Acenaphthylene, 5,6-dibromo-1,2-dihydro-
- CAS No.
- 19190-91-1
- Chemical Name:
- Acenaphthylene, 5,6-dibromo-1,2-dihydro-
- Synonyms
- 5,6-dibromo-1,2-dihydroacenaphthene;Acenaphthylene, 5,6-dibromo-1,2-dihydro-
- CBNumber:
- CB41244364
- Molecular Formula:
- C12H8Br2
- Molecular Weight:
- 312
- MDL Number:
- MFCD00191989
- MOL File:
- 19190-91-1.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
Acenaphthylene, 5,6-dibromo-1,2-dihydro- price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | FD67422 | 5,6-Dibromoacenaphthene | 19190-91-1 | 5g | $263.1 | 2026-06-04 | Buy |
| Biosynth | FD67422 | 5,6-Dibromoacenaphthene | 19190-91-1 | 10g | $426.6 | 2026-06-04 | Buy |
| Activate Scientific | AS93620 | 5,6-Dibromo-1,2-dihydroacenaphthylene 95% | 19190-91-1 | 1g | $46 | 2026-06-04 | Buy |
| Activate Scientific | AS93620 | 5,6-Dibromo-1,2-dihydroacenaphthylene 95% | 19190-91-1 | 5g | $205 | 2026-06-04 | Buy |
| Matrix Scientific | 063627 | 5,6-Dibromo-1,2-dihydroacenaphthylene | 19190-91-1 | 500.00mg | $115 | 2026-05-18 | Buy |
Acenaphthylene, 5,6-dibromo-1,2-dihydro- Chemical Properties, Uses, Production
Uses
5,6-Dibromoacenaphthene is a byproduct during the synthesis of 3,5,6-Tribromo-1,2-dihydroacenaphthylene (T771875), a derived from Acenaphthene (1,2-Dihydro Acenaphthylene) (D448330), which is a polycyclic aromatic hydrocarbons as carcinogenic agents.
Synthesis
83-32-9
19190-91-1
The general procedure for the synthesis of 5,6-dibromo-1,2-dihydroacenaphthene from acenaphthene was as follows: compound C (4,5-dibromonaphthalene) was prepared as follows: 37.01 g (240 mmol) of acenaphthene and 200 mL of N,N-dimethylformamide (DMF) were added to a 500 mL two-necked flask, and the reaction temperature was maintained at 13 °C with continuous stirring. 103.23 g (580 mmol) of N-bromosuccinimide (NBS) was dissolved in 200 mL of DMF and then slowly added dropwise to the DMF solution of acenaphthene through a dropping funnel, and the dropwise process was completed in about 5 hours. After the dropwise addition, the reaction mixture was continued to be stirred at room temperature overnight. After completion of the reaction, vacuum filtration was carried out to collect the solid residue. The residue obtained by filtration was mixed with 100 mL of ethanol and refluxed for 10 hours. The reaction mixture was cooled at room temperature and filtered again to obtain 24.3 g of off-white solid product in 32.45% yield.
References
[1] Patent: CN108409720, 2018, A. Location in patent: Paragraph 0066-0068
[2] Patent: CN108440424, 2018, A. Location in patent: Paragraph 0065-0067
[3] Journal of Organic Chemistry, 2011, vol. 76, # 15, p. 6383 - 6388
[4] Chinese Chemical Letters, 2014, vol. 25, # 10, p. 1399 - 1402
[5] European Journal of Inorganic Chemistry, 2016, vol. 2016, # 21, p. 3513 - 3523
Acenaphthylene, 5,6-dibromo-1,2-dihydro- Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Baiyin Chengze Chemical Technology Co., Ltd. | +86 943-8535351 13389336721 | sales@chengzechem.com | China | 300 | 58 |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
| Hunan HuaTeng Pharmaceutical Co., Ltd., | 400-8592883 15367835770 | sales@huatengsci.com | China | 5869 | 58 |
| Shanghai HuanChuan Industry Co.,Ltd. | 021-61478794 | sales@hcshhai.com | China | 9781 | 50 |
| Credit Asia Chemical Co., Ltd. | +86 (21) 61124340 | China | 9739 | 58 | |
| Zhengzhou Gecko Scientific Inc. | 0371-63336364 17344886665 | 209932355@qq.com | China | 535 | 55 |
| Quzhou AMK BioTech Co., Ltd | 0570-3081766 18357083060 | sales@qzamkbio.com | China | 1200 | 55 |
| Lanzhou Angeli Biochemical Technology Co., Ltd. | 0931-8235634 13321316780 | 1455540579@qq.com | China | 957 | 55 |
View Latest Price from Acenaphthylene, 5,6-dibromo-1,2-dihydro- manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2020-01-10 | Acenaphthylene, 5,6-dibromo-1,2-dihydro-
19190-91-1
|
$1.00 | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- Acenaphthylene, 5,6-dibromo-1,2-dihydro-
19190-91-1
- $1.00
- 99%
- Career Henan Chemical Co
