ChemicalBook >> CAS DataBase List >>METHYL ALPHA-BROMOPHENYLACETATE
METHYL ALPHA-BROMOPHENYLACETATE
- CAS No.
- 3042-81-7
- Chemical Name:
- METHYL ALPHA-BROMOPHENYLACETATE
- Synonyms
- Methyl α-Bromophenylacetate;Methyl α-altropyranoside;(2RS,3RS)-α-L-Lyxopyranoside;Methyl α-broMo acid;-Bromophenylacetate;-Cyclopentylmandelate;4-(Methoxy-d3)-αMethylbromophenylacetate
- CBNumber:
- CB4266950
- Molecular Formula:
- C9H9BrO2
- Molecular Weight:
- 229.07
- MDL Number:
- MFCD00013535
- MOL File:
- 3042-81-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-05-28 04:45:12
| Product description | Number | Pack Size | Price |
| Methyl α-bromophenylacetate 97% | 365270 | 5g | $67.4 |
| Methyl α-Bromophenylacetate >98.0%(GC) | M2038 | 5g | $43 |
| Methyl α-Bromophenylacetate >98.0%(GC) | M2038 | 25g | $138 |
| Methyl bromo(phenyl)acetate | 083244 | 1.00g | $47 |
| Methyl bromo(phenyl)acetate | 083244 | 10.00g | $210 |
| Boiling point | 113 °C3 mm Hg(lit.) |
|---|---|
| Density | 1.46 g/mL at 20 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| color | Colorless to Light orange to Yellow |
| BRN | 1102743 |
| InChI | 1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3 |
| InChIKey | NHFBYYMNJUMVOT-UHFFFAOYSA-N |
| SMILES | COC(=O)C(Br)c1ccccc1 |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 36/37/38-34 | |||||||||
| Safety Statements | 26-36/39-45-36/37/39 | |||||||||
| RIDADR | UN 3265 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29163990 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Skin Corr. 1B | |||||||||
| Limited Quantities | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
METHYL ALPHA-BROMOPHENYLACETATE price More Price(33)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 365270 | Methyl α-bromophenylacetate 97% | 3042-81-7 | 5g | $67.4 | 2026-04-30 | Buy |
| TCI Chemical | M2038 | Methyl α-Bromophenylacetate >98.0%(GC) | 3042-81-7 | 5g | $43 | 2026-04-30 | Buy |
| TCI Chemical | M2038 | Methyl α-Bromophenylacetate >98.0%(GC) | 3042-81-7 | 25g | $138 | 2026-04-30 | Buy |
| Matrix Scientific | 083244 | Methyl bromo(phenyl)acetate | 3042-81-7 | 1.00g | $47 | 2026-05-18 | Buy |
| Matrix Scientific | 083244 | Methyl bromo(phenyl)acetate | 3042-81-7 | 10.00g | $210 | 2026-05-18 | Buy |
METHYL ALPHA-BROMOPHENYLACETATE Chemical Properties,Uses,Production
Chemical Properties
Light yellow to yellow liquid
Uses
Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.
Synthesis Reference(s)
Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6
General Description
Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.
METHYL ALPHA-BROMOPHENYLACETATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL ALPHA-BROMOPHENYLACETATE Suppliers
Global( 120)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23541 | 58 |
| Unipharm pharmaceutical industry Co., Ltd | 536-8266195 +8613953676784 | lee@unipharm-sd.com | China | 1202 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
| Coresyn Pharmatech Co., Ltd. | +86-571-86626709 +86-18157142896 | cbc@coresyn.com | China | 9984 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18126 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| ZHEJIANG JIUZHOU CHEM CO., LTD | +86-0576225566889 +86-13454675544 | admin@jiuzhou-chem.com；jamie@jiuzhou-chem.com；alice@jiuzhou-chem.com | China | 12272 | 58 |
View Lastest Price from METHYL ALPHA-BROMOPHENYLACETATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-31 | METHYL ALPHA-BROMOPHENYLACETATE
3042-81-7
|
$1.00 | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- METHYL ALPHA-BROMOPHENYLACETATE
3042-81-7
- $1.00
- 99%
- Career Henan Chemical Co
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Methyl alpha-bromophenylacetate 97%
-Bromophenylacetate
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2-BROMO-2-PHENYLACETIC ACID METHYL ESTER
(±)-α-bromophenylacetic acid methyl ester
à-bromophenylacetic acid methyl ester
methyl à-bromophenylacetate
Phenylbromoacetic acid methyl ester
α-Bromobenzeneacetic acid methyl ester
Methylα-Bromophenylacetate>
Benzeneacetic acid, α-bromo-, methyl ester
α- Bromo-Phenyl Acetic Acid Methyl Ester
(±)-Methyl α-bromophenylacetate, CAS 3042-81-7
(±)-Methyl α-bromophenylacetate
Methyl α-Bromophenylacetate
3042-81-7
C6H5CHBrCOOCH3
C6H5CHBrCO2CH3
C8 to C9
Carbonyl Compounds
Building Blocks
Esters
Organic Building Blocks
Building Blocks
C8 to C9
Carbonyl Compounds
Chemical Synthesis
