organosilicon Si (Classes of Silicon Compounds) Si-(C)4 Compounds Silicon Compounds (for Synthesis) Sulfur Compounds (for Synthesis) Synthetic Organic Chemistry