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2-Naphthaldehyde

CAS No.
66-99-9
Chemical Name:
2-Naphthaldehyde
Synonyms
naphthalene-2-carbaldehyde;2-Naphthalenecarboxaldehyde;2-Formylnaphthalene;2-NAPHTHALENECARBALDEHYDE;2-NaphthaL;2-Naphthakdehyde;B-NAPHTHALDEHYDE;2-NAPHTHALDEHYDE;Naphthaldehyde,97%;2-NAPHTHYLALDEHYDE
CBNumber:
CB4496391
Molecular Formula:
C11H8O
Molecular Weight:
156.18
MDL Number:
MFCD00004094
MOL File:
66-99-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 04:40:44
Product description Number Pack Size Price
2-Naphthaldehyde 98% N206 5G $53.6
2-Naphthaldehyde 98% N206 25g $136
2-Naphthaldehyde 98% N206 100g $528
2-Naphthaldehyde >98.0%(GC) N0003 5g $39
2-Naphthaldehyde >98.0%(GC) N0003 25g $150
More product size

2-Naphthaldehyde Properties

Melting point 58-61 °C (lit.)
Boiling point 160 °C (19 mmHg)
Density 1.6211
refractive index 1.6211 (estimate)
Flash point 160°C/19mm
storage temp. -20°C
solubility Chloroform, Methanol (Sparingly)
form Powder or Chunks
color Off-white to yellow or light beige
Water Solubility Soluble in hot water.
FreezingPoint 1.0755
Sensitive Air Sensitive
BRN 507750
Henry's Law Constant 6.0×101 mol/(m3Pa) at 25℃, Abraham and Jr. (2019)
InChI 1S/C11H8O/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-8H
InChIKey PJKVFARRVXDXAD-UHFFFAOYSA-N
SMILES [H]C(=O)c1ccc2ccccc2c1
CAS DataBase Reference 66-99-9(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII GZX30H50DE
NIST Chemistry Reference 2-Naphthalenecarboxaldehyde(66-99-9)
EPA Substance Registry System 2-Naphthalenecarboxaldehyde (66-99-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Skull and Crossbones (GHS06)
GHS07,GHS06
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H301-H335
Precautionary statements  P280a-P301+P310a-P305+P351+P338-P405-P501a-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xn,Xi
Risk Statements  36/37/38-22
Safety Statements  22-24/25-36-26
RIDADR  UN 3335
WGK Germany  3
RTECS  QJ0190010
10-23
HS Code  29122900
Storage Class 11 - Combustible Solids
NFPA 704
1
2 0

2-Naphthaldehyde price More Price(73)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich N206 2-Naphthaldehyde 98% 66-99-9 5G $53.6 2026-04-30 Buy
Sigma-Aldrich N206 2-Naphthaldehyde 98% 66-99-9 25g $136 2026-04-30 Buy
Sigma-Aldrich N206 2-Naphthaldehyde 98% 66-99-9 100g $528 2026-04-30 Buy
TCI Chemical N0003 2-Naphthaldehyde >98.0%(GC) 66-99-9 5g $39 2026-04-30 Buy
TCI Chemical N0003 2-Naphthaldehyde >98.0%(GC) 66-99-9 25g $150 2026-04-30 Buy
Product number Packaging Price Buy
N206 5G $53.6 Buy
N206 25g $136 Buy
N206 100g $528 Buy
N0003 5g $39 Buy
N0003 25g $150 Buy

2-Naphthaldehyde Chemical Properties,Uses,Production

Chemical Properties

Pink crystalline

Uses

2-Naphthaldehyde aids in stereo-selective formation of bicyclo 2-siloxy-2-alkoxyoxetanes. It is also used as catalytic agent and petrochemical additive.

Uses

2-Naphthaldehyde can be used as a reactant:

  • In proline catalyzed aldol reaction.
  • In asymmetric three-component Mannich reaction.
  • For the synthesis of Hantzsch 1,4-dihydropyridines.13}
  • Asymmetric benzoin condensation reaction.
  • For the synthesis of pyrazolo[1,2b]phthalazinediones.
  • For the synthesis C60 by flash vacuum pyrolysis.

Definition

ChEBI: A naphthaldehyde that is naphthalene substituted by a formyl group at position 2.

Synthesis Reference(s)

Synthesis, p. 470, 1996 DOI: 10.1055/s-1996-4246

Purification Methods

Distil 2-naphthaldehyde with steam then crystallise it from water or EtOH. [Beilstein 7 IV 1288.]

939-26-4
66-99-9
Synthesis of 2-Naphthaldehyde from 2-(Bromomethyl)naphthalene
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View Lastest Price from 2-Naphthaldehyde manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Naphthaldehyde pictures 2026-06-07 2-Naphthaldehyde
66-99-9
$70.00-110.00 1kg 99% 5000 HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
2-Naphthaldehyde pictures 2026-06-05 2-Naphthaldehyde
66-99-9
1kg 98%min 1000kg WUHAN FORTUNA CHEMICAL CO., LTD
2-Naphthaldehyde pictures 2026-05-28 2-Naphthaldehyde
66-99-9
$2.00-5.00 1KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
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  • 2-Naphthaldehyde
    66-99-9
  • $70.00-110.00
  • 99%
  • HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
2-Naphthakdehyde 2-naphthaldehyde (beta) Naphthaldehyde,97% 2-Naphthaldehyde,98% B-NAPHTHALDEHYDE 2-NAPHTHALDEHYDE 98% 2-Naphthaldehyde, 98% 25GR 2-Naphthaldehyde, 98% 5GR 2-Naphthaldehyde (8CI) 2-Naphthalenealdehyde 2- naphthaleneforMaldehyde BETA-NAPHTHALDEHYDE N**2-Naphthaldehyde 2-NAPHTHALDEHYDE 2-NAPHTHYLALDEHYDE 2-Formylanaphthalene 2-Formylnaphthalene beta-Formylnaphthalene beta-Naphthylaldehyde beta-Naphthylcarboxaldehyde NAPHTHALDEHYDE(2-) NAPHTHALENE-B-ALDEHYDE 2-NaphthaL 2-Naphthaldehyde> 2-Naphthaldehyde, 98%, for synthesis 2-Naphthalenecarboxaldehyde (9CI, ACI) Chlorobutanol Impurity?6 2-NAPHTHALENECARBALDEHYDE 2-Naphthalenecarboxaldehyde naphthalene-2-carbaldehyde 66-99-9 C11H8O ALDEHYDE C10 to C21 Carbonyl Compounds Building Blocks Aldehydes Organic Building Blocks Naphthalene series Pyridines