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METHYLDICHLOROPHOSPHINE

CAS No.
676-83-5
Chemical Name:
METHYLDICHLOROPHOSPHINE
Synonyms
DICHLOROMETHYLPHOSPHINE;CH3PCl2;AURORA KA-1256;METHYLDICHLOROPHOSPHINE;Methyldichlorophosphane;Methylphosphinic dichloride;methylphosphonousdichloride;methyl-phosphonousdichlorid;Methylphosphorus dichloride;METHYLDICHLOROPHOSPHINE,97%
CBNumber:
CB4165626
Molecular Formula:
CH3Cl2P
Molecular Weight:
116.91
MDL Number:
MFCD00013616
MOL File:
676-83-5.mol
Last updated:2026-05-28 04:42:36
Product description Number Pack Size Price
Dichloromethylphosphine 96% 466840 15ml $1380
Methyldichlorophosphine, 97% 97% 15-3220 5g $258
Methyldichlorophosphine, 97% 15-3220 5g $257
Methyldichlorophosphine, 97% 15-3220 25g $866
Dichloromethylphosphine 97% MT-08643 100g $595
More product size

METHYLDICHLOROPHOSPHINE Properties

Melting point 81.5 °C
Boiling point 81-82 °C
Density 1.3
refractive index 1.4944-1.4964
Flash point 48 °C
storage temp. Flammables area
form Liquid
color Colorless
Water Solubility Reacts with water.
Sensitive Air & Moisture Sensitive
InChI 1S/CH3Cl2P/c1-4(2)3/h1H3
InChIKey CDPKWOKGVUHZFR-UHFFFAOYSA-N
SMILES CP(Cl)Cl
EPA Substance Registry System Methylphosphonous dichloride (676-83-5)
UNSPSC Code 12352101

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H252-H318-H226-H250-H301-H311-H314-H331
Precautionary statements  P210-P303+P361+P353-P305+P351+P338-P405-P422a-P501a-P222-P231-P261-P280-P301+P310-P422
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  T-F,T,F
Risk Statements  34-29-23/24/25-17-14-10
Safety Statements  8-45-43-36/37/39-33-26-16-23
RIDADR  2845
WGK Germany  3
TSCA  TSCA listed
HazardClass  6.1
PackingGroup  I
HS Code  29310099
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
Hazard Classifications Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Pyr. Liq. 1
Skin Corr. 1B
REACH Registrations Inactive
NFPA 704
4
3 0
W

METHYLDICHLOROPHOSPHINE price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 466840 Dichloromethylphosphine 96% 676-83-5 15ml $1380 2024-03-01 Buy
Strem Chemicals 15-3220 Methyldichlorophosphine, 97% 97% 676-83-5 5g $258 2026-04-30 Buy
Strem Chemicals 15-3220 Methyldichlorophosphine, 97% 676-83-5 5g $257 2024-03-01 Buy
Strem Chemicals 15-3220 Methyldichlorophosphine, 97% 676-83-5 25g $866 2021-12-16 Buy
AHH MT-08643 Dichloromethylphosphine 97% 100g $595 2026-05-26 Buy
Product number Packaging Price Buy
466840 15ml $1380 Buy
15-3220 5g $258 Buy
15-3220 5g $257 Buy
15-3220 25g $866 Buy
MT-08643 100g $595 Buy

METHYLDICHLOROPHOSPHINE Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Methyldichlorophosphine is used to prepare difunctional phosphonoamidite coupling reagents in nucleoside chemistry and "phospha-Wittig"reagents.

General Description

A colorless liquid with a pungent odor. Very toxic by inhalation. Denser than water.

Air & Water Reactions

Highly flammable. Forms fumes containing HCl in moist air. Can spontaneously ignite on contact with moist air. Reacts with water to form hydrochloric acid, reaction may be violent and ignite unreacted material.

Reactivity Profile

METHYLDICHLOROPHOSPHINE is water reactive. Incompatible with strong oxidizing agents, alcohols, bases (including amines). May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.

Fire Hazard

Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Safety Profile

A poison. A corrosive irritant to the skin, eyes, and mucous membranes. Flammable when exposed to heat or flame; can react vigorously with oxidtzing materials. When heated to decomposition it emits very toxic fumes of Cland POx.

METHYLDICHLOROPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 54)Suppliers
Supplier Tel Email Country ProdList Advantage
Guangzhou Xijia New Materials Co.,Ltd
+undefined13650882421 ebswax@163.com China 99 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21587 55
Shaanxi Dideu Medichem Co. Ltd
+86-29-81139210 +86-18192627656 1059@dideu.com China 3587 58
Xi'an MC Biotech, Co., Ltd.
029-89275612 +8618991951683 mcbio_sales@163.com China 2251 58
Aston Chemical
-- sales@astonchem.com United States 1634 58
VladaChem GmbH
+49-7246-3082843 info@vladachem.de Germany 1859 58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.
+8618950047208 ellena@amitychem.com China 43414 58
J & K SCIENTIFIC LTD. 18210857532; 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30123 84
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18207 66

View Lastest Price from METHYLDICHLOROPHOSPHINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYLDICHLOROPHOSPHINE pictures 2026-04-27 METHYLDICHLOROPHOSPHINE
676-83-5
1kg 99% 10000kg Guangzhou Xijia New Materials Co.,Ltd
Methyldichlorophosphine   pictures 2025-12-12 Methyldichlorophosphine
676-83-5
$1.00 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd
METHYLDICHLOROPHOSPHINE AURORA KA-1256 CH3PCl2 Methylphosphonous dichloride methyl-phosphonousdichlorid methylphosphonousdichloride Phosphonous dichloride, methyl- DICHLOROMETHYLPHOSPHINE 96% Methyldichlorophosphine,98+% Dichloromethylphosphine, tech., 90% Methylphosphinic dichloride Methylphosphinous dichloride Methylphosphorus dichloride METHYLDICHLOROPHOSPHINE,97% Dichloromethylphosphine,90%,tech. Methyldichlorophosphine, 99+% Dichloromethylphosphine: (Methylphosphonous dichloride) Methylphosphonous aciddichloride Phosphonous dichloride, P-methyl- Methyldichlorophosphane DICHLOROMETHYLPHOSPHINE 676-83-5 CH3Cl2P Phosphorus Compounds Phosphorus Precursors Catalysis and Inorganic Chemistry Ligand organophosphine halide