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Methyltriphenylphosphonium iodide

CAS No.
2065-66-9
Chemical Name:
Methyltriphenylphosphonium iodide
Synonyms
methyltriphenylphosphonium;MPJ;Methyltriphenylphosp;Methyltriphenyl iodide;MethyltriphenylphosphoniuM iod;Triphenylmethylphosphine iodide;METHYLTRIPHENYPHOSPHONIUMIODIDE;Methyltriphenylphosphonium Iodi;Methyltriphenylphosphanium iodid;Triphenylmethylphosphinium iodide
CBNumber:
CB3673698
Molecular Formula:
C19H18IP
Molecular Weight:
404.22
MDL Number:
MFCD00066175
MOL File:
2065-66-9.mol
MSDS File:
SDS
Last updated:2026-01-13 11:18:10
Product description Number Pack Size Price
Methyltriphenylphosphonium iodide 97% 245054 25g $95.4
Methyltriphenylphosphonium Iodide >98.0%(T) M0253 25g $64
Methyltriphenylphosphonium Iodide >98.0%(T) M0253 100g $202
Methyltriphenylphosphonium Iodide >98.0%(T) M0253 500g $591
Methyltriphenylphosphonium Iodide M330995 1g $45
More product size

Methyltriphenylphosphonium iodide Properties

Melting point 183-185 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Powder
color White to light yellow
Water Solubility SOLUBLE
Sensitive Light Sensitive & Hygroscopic
InChI InChI=1S/C19H18P.HI/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
InChIKey JNMIXMFEVJHFNY-UHFFFAOYSA-M
SMILES [P+](C)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[I-]
CAS DataBase Reference 2065-66-9(CAS DataBase Reference)
FDA UNII 3B2B7G7R4G
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi,T
Risk Statements  36/37/38-25
Safety Statements  26-36-45-37/39-28A
RIDADR  UN3464
WGK Germany  3
HazardClass  6.1
PackingGroup  III
HS Code  29319090
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
3 1

Methyltriphenylphosphonium iodide price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 245054 Methyltriphenylphosphonium iodide 97% 2065-66-9 25g $95.4 2026-03-19 Buy
TCI Chemical M0253 Methyltriphenylphosphonium Iodide >98.0%(T) 2065-66-9 25g $64 2026-03-19 Buy
TCI Chemical M0253 Methyltriphenylphosphonium Iodide >98.0%(T) 2065-66-9 100g $202 2026-03-19 Buy
TCI Chemical M0253 Methyltriphenylphosphonium Iodide >98.0%(T) 2065-66-9 500g $591 2026-03-19 Buy
TRC M330995 Methyltriphenylphosphonium Iodide 2065-66-9 1g $45 2021-12-16 Buy
Product number Packaging Price Buy
245054 25g $95.4 Buy
M0253 25g $64 Buy
M0253 100g $202 Buy
M0253 500g $591 Buy
M330995 1g $45 Buy

Methyltriphenylphosphonium iodide Chemical Properties,Uses,Production

Chemical Properties

WHITE TO LIGHT YELLOW POWDER

Uses

suzuki reaction

Uses

Methyltriphenylphosphonium iodide is as a reactant for synthesis of triphenylamine-based dyes and polyolefinic aromatic molecules with pyrene for use in dye-sensitized solar cells. Used as ligand in coupling reaction. It is also used as a precursor to a Wittig reagent.

Preparation

Methyltriphenylphosphonium iodide was prepared by the following procedure. Triphenylphosphine was recrystallized from ethanol and dried over phosphorus pentoxide under reduced pressure for 12 hr. A solution of 39 g (0.15 mol) of triphenylphosphine and 10.0 mL (22.8 g, 0.16 mol) of iodomethane in 105 mL of benzene was allowed to stir at room temperature for 12 hr. The precipitate was filtered, washed with benzene, and dried over phosphorus pentoxide under reduced pressure for 12 hr. The yield was 57 g (94%), mp 189°C (lit.2 mp 182°C).

reaction suitability

reaction type: C-C Bond Formation

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View Lastest Price from Methyltriphenylphosphonium iodide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyltriphenylphosphonium iodide pictures 2026-04-23 Methyltriphenylphosphonium iodide
2065-66-9
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Methyltriphenylphosphoniumiodide pictures 2025-09-25 Methyltriphenylphosphoniumiodide
2065-66-9
US $5.00-0.50 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Methyltriphenylphosphonium iodide pictures 2025-06-27 Methyltriphenylphosphonium iodide
2065-66-9
US $0.00 / KG 1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
METHYLTRIPHENYLPHOSPHONIUM IODIDE MPJ TRIPHENYLMETHYL PHOSPHONIUM IODIDE Methyl triphenylphosphonium iodide, 98+% METHYLTRIPHENYPHOSPHONIUMIODIDE Methyltriphenylphosphanium iodide Phosphonium, methyltriphenyl-, iodide Triphenylmethylphosphine iodide Triphenylmethylphosphinium iodide methyltriphenylphosphonium Methyltriphenylphosphonium iodide,97% Methyl(trisphenyl)phosphonium iodide Methyltriphenylphosp MethyltriphenylphosphoniuM iod MethylTriphenyl phosphoniuM iodine Methyl(trisphenyl)phosphonium iodide 97% MethyltriphenylphosphoniuM Iodide , 98.0%(T) Methyltriphenylphosphonium iodide 97% METHYL TRIPHENYL PHOSPHONIUM IODIDE MTPPI Methyltriphenylphosphanium iodid MethyltriphenylphosphoniumIodide> Methyltriphenyl iodide Methyltriphenylphosphonium Iodi 2065-66-9 C19H19IP C19H18PI C6H53PCH3I Wittig Reagents Synthetic Reagents Olefination Wittig Reaction Wittig & Horner-Emmons Reaction Phosphonium Compounds C-C Bond Formation C-C Bond Formation Olefination Wittig Reagents Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction