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1,2,3-Trimethoxybenzene

CAS No.
634-36-6
Chemical Name:
1,2,3-Trimethoxybenzene
Synonyms
1 1,2,3-;Methylsyringol;1,2,3-TriMetho;dimethoxyanisole;1,2,3-Methoxybenzene;Tri-O-methylpyrogallol;1,2,3-Trimethoxybenzol;1,2,3-TRIMETHOXYBENZENE;1,2,3-trimethoxy-benzen;1,2,3-trimethyoxy benzene
CBNumber:
CB4332644
Molecular Formula:
C9H12O3
Molecular Weight:
168.19
MDL Number:
MFCD00008358
MOL File:
634-36-6.mol
MSDS File:
SDS
Last updated:2026-01-13 11:21:03
Product description Number Pack Size Price
1,2,3-Trimethoxybenzene 98% 137995 25g $65.6
1,2,3-Trimethoxybenzene >99.0%(GC) T1102 25g $47
1,2,3-Trimethoxybenzene >99.0%(GC) T1102 500g $551
1,2,3-Trimethoxybenzene F938 1kg $481
1,2,3-TRIMETHOXYBENZENE 95.00% FFG0002339 25G $1129.56
More product size

1,2,3-Trimethoxybenzene Properties

Melting point 43-47 °C (lit.)
Boiling point 241 °C (lit.)
Density 1.112 g/mL at 25 °C (lit.)
refractive index 1.5470 (estimate)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly)
form Powder
color White to dark beige
Water Solubility Insoluble in water.
BRN 1910422
InChI 1S/C9H12O3/c1-10-7-5-4-6-8(11-2)9(7)12-3/h4-6H,1-3H3
InChIKey CRUILBNAQILVHZ-UHFFFAOYSA-N
SMILES COc1cccc(OC)c1OC
LogP 1.530
CAS DataBase Reference 634-36-6(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII MRE1O894FG
NIST Chemistry Reference 1,2,3-Trimethoxybenzene(634-36-6)
EPA Substance Registry System Benzene, 1,2,3-trimethoxy- (634-36-6)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
Risk Statements  36/37/38
Safety Statements  22-24/25
WGK Germany  3
TSCA  TSCA listed
HS Code  29093090
Storage Class 11 - Combustible Solids
NFPA 704
1
0 0

1,2,3-Trimethoxybenzene price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 137995 1,2,3-Trimethoxybenzene 98% 634-36-6 25g $65.6 2026-03-19 Buy
TCI Chemical T1102 1,2,3-Trimethoxybenzene >99.0%(GC) 634-36-6 25g $47 2026-03-19 Buy
TCI Chemical T1102 1,2,3-Trimethoxybenzene >99.0%(GC) 634-36-6 500g $551 2026-03-19 Buy
AK Scientific F938 1,2,3-Trimethoxybenzene 634-36-6 1kg $481 2021-12-16 Buy
American Custom Chemicals Corporation FFG0002339 1,2,3-TRIMETHOXYBENZENE 95.00% 634-36-6 25G $1129.56 2021-12-16 Buy
Product number Packaging Price Buy
137995 25g $65.6 Buy
T1102 25g $47 Buy
T1102 500g $551 Buy
F938 1kg $481 Buy
FFG0002339 25G $1129.56 Buy

1,2,3-Trimethoxybenzene Chemical Properties,Uses,Production

Chemical Properties

WHITE TO DARK BEIGE POWDER

Uses

1,2,3-Trimethoxybenzene can be used for RSM-optimised slow pyrolysis of rice husk for bio-oil production.

Uses

1,2,3-Trimethoxybenzene was used to study the effect of solvent on photoinduced electron-transfer reactions.

Definition

ChEBI: A methoxybenzene that is benzene substituted by methoxy groups at positions 1, 2 and 3 respectively.

General Description

1,2,3-Trimethoxybenzene on condensation with 2,4-diamino-5-(hydroxymethyl)pyrimidine yields 2,4-diamino-5-(2,3,4-trimethoxybenzyl)pyrimidine.

Synthesis

Aqueous sodium hydroxide (40%,150 ml) is added dropwise during3-4 hr to a stirred mixture of pyrogallol (42 g,0.33 mole),sodiumhydrosulphite (10 g,0.057 mole),dimethyl sulphate (146 ml,194.60 g,1.54 mole) kept at 18-22°. Ice (1 kg) is then added and the reactionmixture left overnight. The separated solid is filtered and washed withwater. It is crystallised from methanol as colourless prisms. Yield 37.5 g(66.9%). M.p. 46-47°.Some more product (4 g, 7.1 %) is obtained byextraction of the mother liquor with ether (lit. m.p.46-47°).
1,2,3-Trimethoxybenzene  synthesis

Purification Methods

Sublime it under vacuum. [Beilstein 6 H 1081, 6 I 540, 6 II 1066, 6 III 6265, 6 IV 7329.]

Global( 411)Suppliers
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View Lastest Price from 1,2,3-Trimethoxybenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,2,3-Trimethoxybenzene pictures 2026-03-22 1,2,3-Trimethoxybenzene
634-36-6
US $10.00 / ASSAYS 1ASSAYS 99% 10 ton RongNa Biotechnology Co.,Ltd
1,2,3-Trimethoxybenzene pictures 2026-03-20 1,2,3-Trimethoxybenzene
634-36-6
US $1.00 / kg 1kg 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
1,2,3-Trimethoxybenzene pictures 2025-09-25 1,2,3-Trimethoxybenzene
634-36-6
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
1,2,3-Trimethoxybenzol Benzene, 1,2,3-trimethoxy- Benzene,1,2,3-trimethoxy- Methylsyringol Tri-O-methylpyrogallol 1,2,3-BENZENETRIOL TRIMETHYL ETHER 1,2,3-trimethyoxy benzene 1,2,3-TRIMETHOXYBENZENE 1,2,3-TRIHYDROXYBENZENE TRIMETHYL ETHER 1,2,3-Trimethoxybenzene(Pyrogallol trimethylether) 1 2 3-TRIMETHOXYBENZENE 97+% 1,2,3-Trimethoxybenzene98% PYROGALLOL TRIMETHYL ETHER PYROGALLIC ACID TRIMETHYL ETHER 1,2,3-trimethoxy-benzen Pyrogallol 1,2,3-trimethyl ether 1 1,2,3-TriMethoxybenzene 1,2,3-TRIMETHOXYBENZENE FOR SYNTHESIS 1,2,3-TriMethoxy Benzene (CAS NO 1,2,3-TriMethoxybenzene, 98% 25GR 1,2,3-Methoxybenzene 1,2,3-TriMethoxybenzene, 99.0% 1,2,3-TriMetho Trimetazidine Impurity 12 1 1,2,3- dimethoxyanisole 1,2,3-TRIMETHOXYBENZENE(CAS NO:634-36-6) 1,2,3-Trimethoxybenzene ISO 9001:2015 REACH 634-36-6 2439-47-2 Ethers Enzyme Substrates Drying Agents Enzymes, Inhibitors, and Substrates Organic Building Blocks Polyols Oxygen Compounds Substrates by Enzyme Special Applications Building Blocks Analytical Reagents Biochemicals and Reagents Analytical Chromatography Product Catalog BioChemical Benzene derivates Aromatic Hydrocarbons (substituted) & Derivatives