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Aluminum oxide

CAS No.
11092-32-3
Chemical Name:
Aluminum oxide
Synonyms
ALUMINIUM OXIDE;CORUNDUM;RUBY;BOILING CHIPS;AlO2;ALUMINA;ALUNDUM;SAPPHIRE;ALUMINA R;ALUMINA A
CBNumber:
CB3490231
Molecular Formula:
AlO2
Crystal structure
aluminum-oxide crystal structure
Molecular Weight:
58.98
MDL Number:
MFCD00003424
MOL File:
11092-32-3.mol
MSDS File:
SDS
Last updated:2026-08-25 20:17:46

Aluminum oxide Properties

Melting point 2040 °C(lit.)
Boiling point 2977 °C
Density 1.06 g/mL at 25 °C
form powder
Water Solubility Insoluble in water.
Exposure limits ACGIH: TWA 1 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
Dielectric constant 4.5(Ambient)
Cosmetic Ingredient Review (CIR) Aluminum oxide (11092-32-3)
InChI InChI=1S/Al.2O
InChIKey DGTWKHOKSKFICW-UHFFFAOYSA-N
SMILES [Al](=O)=O
CAS DataBase Reference 11092-32-3(CAS DataBase Reference)
EWG's Food Scores 1
ATC code D10AX04
UNSPSC Code 11181511
NACRES NA.23

SAFETY

Risk and Safety Statements

Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
RIDADR  UN1263
WGK Germany  -
RTECS  BD1200000
3
TSCA  Yes
HazardClass  3
PackingGroup  III
NFPA 704
0
1 0

Aluminum oxide price More Price(63)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich GF96001387 Alumina washer,sizem8(ansi),length25pcs,outsidediameter24.48-25.40mm 1ea $642 2026-04-30 Buy
Sigma-Aldrich GF92436026 Alumina powder,45meanparticlesize(micron),weight100 g,purity99.9% 1ea $247 2026-04-30 Buy
Sigma-Aldrich GF91715014 Alumina sphere,0.5 mmdiameter,20pcs,tolerance+/-2.5um 1ea $278 2026-04-30 Buy
Sigma-Aldrich GF90662744 Alumina bolt,length25pcs,sizem5x30mm,headstylehexagonal 1ea $1690 2026-04-30 Buy
Sigma-Aldrich GF90406492 Alumina tube,outsidediameter26mm,wallthickness3 mm,length100mm 1ea $487 2026-04-30 Buy
Product number Packaging Price Buy
GF96001387 1ea $642 Buy
GF92436026 1ea $247 Buy
GF91715014 1ea $278 Buy
GF90662744 1ea $1690 Buy
GF90406492 1ea $487 Buy

Aluminum oxide Chemical Properties, Uses, Production

Characteristics

Aluminum Oxide (Alumina) is the most widely used oxide, chiefly because it is plentiful, relatively low in cost, and equal to or better than most oxides in mechanical properties. Density can be varied over a wide range, as can purity — down to about 90% alumina — to meet specific application requirements. Alumina ceramics are the hardest, strongest, and stiffest of the oxides. They are also outstanding in electrical resistivity, dielectric strength, are resistant to a wide variety of chemicals, and are unaffected by air, water vapor, and sulfurous atmospheres. However, with a melting point of only 2039°C, they are relatively low in refractoriness, and at 1371°C retain only about 10% of room-temperature strength. In addition to its wide use as electrical insulators and its chemical and aerospace applications, the high hardness and close dimensional tolerance capability of alumina make this ceramic suitable for such abrasion-resistant parts as textile guides, pump plungers, chute linings, discharge orifices, dies, and bearings.

Uses

Aluminum oxide is used for the separation of both inorganic anions and acidic organic molecules such as acidic amino acids, aromatic acids and carboxylic acids. It is essential in protein extraction as a component in the preparation of tissues. It is also used as a grinding or blending agent. Aluminum oxide is a source of aluminum in reactions, an abrasive agent, and as a refractory material. Also Aluminum oxide can act as a catalyst in a variety of reactions such as the claus process and in the dehydration of alcohols to alkenes. In single crystals of aluminum oxide intrinsic diffusion occurs in a high temperature region.

Preparation

Pure alumina, needed to produce aluminum by the Hall process, is made by the Bayer process. The starting material is bauxite (Al2O3 nH2O). The ore contains impurities, such as, SiO2, Fe2O3, TiO2, and Na2O. Most impurities are removed following treatment with caustic soda solution. Bauxite is dissolved in NaOH solution. Silica, iron oxides and other impurities are filtered out of the solution. CO2 is then bubbled through this solution. This precipitates out hydrated alumina, which is heated to remove water and produce Al2O3. These impurities are removed. Calcinations of bauxite produce alumina of abrasive and refractory grades. Activated aluminas of amorphous type, as well as the transition aluminas of γ, η, χ, and ρ forms, are obtained from various aluminum hydroxides, such as, α- and β-trihydrates, α-monohydrate and alumina gel. Such chemicals are obtained from bauxite by the Bayer process also.

Definition

A mineral form of aluminiumoxide, Al2O3. It crystallizesin the trigonal system and occurs aswell-developed hexagonal crystals. Itis colourless and transparent whenpure but the presence of other elementsgives rise to a variety ofcolours. Ruby is a red variety containingchromium; sapphire is ablue variety containing iron andtitanium. Corundum occurs as arock-forming mineral in both metamorphicand igneous rocks. It ischemically resistant to weatheringprocesses and so also occurs in alluvial(placer) deposits. The secondhardest mineral after diamond (it hasa hardness of 9 on the Mohs’ scale), itis used as an abrasive.

Hazard

Chronic inhalation of Al2O3 dusts may cause lung damage.

Agricultural Uses

Alumina is a white or colorless oxide occurring in two forms, a-alumina and γ-alumina. The γ-alumina turns into a stable a form on heating. Naturally occurring alumina is called corundum or emery.
The gemstones ruby and sapphire are aluminum oxides colored by minute traces of chromium and cobalt, respectively. The highly protective film of oxide formed on the surface of aluminum is yet another structural variation, a defective form of rock salt.
Pure aluminum oxide is obtained by dissolving bauxite ore in sodium hydroxide solution to eliminate insoluble impurities. Seeding the solution with material from a previous batch precipitates the hydrated oxide, which on further heating gives γ-alumina at 500 to 800°C and pure a-alumina at 1150 to 1200°C. The latter is one of the hardest materials known. It is used widely as an abrasive substance in both its natural and synthetic forms. Its refractory nature makes alumina bricks an ideal material for furnace linings and high temperature cements.
Alumina occurs in phosphate rocks along with iron and other impurities in small percentages. Alumina and iron in phosphate rock make the superphosphate moist and sticky. The maximum acceptable alumina and iron in the rock for farming is 3 to 4 %

Materials Uses

Fused aluminum oxide was the second synthetic abrasive to be developed. Synthetic aluminum oxide (alumina) is made as a white powder and can be somewhat harder than corundum (natural alumina) because of its purity. However, corundum has a Mohs hardness of approximately 9 (on a scale of 1 to 10. Alumina can be processed with different properties by slight alteration of the reactants in the manufacturing process. Several grain sizes of alumina are available, and alumina has largely replaced emery for several abrasive uses. Aluminum oxide is widely used to make bonded abrasives, coated abrasives, and air-propelled grit abrasives for dental applications.
Sintered aluminum oxide is used to make white stones, which are popular for adjusting dental enamel and finishing metal alloys, resin-based composites, and ceramic materials.
Pink and ruby variations of aluminum oxide abrasives are made by adding chromium compounds to the original melt. These variations are sold in a vitreous-bonded form as noncontaminating mounted stones for the preparation of metal– ceramic alloys to receive porcelain. Remnants of these abrasives and other debris should be removed from the surface of metals used for metal–ceramic bonding so as not to prevent optimal bonding of porcelain to the metal alloy. A review by Yamamoto (see Selected Reading) suggests that carbide burs are the most effective instruments for finishing this type of alloy because they do not contaminate the metal surface with entrapped abrasive particles.
CORUNDUM: This mineral form of aluminum oxide is usually white. Its physical properties are inferior to those of manufactured alpha (α) aluminum oxide (Al2O3), which has largely replaced corundum in dental applications. Corundum is used primarily for grinding metal alloys and is available as a bonded abrasive in several shapes. It is most commonly used in an instrument known as a white stone.

Aluminum oxide Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 85)
Supplier Tel Email Country ProdList Advantage
3B Pharmachem (Wuhan) International Co.,Ltd. 18930552037 3bsc@sina.com China 15813 69
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Alfa Chemistry +1-5166625404; Info@alfa-chemistry.com United States 20000 58
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418671 +86-189 4982 3763 sales@tnjchem.com China 34526 58
career henan chemical co +86-0371-86658258 factory@coreychem.com China 29780 58
Energy Chemical 400-0056266 marketing1@energy-chemical.com China 44927 58
Hubei yongkuo Technology Co., Ltd 027-59223108 15972152991 1248580099@qq.com China 9910 58
Hubei Wande Chemical Co., Ltd 15377098680 15377098680 1148280011@qq.com China 9436 58
Wuhan Penglei Biological Technology Co., Ltd. 18672616696 229092275@qq.com China 706 58
Dongguan Walixi Chemical Co., Ltd 0796-8612228 18664658771 1489577060@qq.com China 4844 58

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Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Aluminum oxide pictures 2026-09-14 Aluminum oxide
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1kg/Bag ≥98% 50 T/Month Hebei Qujie Technology Co., Ltd.
aluminum oxide pictures 2020-02-01 aluminum oxide
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$1.00 1KG Min98% HPLC Career Henan Chemical Co
Alumina; Aluminum Oxide pictures 2018-04-25 Alumina; Aluminum Oxide
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$22.60 25KG 99.999%; 99.99%; 99.9% 1000tons Chemson Industrial (Shanghai) Co., Ltd.
Alummum oxide Single-pass AAO V type AAO Double-pass AAO Aluminum oxide, Single crystal, 25.4mm dia x 0.5mm thick, random orientation ALUMINIUM OXIDE BASIC ALUMINIUM OXIDE, BROCKMANN TYPE I ALUMINIUM OXIDE, BROCKMANN TYPE II ALUMINIUM OXIDE NEUTRAL ALUMINA N-TLC ALUMINA R ALUMINAR CC-10 ALUMINA ALUMINA A ALUMINA A 18-32 ALUMINA, ACID, BROCKMAN ACTIVITY I ALUMINA, ACTIVATED ALUMINA ACTIVATED 200 ALUMINA ACTIVATED 300 ALUMINA, ACTIVATED, ACIDIC, BROCKMANN I ALUMINA, ACTIVATED, BASIC ALUMINA, ACTIVATED, BASIC, BROCKMANN I ALUMINA, ACTIVATED, NEUTRAL, BROCKMANN I ALUMINA, ADSORPTION ALUMINIUM OXIDE 150 ALUMINIUM OXIDE 150 BASIC (TYPE T) ALUMINIUM OXIDE 60 ALUMINIUM OXIDE 60GF254 ALUMINIUM OXIDE 60 GF254 NEUTRAL ALUMINIUM OXIDE 60 G NEUTRAL ALUMINIUM OXIDE 90 ALUMINIUM OXIDE 90, ACTIVE BASIC ALUMINIUM OXIDE ACIDIC ALUMINIUM OXIDE, ACTIVATED ALUMINUM OXIDE GAMMA-ALPHA ALUMINUM OXIDE H 31101 ALUMINUM OXIDE H 32001 ALUMINUM OXIDE, NEUTRAL ALUMINUM OXIDE, REFRACTORY BRUSHABLE PAINT, WATER-BASED ALUMINUM OXIDE SUBSTRATE ALUMINUM OXIDE, WEAKLY ACIDIC ALUMINUM OXIDE 60 ALUMINUM OXIDE 60 BASIC ALUMINUM OXIDE 60 G ALUMINUM OXIDE 60 GF254 ALUMINUM OXIDE 60 GF254 NEUTRAL ALUMINUM OXIDE 60 G NEUTRAL ALUMINUM OXIDE 60 PF254/366 ALUMINUM OXIDE 90 ALUMINUM OXIDE 90 ACIDIC ALUMINUM OXIDE 90 BASIC ALUMINUM OXIDE 90 NEUTRAL ALUMINUM OXIDE, ACID ALUMINUM OXIDE, ACTIVATED ALUMINUM OXIDE, ACTIVATED, ACIDIC ALUMINUM OXIDE, ACTIVATED, ACIDIC, BROCKMANN I ALUMINUM OXIDE ACTIVATED, BASIC ALUMINUM OXIDE ACTIVATED, NEUTRAL