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5-Bromo-2-(dimethylamino)pyridine

CAS No.
26163-07-5
Chemical Name:
5-Bromo-2-(dimethylamino)pyridine
Synonyms
3-Bromo-6-dimethylaminopyridine;5-Bromo-N,N-dimethylpyridin-2-amine;5-Bromo-N,N-dimethyl-2-pyridinamine;(5-bromo-pyridin-2-yl)-dimethylamine;5-bromo-2-(N,N-dimethyl-1-yl)pyridine;2-PyridinaMine, 5-broMo-N,N-diMethyl-;5-Bromo-2-(dimethylamino)pyridine ISO 9001:2015 REACH
CBNumber:
CB3957798
Molecular Formula:
C7H9BrN2
Molecular Weight:
201.06
MDL Number:
MFCD00099486
MOL File:
26163-07-5.mol
MSDS File:
SDS
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
5-Bromo-2-dimethylaminopyridine SYX00280 1g $87.5
5-Bromo-2-(dimethylamino)pyridine B691533 1g $75
5-Bromo-2-(dimethylamino)pyridine B691533 250mg $55
5-Bromo-2-(dimethylamino)pyridine 3H32-9-Y9 5G $66
5-Bromo-2-(dimethylamino)pyridine 97% B1391 25g $70

5-Bromo-2-(dimethylamino)pyridine Properties

Melting point 69-71 °C
Boiling point 253.5±20.0 °C(Predicted)
Density 1.469±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
form solid
pka 5.31±0.10(Predicted)
Appearance Off-white to light yellow Solid
InChI InChI=1S/C7H9BrN2/c1-10(2)7-4-3-6(8)5-9-7/h3-5H,1-2H3
InChIKey XIMCGXXYEMOWQP-UHFFFAOYSA-N
SMILES C1(N(C)C)=NC=C(Br)C=C1
UNSPSC Code 12352200

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P280-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  22
Hazard Note  Irritant
HS Code  2933399990

5-Bromo-2-(dimethylamino)pyridine price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich SYX00280 5-Bromo-2-dimethylaminopyridine 26163-07-5 1g $87.5 2025-07-31 Buy
TRC B691533 5-Bromo-2-(dimethylamino)pyridine 26163-07-5 1g $75 2021-12-16 Buy
TRC B691533 5-Bromo-2-(dimethylamino)pyridine 26163-07-5 250mg $55 2021-12-16 Buy
SynQuest Laboratories 3H32-9-Y9 5-Bromo-2-(dimethylamino)pyridine 26163-07-5 5G $66 2021-12-16 Buy
Frontier Specialty Chemicals B1391 5-Bromo-2-(dimethylamino)pyridine 97% 26163-07-5 25g $70 2021-12-16 Buy
Product number Packaging Price Buy
SYX00280 1g $87.5 Buy
B691533 1g $75 Buy
B691533 250mg $55 Buy
3H32-9-Y9 5G $66 Buy
B1391 25g $70 Buy

5-Bromo-2-(dimethylamino)pyridine Chemical Properties,Uses,Production

Synthesis

2-Amino-5-bromopyridine

1072-97-5

Iodomethane

74-88-4

5-Bromo-2-(dimethylamino)pyridine

26163-07-5

Step 64a: Synthesis of 5-bromo-N,N-dimethylpyridin-2-amine (Compound 0601-114) To a solution of 5-bromopyridin-2-amine (1.0 g, 5.8 mmol) in tetrahydrofuran (THF, 25 mL) was added sodium hydride (NaH, 60% dispersed in mineral oil, 0.92 g, 23.1 mmol) at 0°C and the reaction mixture was stirred for 10 minutes. Subsequently, iodomethane (CH3I, 1 mL, 16 mmol) was added and the reaction continued to be stirred for 2 hours. Upon completion of the reaction, the reaction was quenched by the addition of water (30 mL) and extracted with ethyl acetate (3 x 30 mL). The organic layers were combined, washed with saturated brine, dried over anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate, 10% v/v) to give the title compound (1.1 g, 94% yield) as a white solid. LCMS: 203 [M+2]+. 1H NMR (400 MHz, DMSO-d6) δ 2.99 (s, 6H), 6.61 (d, J = 9.6 Hz, 1H), 7.62 (dd, J = 9.2, 2.8 Hz, 1H), 8.12 (d, J = 2.4 Hz, 1H).

References

[1] Patent: WO2011/130628, 2011, A1. Location in patent: Page/Page column 206
[2] Patent: US2013/102595, 2013, A1. Location in patent: Paragraph 0485; 0486
[3] Patent: JP2015/187145, 2015, A. Location in patent: Paragraph 0418

53939-30-3
506-59-2
26163-07-5
Synthesis of 5-Bromo-2-(dimethylamino)pyridine from 5-Bromo-2-chloropyridine and Dimethylamine hydrochloride

5-Bromo-2-(dimethylamino)pyridine Suppliers

Global( 105)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Yushan Wanfang Biotechnology Co., Ltd.
+86-025-84918180 +86-18014482516 3552541679@qq.com China 997 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5906 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10821 58
career henan chemical co
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Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
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SIMAGCHEM CORP
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Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23541 58

View Lastest Price from 5-Bromo-2-(dimethylamino)pyridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5-Bromo-2-(dimethylamino)pyridine pictures 2025-06-25 5-Bromo-2-(dimethylamino)pyridine
26163-07-5
US $1.10 / g 1g 99.0% min 100 tons min Shaanxi Dideu Medichem Co. Ltd
5-Bromo-2-(dimethylamino)pyridine pictures 2021-07-13 5-Bromo-2-(dimethylamino)pyridine
26163-07-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
5-Bromo-2-(dimethylamino)pyridine pictures 2021-07-10 5-Bromo-2-(dimethylamino)pyridine
26163-07-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

5-Bromo-2-(dimethylamino)pyridine Spectrum

2-PyridinaMine, 5-broMo-N,N-diMethyl- 5-Bromo-N,N-dimethyl-2-pyridinamine 5-Bromo-N,N-dimethylpyridin-2-amine 5-bromo-2-(N,N-dimethyl-1-yl)pyridine (5-bromo-pyridin-2-yl)-dimethylamine 3-Bromo-6-dimethylaminopyridine 5-Bromo-2-(dimethylamino)pyridine ISO 9001:2015 REACH 26163-07-5 alkyl bromide Pyridine Amino Organohalides