Dimethyl 2-bromo-2,6-pyridinedicarboxylate
- CAS No.
- 162102-79-6
- Chemical Name:
- Dimethyl 2-bromo-2,6-pyridinedicarboxylate
- Synonyms
- dimethyl 4-bromopyridine-2,6-dicarboxylate;Dimethyl 4-bromo-2,6-pyridinedicarboxylate;Dimethyl 2-bromo-2,6-pyridinedicarboxylate;2,6-diMethyl 4-broMopyridine-2,6-dicarboxylate;4-BroMo-pyridine-2,6-dicarboxylic acid diMethyl este;2,6-Pyridinedicarboxylic acid, 4-bromo-, 2,6-dimethyl ester
- CBNumber:
- CB41501595
- Molecular Formula:
- C9H8BrNO4
- Molecular Weight:
- 274.07
- MDL Number:
- MFCD09910266
- MOL File:
- 162102-79-6.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Dimethyl 4-bromopyridine-2,6-dicarboxylate | FD144342 | 100mg | $100 |
| Dimethyl 4-bromopyridine-2,6-dicarboxylate | FD144342 | 250mg | $150 |
| Dimethyl4-bromopyridine-2,6-dicarboxylate 95% | JK1018934 | 250mg | $225 |
| Dimethyl 4-bromopyridine-2,6-dicarboxylate | FD144342 | 2g | $650 |
| Dimethyl 4-bromopyridine-2,6-dicarboxylate | FD144342 | 500mg | $250 |
| More product size | |||
| Melting point | 176 °C |
|---|---|
| Boiling point | 369.6±37.0 °C(Predicted) |
| Density | 1.569±0.06 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| pka | -2.40±0.10(Predicted) |
| Appearance | White to light brown Solid |
| InChI | InChI=1S/C9H8BrNO4/c1-14-8(12)6-3-5(10)4-7(11-6)9(13)15-2/h3-4H,1-2H3 |
| InChIKey | WYROXHCDUWIUMW-UHFFFAOYSA-N |
| SMILES | C1(C(OC)=O)=NC(C(OC)=O)=CC(Br)=C1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H332-H335 |
| Precautionary statements | P280-P305+P351+P338-P310 |
| Safety Statements | 24/25 |
| HS Code | 29333990 |
Dimethyl 2-bromo-2,6-pyridinedicarboxylate price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth Carbosynth | FD144342 | Dimethyl 4-bromopyridine-2,6-dicarboxylate | 162102-79-6 | 100mg | $100 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD144342 | Dimethyl 4-bromopyridine-2,6-dicarboxylate | 162102-79-6 | 250mg | $150 | 2021-12-16 | Buy |
| Frontier Specialty Chemicals | JK1018934 | Dimethyl4-bromopyridine-2,6-dicarboxylate 95% | 162102-79-6 | 250mg | $225 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD144342 | Dimethyl 4-bromopyridine-2,6-dicarboxylate | 162102-79-6 | 2g | $650 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD144342 | Dimethyl 4-bromopyridine-2,6-dicarboxylate | 162102-79-6 | 500mg | $250 | 2021-12-16 | Buy |
Dimethyl 2-bromo-2,6-pyridinedicarboxylate Chemical Properties,Uses,Production
Synthesis
138-60-3
162102-79-6
The general procedure for the synthesis of pyridine 4-bromo-2,6-dicarboxylic acid methyl ester from 4-oxo-1,4-dihydro-2,6-pyridinedicarboxylic acid was as follows: compound 1 was prepared by a modified method from literature [29]. Tribenzoic acid monohydrate (2.20 g, 10.9 mmol) and phosphorus pentabromide (23.4 g, 54.3 mmol, 5 eq.) were heated to 90 °C under nitrogen protection and the reaction was maintained for 2 hours. Upon completion of the reaction, the dark red melt was cooled to room temperature and dissolved by addition of chloroform (25 mL). The reaction mixture was filtered and the filtrate was cooled in an ice bath (0 °C) and methanol (90 mL) was added slowly to promote crystallization. Crystallization was induced by scraping and the resulting crystalline solid was collected by vacuum filtration and dried under vacuum to afford compound 1 as a white crystalline solid (2.82 g, 86% yield).1H NMR (300 MHz, CDCl3) δ 8.45 (s, 2H), 4.02 (s, 6H).
References
[1] Journal of Inorganic Biochemistry, 2016, vol. 162, p. 253 - 262
[2] Organic Letters, 2011, vol. 13, # 3, p. 442 - 445
[3] Chemical Communications, 2012, vol. 48, # 80, p. 10025 - 10027
[4] Chemical Communications, 2014, vol. 50, # 68, p. 9665 - 9668
[5] Dalton Transactions, 2017, vol. 46, # 16, p. 5229 - 5239
Dimethyl 2-bromo-2,6-pyridinedicarboxylate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29796 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8830 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| Labnetwork lnc. | +86-27-50766799 +8618062016861 | contact@labnetwork.com | China | 19987 | 58 |
| Alfa Chemistry | +1-5166625404; | Info@alfa-chemistry.com | United States | 20405 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
View Lastest Price from Dimethyl 2-bromo-2,6-pyridinedicarboxylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-26 | Dimethyl 2-bromo-2,6-pyridinedicarboxylate
162102-79-6
|
US $9.80 / KG | 1g | ≥99% | 100kg | Career Henan Chemical Co |
-
- Dimethyl 2-bromo-2,6-pyridinedicarboxylate
162102-79-6
- US $9.80 / KG
- ≥99%
- Career Henan Chemical Co
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