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(R)-VAPOL

CAS No.
147702-16-7
Chemical Name:
(R)-VAPOL
Synonyms
(S)-VAPOL;(R)-VAPOL;(R)-VAPOL 97%;(R)-VAPOL;(R)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(R) -2,2'--diphenyl-3,3 '- (4-phenanthrenol;(3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
CBNumber:
CB4450751
Molecular Formula:
C40H26O2
Molecular Weight:
538.63
MDL Number:
MFCD08459339
MOL File:
147702-16-7.mol
MSDS File:
SDS
Last updated:2026-05-28 03:29:12

(R)-VAPOL Properties

Melting point 225-229 °C
alpha -123.4° (c 1.0, THF)
Boiling point 712.2±60.0 °C(Predicted)
Density 1.286±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 8.37±0.30(Predicted)
form Powder
color white to pale yellow
optical activity [α]20/D -144°, c = 1 in chloroform
InChIKey UFYXKDMLGBKHIC-UHFFFAOYSA-N
SMILES Oc1c(c(cc2ccc3ccccc3c12)-c4ccccc4)-c5c(O)c6c(ccc7ccccc67)cc5-c8ccccc8
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H318-H335-H351
Precautionary statements  P201-P202-P280-P302+P352-P305+P351+P338-P308+P313
target organs Respiratory system
Hazard Codes  Xn
Risk Statements  37/38-40-41
Safety Statements  26-36/37/39
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Carc. 2
Eye Dam. 1
Skin Irrit. 2
STOT SE 3

(R)-VAPOL price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 675210 (R)-VAPOL 97% 147702-16-7 100mg $152 2026-04-30 Buy
Sigma-Aldrich 675210 (R)-VAPOL 97% 147702-16-7 500mg $726 2026-04-30 Buy
Strem Chemicals 08-1704 (3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (R)-VAPOL min.98% 147702-16-7 100mg $273 2026-04-30 Buy
Strem Chemicals 08-1704 (3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (R)-VAPOL min.98% 147702-16-7 500mg $1090 2026-04-30 Buy
aablocks AA001F1N (3R)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol ≥98%,≥99%(ee) 147702-16-7 25mg $63 2026-05-28 Buy
Product number Packaging Price Buy
675210 100mg $152 Buy
675210 500mg $726 Buy
08-1704 100mg $273 Buy
08-1704 500mg $1090 Buy
AA001F1N 25mg $63 Buy

(R)-VAPOL Chemical Properties, Uses, Production

Reaction

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 
Reactions of 147702-16-7

Uses

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(R)-VAPOL Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-VAPOL Suppliers

Global Suppliers ( 33)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 7909 65
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 4501 58
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
Greenherbs Science and Technology Development Co., Ltd. 010-61136123 pub02@greenherbs.com.cn China 4045 58
Aikon International Limited 025-58859352 13913916777 dt3@aikonchem.com China 15490 58

(R)-VAPOL Spectrum

(R)-VAPOL 97% (R)-VAPOL,99%e.e. (S)-2,2'-DIPHENYL-(4-BIPHENANTHROL) (R)-VAPOL (S)-VAPOL (R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL) (3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(R)-VAPOL (3R)-(-)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (R)-VAPOL (R) -2,2'--diphenyl-3,3 '- (4-phenanthrenol (3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol 3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, (3R)- (3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol (R)-VAPOL 147702-16-7 C40H26O212CH2Cl2 BINOL Series Chiral Oxygen