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Caronic anhydride

CAS No.
67911-21-1
Chemical Name:
Caronic anhydride
Synonyms
6,6-Dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione;aronicanhydride;caronic anhydride;Calderon anhydride;Vanillin Impurity 4;Caronic Anhydride >WIDELY Caronic anhydride;Caronic anhydride(Cas number:67911-21-1);6,6-Dimethyl-3-oxabicyclo[3.1.]hexane-2,4-dione;6,6-Dimethyl-3-oxa-bicyclo[3.1.0]hexan-2,4-dione
CBNumber:
CB3855588
Molecular Formula:
C7H8O3
Molecular Weight:
140.14
MDL Number:
MFCD09751198
MOL File:
67911-21-1.mol
MSDS File:
SDS
Last updated:2026-01-12 17:28:22
Product description Number Pack Size Price
Caronic Anhydride >98.0%(GC)(T) C2596 1g $102
Caronic Anhydride >98.0%(GC)(T) C2596 5g $368
Caronic Anhydride C184263 500mg $65
Caronic Anhydride C184263 100mg $45
Caronic Anhydride FC75910 10g $57.6
More product size

Caronic anhydride Properties

Melting point 53-57℃
Boiling point 246°C
Density 1.274
Flash point 113°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility soluble in Methanol
form Solid
color White
Sensitive Moisture Sensitive
InChI InChI=1S/C7H8O3/c1-7(2)3-4(7)6(9)10-5(3)8/h3-4H,1-2H3
InChIKey QKAHKEDLPBJLFD-UHFFFAOYSA-N
SMILES C12C(C1(C)C)C(=O)OC2=O
CAS DataBase Reference 67911-21-1(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
HazardClass  IRRITANT
HS Code  2914199090
NFPA 704
1
2 0

Caronic anhydride price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical C2596 Caronic Anhydride >98.0%(GC)(T) 67911-21-1 1g $102 2025-07-31 Buy
TCI Chemical C2596 Caronic Anhydride >98.0%(GC)(T) 67911-21-1 5g $368 2025-07-31 Buy
TRC C184263 Caronic Anhydride 67911-21-1 500mg $65 2021-12-16 Buy
TRC C184263 Caronic Anhydride 67911-21-1 100mg $45 2021-12-16 Buy
Biosynth Carbosynth FC75910 Caronic Anhydride 67911-21-1 10g $57.6 2021-12-16 Buy
Product number Packaging Price Buy
C2596 1g $102 Buy
C2596 5g $368 Buy
C184263 500mg $65 Buy
C184263 100mg $45 Buy
FC75910 10g $57.6 Buy

Caronic anhydride Chemical Properties,Uses,Production

Chemical Properties

White crystalline powder

Uses

Caronic anhydride, also known as 6,6-Dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione, is a pharmaceutical intermediate mainly used as a synthesis of Boceprevir, an oral protease inhibitor of hepatitis C. It is widely used in agricultural chemicals and other organic synthesis field.

Synthesis

Step 1: Ethyl dichlorochrysanthemate in ethyl acetate is ozonized at -5C until conversion exceeds 99%. Work-up, saponification, acidification, extraction, and concentration yield 3,3-dimethyl-1,2-cyclopropanedicarboxylic acid.
Step 2: The diacid is heated with acetic anhydride and sodium acetate at 170C to form the anhydride via dehydration. Work-up and recrystallization from toluene/petroleum ether give 6,6-dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione (Caronic anhydride).

497-42-7
67911-21-1
Synthesis of Caronic anhydride from 3,3 DIMETHYL CIS 1,2 CYCLOPROPANE DICARBOXYLIC ACID

Caronic anhydride Preparation Products And Raw materials

Global( 374)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Safer Pharmaceutical Technology Co., Ltd.
021-31761238 sales@saferph.com CHINA 897 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 18843 58
Jiangxi Huihe Chemical Co., Ltd.
+86-19189228086 +8618858568638 wuzhouding@huihecrop.com China 886 58
Shaoxing Fangxiao Chemical Co., LTD
+86-13456999252 +86-13868192239 kenny@fangxiaochem.com China 50 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615350571055 Sibel@chuanghaibio.com China 8752 58
Hebei Yanxi Chemical Co., Ltd.
+8618531123677 faithe@yan-xi.com China 5853 58
Hangzhou ICH Biofarm Co., Ltd
+86-0571-28186870; +undefined8613073685410 sales@ichemie.com China 1006 58
airuikechemical co., ltd.
+86-18353166132 sales02@airuikechemical.com China 983 58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 16513 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718; +8613336195806 sales@capot.com China 29735 60

View Lastest Price from Caronic anhydride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Caronic anhydride pictures 2026-03-06 Caronic anhydride
67911-21-1
US $0.00-0.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
Caronic anhydride pictures 2026-03-06 Caronic anhydride
67911-21-1
US $0.00-0.00 / kg 1kg 99% 500kg WUHAN FORTUNA CHEMICAL CO., LTD
Caronicanhydride pictures 2026-01-04 Caronicanhydride
67911-21-1
US $0.00-0.00 / kg 1kg 99.0% 20 tons Hangzhou ICH Biofarm Co., Ltd
  • Caronic anhydride pictures
  • Caronic anhydride
    67911-21-1
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Chuanghai Biotechnology Co., Ltd

Caronic anhydride Spectrum

6,6-Dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione caronic anhydride 6,6-Dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione caronic anhydride aronicanhydride aronicanhydride 3-Oxabicyclo[3.1.0]hexane-2,4-dione,6,6-diMethyl- 6,6-Dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione (Caronic anhydride) 6,6-dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-quinone 6,6-Dimethyl-3-oxabicyclo[3.1.]hexane-2,4-dione Caronic anhydride(Cas number:67911-21-1) Caronic Anhydride > 3,3-Dimethyl-1,2-cyclopropanedicarboxylic Anhydride WIDELY Caronic anhydride Calderon anhydride Vanillin Impurity 4 (1R,5S)-6,6-Dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione 6,6-Dimethyl-3-oxa-bicyclo[3.1.0]hexan-2,4-dione 67911-21-1 API 1 3 67911-21-1