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2,2,2-TRIFLUOROETHYL FORMATE

2,2,2-TRIFLUOROETHYL FORMATE Structure
2,2,2-TRIFLUOROETHYL FORMATE structure
CAS No.
32042-38-9
Chemical Name:
2,2,2-TRIFLUOROETHYL FORMATE
Synonyms
TFEF;HCOOCH2CF3;Ethyltrifluoroformate;2,2,2-TRIFLUOROETHYL FORMATE;2,2,2-Trifluoroethylformate97%;2,2,2-Trifluoroethyl methanoate;2,2,2-Trifluoro-ethanol formate;2,2,2-Trifluoroethyl formate 97%;2,2,2-TRIFLUOROETHYL FORMATE, 96+%;Ethanol,2,2,2-trifluoro-, 1-formate
CBNumber:
CB4115757
Molecular Formula:
C3H3F3O2
Molecular Weight:
128.05
MDL Number:
MFCD06797733
MOL File:
32042-38-9.mol
MSDS File:
SDS
Last updated:2026-04-10 10:27:13
Product description Number Pack Size Price
2,2,2-Trifluoroethyl formate 95% 669083 5g $74.1
2,2,2-Trifluoroethyl formate 95% 669083 1g $30
2,2,2-Trifluoroethyl Formate >95.0%(GC) T2586 1g $27
2,2,2-Trifluoroethyl Formate >95.0%(GC) T2586 5g $79
2,2,2-Trifluoroethyl Formate T774535 10g $80
More product size
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2,2,2-TRIFLUOROETHYL FORMATE Properties

Boiling point 60
Density 1.317 g/mL at 25 °C
refractive index n 20/D <1.001
Flash point 45 °C
storage temp. Sealed in dry,Room Temperature
solubility soluble in Chloroform, Ethyl Acetate
form clear liquid
Specific Gravity 1.36
color Colorless to Almost colorless
Henry's Law Constant 5.4×10-3 mol/(m3Pa) at 25℃, Burkholder et al. (2019)
InChI InChI=1S/C3H3F3O2/c4-3(5,6)1-8-2-7/h2H,1H2
InChIKey CAFROQYMUICGNO-UHFFFAOYSA-N
SMILES C(OC=O)C(F)(F)F
EPA Substance Registry System 2,2,2-Trifluoroethyl formate (32042-38-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H302-H319
Precautionary statements  P210-P233-P240-P241-P301+P312-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  F,Xn
Risk Statements  11-22-36
Safety Statements  26
RIDADR  UN 1993 3/PG 2
WGK Germany  3
Hazard Note  Harmful/Highly Flammable
HazardClass  3
PackingGroup  II
HS Code  29151300
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 2
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3
2 0

2,2,2-TRIFLUOROETHYL FORMATE price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 669083 2,2,2-Trifluoroethyl formate 95% 32042-38-9 5g $74.1 2026-03-19 Buy
Sigma-Aldrich 669083 2,2,2-Trifluoroethyl formate 95% 32042-38-9 1g $30 2023-06-20 Buy
TCI Chemical T2586 2,2,2-Trifluoroethyl Formate >95.0%(GC) 32042-38-9 1g $27 2026-03-19 Buy
TCI Chemical T2586 2,2,2-Trifluoroethyl Formate >95.0%(GC) 32042-38-9 5g $79 2026-03-19 Buy
TRC T774535 2,2,2-Trifluoroethyl Formate 32042-38-9 10g $80 2021-12-16 Buy
Product number Packaging Price Buy
669083 5g $74.1 Buy
669083 1g $30 Buy
T2586 1g $27 Buy
T2586 5g $79 Buy
T774535 10g $80 Buy

2,2,2-TRIFLUOROETHYL FORMATE Chemical Properties,Uses,Production

Chemical Properties

Clear slightly yellow liquid

Uses

Reagent for the formylation of alcohols and amines. Hydroxylamines provide high yields of the N-formylated product.

2,2,2-TRIFLUOROETHYL FORMATE Preparation Products And Raw materials

Raw materials

Preparation Products

2,2,2-TRIFLUOROETHYL FORMATE Suppliers

Global( 170)Suppliers
Supplier Tel Email Country ProdList Advantage
Allfluoro pharmaceutical co. ltd.
+86-400-0216110 +86-15958047586 sales@allfluoro.com China 11385 58
Hong Kong Pure Biotechnology LIMITED
+86-44-7899295894 +8613639316680 hannah_7@pure-chem.net China 221 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20125 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 13815 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29824 58
Jinan Carbotang Biotech Co.,Ltd. 		+8615866703830 figo.gao@foxmail.com China 8497 58
Xiamen AmoyChem Co., Ltd 		+86-86-5926051114 +8615060885618 sales@amoychem.com China 6369 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49977 58
Neostar United (Changzhou) Industrial Co., Ltd. 		+86-0519-85551759 +8613506123987 marketing1@neostarunited.com China 8828 58
Supplier Advantage
Allfluoro pharmaceutical co. ltd.
58
Hong Kong Pure Biotechnology LIMITED
58
Henan Fengda Chemical Co., Ltd 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Jinan Carbotang Biotech Co.,Ltd. 		58
Xiamen AmoyChem Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58
Neostar United (Changzhou) Industrial Co., Ltd. 		58

View Lastest Price from 2,2,2-TRIFLUOROETHYL FORMATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,2,2-Trifluoroethyl formate pictures 2025-09-25 2,2,2-Trifluoroethyl formate
32042-38-9
 US $30.00-0.90 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2,2,2-TRIFLUOROETHYL FORMATE pictures 2025-04-04 2,2,2-TRIFLUOROETHYL FORMATE
32042-38-9
 US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
Phenethyl isocyanate pictures 2019-07-06 Phenethyl isocyanate
32042-38-9
 US $1.00 / kg 1kg 99% Customized Career Henan Chemical Co

2,2,2-TRIFLUOROETHYL FORMATE Spectrum

2,2,2-TRIFLUOROETHYL FORMATE(32042-38-9)1HNMR2,2,2-TRIFLUOROETHYL FORMATE(32042-38-9)FT-IR

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TFEF formic acid 2,2,2-trifluoroethyl ester 2,2,2-TRIFLUOROETHYL FORMATE HCOOCH2CF3 2,2,2-Trifluoroethyl formate 97% 2,2,2-Trifluoroethylformate97% 2,2,2-TRIFLUOROETHYL FORMATE, 96+% Formic Acid 2,2,2-Trifluoroethyl Ester TFEF 2,2,2-Trifluoroethyl methanoate Ethanol,2,2,2-trifluoro-, 1-formate Lisinopril Impurity 12 (2,2,2-trifluoroethyl formate) Ethyltrifluoroformate 2,2,2-Trifluoro-ethanol formate 32042-38-9 34042-38-9 HCO2CH2CF3 CF3CH2OCOH Building Blocks Carbonyl Compounds C2 to C5 Esters Organic Building Blocks