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2-Bromodibenzofuran

CAS No.
86-76-0
Chemical Name:
2-Bromodibenzofuran
Synonyms
2-BroModibenzo[b,d]furan;DBF-Brc;2-DCDF-A;NSC 1735;2-bromo-dibenzouran;2-BROMO-DIBENZOFURAN;Dibenzofuran, 2-broMo-;2-Bromodibenzofuran >2-MONOBROMODIBENZOFURAN;2-Bromo-dibenzofuran 98%
CBNumber:
CB4373496
Molecular Formula:
C12H7BrO
Molecular Weight:
247.09
MDL Number:
MFCD00092338
MOL File:
86-76-0.mol
MSDS File:
SDS
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
2-Bromodibenzofuran >98.0%(GC) B4459 1g $53
2-Bromodibenzofuran >98.0%(GC) B4459 5g $126
2-Bromodibenzofuran B683295 25g $1190
2-BROMODIBENZOFURAN 95.00% HCH0107700 10G $1247.05
2-Bromodibenzo[b,d]furan FB155737 1g $40
More product size

2-Bromodibenzofuran Properties

Melting point 121-122℃
Boiling point 344℃
Density 1.577
refractive index 1.5290 (estimate)
Flash point 162℃
storage temp. Sealed in dry,Room Temperature
solubility Soluble in hot methanol.
form Solid
color White to Off-White
InChI InChI=1S/C12H7BrO/c13-8-5-6-12-10(7-8)9-3-1-2-4-11(9)14-12/h1-7H
InChIKey CRJISNQTZDMKQD-UHFFFAOYSA-N
SMILES O1C2=CC=CC=C2C2=CC(Br)=CC=C12
FDA UNII C36TC73SME

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H319-H413
Precautionary statements  P264-P280i-P301+P312a-P305+P351+P338-P337+P313-P501a
Risk Statements  22-36-53
Safety Statements  26-36-60-61
HS Code  29329990
NFPA 704
1
2 0

2-Bromodibenzofuran price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B4459 2-Bromodibenzofuran >98.0%(GC) 86-76-0 1g $53 2026-03-19 Buy
TCI Chemical B4459 2-Bromodibenzofuran >98.0%(GC) 86-76-0 5g $126 2026-03-19 Buy
TRC B683295 2-Bromodibenzofuran 86-76-0 25g $1190 2021-12-16 Buy
American Custom Chemicals Corporation HCH0107700 2-BROMODIBENZOFURAN 95.00% 86-76-0 10G $1247.05 2021-12-16 Buy
Biosynth Carbosynth FB155737 2-Bromodibenzo[b,d]furan 86-76-0 1g $40 2021-12-16 Buy
Product number Packaging Price Buy
B4459 1g $53 Buy
B4459 5g $126 Buy
B683295 25g $1190 Buy
HCH0107700 10G $1247.05 Buy
FB155737 1g $40 Buy

2-Bromodibenzofuran Chemical Properties,Uses,Production

Description

2-Bromo-dibenzofuran is the bromo modified form of dibenzofuran, an aromatic compound consisting two benzene rings fused to a central furan ring. It can be used as a reagent in Friedel-Crafts acylation reactions.

Chemical Properties

off-white powder

Uses

2-Bromodibenzofuran is used as a reagent in Friedel-Crafts acylation reactions.

Synthesis

Dibenzofuran

132-64-9

2-Bromodibenzofuran

86-76-0

General procedure for the synthesis of 2-bromodibenzo[b,d]furan from dibenzofuran: Under argon protection, dibenzofuran (3.36 g, 20 mmol), N-bromosuccinimide (NBS, 3.92 g, 22 mmol), zirconium chloride (ZrCl4, 0.10 g, 0.44 mmol) and N,N-dimethylformamide (DMF, 40 mL) were added to a 100 mL Schlenk flask equipped with a magnetic stirrer. The reaction mixture was stirred at 70 °C for 18 hours. Upon completion of the reaction, the reaction solution was slowly poured into water (200 mL) to precipitate solids and the suspension was continued to be stirred for 30 minutes. The solids were collected by filtration and the filter cake was washed with hot water (100 mL, 90 °C). The solid on the filter paper was recovered and dried to give 4.1 g of 2-bromodibenzo[b,d]furan in 83% yield.

References

[1] Patent: JP2016/175849, 2016, A. Location in patent: Paragraph 0144
[2] Patent: JP2015/205860, 2015, A. Location in patent: Paragraph 0130-0131
[3] Journal of Organic Chemistry, 1997, vol. 62, # 5, p. 1348 - 1355
[4] Patent: KR2015/133998, 2015, A. Location in patent: Paragraph 0126-0129
[5] Patent: JP2018/90561, 2018, A. Location in patent: Paragraph 0075

132-64-9
86-76-0
Synthesis of 2-Bromodibenzofuran from Dibenzofuran
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View Lastest Price from 2-Bromodibenzofuran manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromodibenzofuran pictures 2025-09-25 2-Bromodibenzofuran
86-76-0
US $200.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Dibenzofuran, 2-bromo- pictures 2025-07-02 Dibenzofuran, 2-bromo-
86-76-0
US $0.00 / KG 1KG 98.00% 150KG /month Shanghai Daken Advanced Materials Co.,Ltd
2-Bromodibenzofuran pictures 2023-11-14 2-Bromodibenzofuran
86-76-0
US $0.00-0.00 / kg 1kg 99.9% 30000 Kg Hebei Xinsheng New Material Technology Co., LTD.
  • 2-Bromodibenzofuran pictures
  • 2-Bromodibenzofuran
    86-76-0
  • US $200.00-1.00 / KG
  • 99%, 99.5% Sublimated
  • Henan Fengda Chemical Co., Ltd
  • 2-Bromodibenzofuran pictures
  • 2-Bromodibenzofuran
    86-76-0
  • US $0.00-0.00 / kg
  • 99.9%
  • Hebei Xinsheng New Material Technology Co., LTD.

2-Bromodibenzofuran Spectrum

2-MONOBROMODIBENZOFURAN 2-BROMO-DIBENZOFURAN 2-DCDF-A 2-Bromo-dibenzofuran 98% DBF-Brc 2-bromo-dibenzouran 12-broMo-8-oxatricyclo[7.4.0.0^{2,7}]trideca-1(9),2,4,6,10,12-hexaene NSC 1735 Dibenzofuran, 2-broMo- 2-Bromodibenzofuran > TIANFU-CHEM 2-BROMO-DIBENZOFURAN 4,4,5,5-tetramethyl-2-(3-(6-phenyldibenzo[b,d]thiophen-4-yl)phenyl)-1,3,2-dioxaborolane 2-Bromodibenzofuran in methanol 2-BroModibenzo[b,d]furan 86-76-0 87-76-0 C12H7BrO