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2-Methoxynaphthalene

2-Methoxynaphthalene structure

CAS No.: 93-04-9

Chemical Name:: 2-Methoxynaphthalene

Synonyms: NEROLIN YARA YARA;YARA YARA;NEROLINE YARA YARA;METHYL 2-NAPHTHYL ETHER;YARA;Jara jara;2-Methoxynaphthalene (Yara Yara);NSC 4171;Yura yara;IMPURITY-M

CBNumber:: CB3483471

Molecular Formula:: C11H10O

Molecular Weight:: 158.2

MDL Number:: MFCD00004061

MOL File:: 93-04-9.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-12 09:16:51

Product description	Number	Pack Size	Price
2-Methoxynaphthalene ≥99%, FG	W470411	1 each	$56.4
2-Methoxynaphthalene ≥99%, FG	W470411	100G	$116
2-Methoxynaphthalene ≥99%, FG	W470411	1KG	$280
NaproxenImpurityM PharmaceuticalSecondaryStandard;CertifiedReferenceMaterial	PHR2525	100MG	$620
2-Methoxynaphthalene ≥99%, FG	W470411	1 unit	$54.8
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2-Methoxynaphthalene Properties

Melting point	70-73 °C (lit.)
Boiling point	274 °C (lit.)
Density	1.064 g/mL at 25 °C (lit.)
vapor pressure	1.097Pa at 25℃
refractive index	1.5440 (estimate)
FEMA	4704 \| BETA-NAPHTHYL METHYL ETHER
FLAVIS Number	04.074 \| 2-Methoxynaphthalene
Flash point	272-274°C
storage temp.	Sealed in dry,Room Temperature
solubility	H2O: soluble (completely)
pka	0[at 20 ℃]
form	Crystalline Solid
color	White to yellow-brown
Odor	at 1.00 % in dipropylene glycol. sweet naphthyl floral orange blossom acacia neroli
Odor Type	naphthyl
biological source	synthetic
Water Solubility	INSOLUBLE
Merck	14,5997
JECFA Number	1257
BRN	1859408
Stability	Stable. Combustible. Incompatible with strong oxidizing agents.
Cosmetics Ingredients Functions	PERFUMING
InChI	1S/C11H10O/c1-12-11-7-6-9-4-2-3-5-10(9)8-11/h2-8H,1H3
InChIKey	LUZDYPLAQQGJEA-UHFFFAOYSA-N
SMILES	COc1ccc2ccccc2c1
LogP	3.318 at 25℃
CAS DataBase Reference	93-04-9(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS)	BETA-NAPHTHYL METHYL ETHER
EWG's Food Scores	1
FDA UNII	VX2T1Z50C4
NIST Chemistry Reference	Naphthalene, 2-methoxy-(93-04-9)
EPA Substance Registry System	Naphthalene, 2-methoxy- (93-04-9)
UNSPSC Code	41116107
NACRES	NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07,GHS09

Signal word

Warning

Hazard statements

H319-H411

Precautionary statements

P264-P273-P280-P305+P351+P338-P337+P313-P391

PPE

Eyeshields, Gloves, type N95 (US)

Safety Statements

22-24/25

RIDADR

UN 3077 9 / PGIII

WGK Germany

RTECS

QJ9468750

TSCA

TSCA listed

HazardClass

HS Code

29093090

Storage Class

11 - Combustible Solids

Hazard Classifications

Aquatic Chronic 2
Eye Irrit. 2

Toxicity

LD50 oral in rat: > 5gm/kg

REACH Registrations

Active

Limited Quantities

5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

NFPA 704


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2-Methoxynaphthalene price More Price(28)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	W470411	2-Methoxynaphthalene ≥99%, FG	93-04-9	1 each	$56.4	2026-04-30	Buy
Sigma-Aldrich	W470411	2-Methoxynaphthalene ≥99%, FG	93-04-9	100G	$116	2026-04-30	Buy
Sigma-Aldrich	W470411	2-Methoxynaphthalene ≥99%, FG	93-04-9	1KG	$280	2026-04-30	Buy
Sigma-Aldrich	PHR2525	NaproxenImpurityM PharmaceuticalSecondaryStandard;CertifiedReferenceMaterial	93-04-9	100MG	$620	2026-04-30	Buy
Sigma-Aldrich	W470411	2-Methoxynaphthalene ≥99%, FG	93-04-9	1 unit	$54.8	2025-07-31	Buy

Product number	Packaging	Price	Buy
W470411	1 each	$56.4	Buy
W470411	100G	$116	Buy
W470411	1KG	$280	Buy
PHR2525	100MG	$620	Buy
W470411	1 unit	$54.8	Buy

2-Methoxynaphthalene Chemical Properties,Uses,Production

Description

β-Naphthyl methyl ether has an intensely sweet, floral odor suggestive of orange blossoms. It is free from naphthol by-odor. It has a sweet, strawberry taste. This may be prepared from potassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthol with dimethyl sulfate or by direct esterification with methyl alcohol.

Chemical Properties

β-Naphthyl methyl ether has an intensely sweet, floral odor suggestive of orange blossoms; free from naphthol by-odor. It has a sweet, strawberry taste

Chemical Properties

white powder

Chemical Properties

Methyl 2-Naphthyl Ether forms white crystals (mp 73–74°C) with an intense orange blossom odor.

Uses

2-Methoxynaphthalene is an Impurity of the non-steroidal anti-inflammatory Naproxen (N377525).

Uses

2-methoxynaphthalene acylation is used as a model reaction to study the catalytic benefits of delamination. It was also used to study the alkali-metal-mediated manganation (AMMMn) reactions.

Uses

2-methoxynaphthalene acylation was used as a model reaction to study the catalytic benefits of delamination. It was also used to study the alkali-metal-mediated manganation (AMMMn) reactions.

Definition

ChEBI: 2-Methoxynaphthalene is a member of naphthalenes.

Preparation

From postassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthlol with dimethyl sulfate or by direct esterification with methyl alcohol

Synthesis Reference(s)

Tetrahedron, 48, p. 6439, 1992 DOI: 10.1016/S0040-4020(01)88233-8
Tetrahedron Letters, 22, p. 3463, 1981 DOI: 10.1016/S0040-4039(01)81932-8

Flammability and Explosibility

Not classified

Synthesis

Preparation of 2-Methoxynaphthalene from 2-naphthol.
Principle: Phenols can be methylated to give methyl ethers. Methylation can be done either by using diazomethane or dimethyl sulphate in alkaline medium.
Reaction:

Procedure: Take 0.5 g 2-naphthol and 0.2 g NaOH in 5 ml distilled water in a beaker (25 ml). Heat on a wire gauze to obtain a clear solution. Cool the solution (10-15°C) and then add 0.35 ml dimethyl sulphate drop wise. After the addition is over, warm the mixture for one hour at 70-80°C and then cool. Filter the product and wash it with 10% sodium hydroxide solution and then with water. Dry the product, record the practical yield and re-crystallize it.
Re-crystallization: Dissolve the crude product in minimum amount of ethyl alcohol in a beaker by heating on a water bath. Filter the hot solution and cool the filtrate. Filter the white crystals of the product. Dry and record the melting point and TLC (using toluene as solvent).

Purification Methods

Fractionally distil the ether under vacuum. Crystallise it from absolute EtOH, aqueous EtOH, *C6H6, pet ether or n-heptane, and dry it under vacuum in an Abderhalden pistol or distil it in vacuo. The picrate has m 118o (from EtOH or CHCl3). [Kikuchi et al. J Phys Chem 91 574 1987, Beilstein 6 III 2969, 6 IV 4257.]

2-Methoxynaphthalene synthesis

Synthesis of 2-Methoxynaphthalene from Dimethyl carbonate and 2-Naphthol

2-Methoxynaphthalene Preparation Products And Raw materials

Raw materials

Aurantiol (methyl anthranilate and hydroxycitronellal schiff base) Methanol 1-Naphthylamine Sulfuric acid 2-Methoxy-1-phenylnaphthalene

1-Iodo-2-methoxynaphthalene 2-CYANO-6-METHOXYNAPHTHALENE 2-methoxy-3-(methylthio)-naphthalen (2-METHOXY-1-NAPHTHYL)BORONIC ACID 1-BROMO-2-METHOXYNAPHTHALENE

2-Bromo-6-methoxynaphthalene Dimethyl acetylenedicarboxylate 4,4'-METHYLENEBIS(2,6-DIMETHYLPHENOL)

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Preparation Products

6-METHOXY-2-NAPHTHOIC ACID 6-METHOXY-1,2,3,4-TETRAHYDRONAPHTHALENE 6-Methoxy-2-naphthaldehyde 2-Acetyl-6-methoxynaphthalene DL-6-METHOXY-ALPHA-METHYL-2-NAPHTHALENEMETHANOL

2-METHOXY-1-NAPHTHOIC ACID 2-Bromo-3-methoxynaphthalene 3-METHOXY-2-NAPHTHOIC ACID

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2-Methoxynaphthalene Suppliers

Global( 554)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shaanxi Dideu Medichem Co. Ltd	+8617392709771	1097@dideu.com	China	3995	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-86-13131129325 +8613131129325	sales1@chuanghaibio.com	China	5235	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615531151365	mina@chuanghaibio.com	China	18126	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20124	58
Hebei Zhuanglai Chemical Trading Co Ltd	+86-16264648883	niki@zlchemi.com	China	7245	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21588	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29817	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	1497	58
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2949	58

Supplier	Advantage
Shaanxi Dideu Medichem Co. Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Hebei Zhuanglai Chemical Trading Co Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Jinan Finer Chemical Co., Ltd	58

View Lastest Price from 2-Methoxynaphthalene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-05-15	2-Methoxynaphthalene 93-04-9	US $0.00 / Kg/Drum	1KG	≥99%	2000mt/year	Jinan Finer Chemical Co., Ltd
2026-04-21	2-Methoxynaphthalene 93-04-9	US $39.00 / mL		99.97%	10g	TargetMol Chemicals Inc.
2026-04-21	2-Methoxynaphthalene 93-04-9	US $39.00 / mL		99.97%	10g	TargetMol Chemicals Inc.

2-Methoxynaphthalene
93-04-9
US $0.00 / Kg/Drum
≥99%
Jinan Finer Chemical Co., Ltd

2-Methoxynaphthalene
93-04-9
US $39.00 / mL
99.97%
TargetMol Chemicals Inc.

2-Methoxynaphthalene
93-04-9
US $39.00 / mL
99.97%
TargetMol Chemicals Inc.

2-Methoxynaphthalene Spectrum

2-Methoxynaphthalene(93-04-9)MS 2-Methoxynaphthalene(93-04-9)¹HNMR 2-Methoxynaphthalene(93-04-9)¹³CNMR 2-Methoxynaphthalene(93-04-9)IR1 2-Methoxynaphthalene(93-04-9)IR2 2-Methoxynaphthalene(93-04-9)Raman

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Naproxen Impurity 13（Naproxen EP Impurity M） 2-Methoxynaphthaleneodium salt hydrate NEROLINE YARA YARA NEROLIN YARA YARA NAPROXEN IMP M 2-NAPHTHYL METHYL ETHER 2-METHOXYNAPHTHALENE methyl β-naphthyl ether 2-METHOXYNAPHTHALENE 99+% 2-Methoxynaphthalene,98% 2-methoxy-naphthalen 2-Naphthol methyl ether 2-naphtholmethylether beta-Methoxynaphthalene Ethyl beta-naphthyl ether Jara jara Methyl beta-naphthyl ether methylbeta-naphthylether Naphthalene,2-methoxy- β-Naphthol methyl ether neroline “old” YARA YARA CRYSTALS 2-Methoxynaphthalene, Methyl 2-naphthyl ether b-Methoxynaphthalene Methyl 2-naphtyl ether 2-Methoxynaphthalene, 98% 5GR 6-Methoxy-2-naphthalene NSC 4171 2-Methoxynaphthalene (Yara Yara) 2-Methoxynaphthalene , 98.0%(GC) YARA -Naphthylmethylether Nerolin (old) nerolin(old) Yura yara METHYL 2-NAPHTHYL ETHER BETA-METHYL NAPHTHYL ETHER BETA NAPHTHOL METHYL ETHER BETA-NAPHTHYL METHYL ETHER B-NAPHTHOL METHYL ETHER B-NAPHTHYL METHYL ETHER YARA YARA METHYL B-NAPHTHYL ETHER Methyl 2-naphthyl ether beta-Naphthyl methyl ether 2-MethoxynaphthaL 2-Methoxynaphthalene(Nerolin) 2-Methoxynaphthalene> High Quality 2-methoxynaphthalene 2-Methoxynaphthalene USP/EP/BP Naproxen EP Impurity M (Nerolin) Naproxen Impurity M Ethyl naphthyl methyl ether IMPURITY-M 2-Methoxynaphthalene in methanol Agomelatine impurity 35 2-Methoxynaphthalene, 10 mM in DMSO 2-Methoxyphthalene Β-Naphthol Methyl Ether