2-Naphthaldehyde
- CAS No.
- 66-99-9
- Chemical Name:
- 2-Naphthaldehyde
- Synonyms
- naphthalene-2-carbaldehyde;2-Naphthalenecarboxaldehyde;2-Formylnaphthalene;2-NAPHTHALENECARBALDEHYDE;2-NaphthaL;2-Naphthakdehyde;B-NAPHTHALDEHYDE;2-NAPHTHALDEHYDE;Naphthaldehyde,97%;2-NAPHTHYLALDEHYDE
- CBNumber:
- CB4496391
- Molecular Formula:
- C11H8O
- Molecular Weight:
- 156.18
- MDL Number:
- MFCD00004094
- MOL File:
- 66-99-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 2-Naphthaldehyde 98% | N206 | 5G | $53.6 |
| 2-Naphthaldehyde 98% | N206 | 25g | $136 |
| 2-Naphthaldehyde 98% | N206 | 100g | $528 |
| 2-Naphthaldehyde >98.0%(GC) | N0003 | 5g | $39 |
| 2-Naphthaldehyde >98.0%(GC) | N0003 | 25g | $150 |
| More product size | |||
| Melting point | 58-61 °C (lit.) |
|---|---|
| Boiling point | 160 °C (19 mmHg) |
| Density | 1.6211 |
| refractive index | 1.6211 (estimate) |
| Flash point | 160°C/19mm |
| storage temp. | -20°C |
| solubility | Chloroform, Methanol (Sparingly) |
| form | Powder or Chunks |
| color | Off-white to yellow or light beige |
| Water Solubility | Soluble in hot water. |
| FreezingPoint | 1.0755 |
| Sensitive | Air Sensitive |
| BRN | 507750 |
| Henry's Law Constant | 6.0×101 mol/(m3Pa) at 25℃, Abraham and Jr. (2019) |
| InChI | 1S/C11H8O/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-8H |
| InChIKey | PJKVFARRVXDXAD-UHFFFAOYSA-N |
| SMILES | [H]C(=O)c1ccc2ccccc2c1 |
| CAS DataBase Reference | 66-99-9(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | GZX30H50DE |
| NIST Chemistry Reference | 2-Naphthalenecarboxaldehyde(66-99-9) |
| EPA Substance Registry System | 2-Naphthalenecarboxaldehyde (66-99-9) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS07,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H301-H335 | |||||||||
| Precautionary statements | P280a-P301+P310a-P305+P351+P338-P405-P501a-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501 | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 36/37/38-22 | |||||||||
| Safety Statements | 22-24/25-36-26 | |||||||||
| RIDADR | UN 3335 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | QJ0190010 | |||||||||
| F | 10-23 | |||||||||
| HS Code | 29122900 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
2-Naphthaldehyde price More Price(73)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | N206 | 2-Naphthaldehyde 98% | 66-99-9 | 5G | $53.6 | 2026-04-30 | Buy |
| Sigma-Aldrich | N206 | 2-Naphthaldehyde 98% | 66-99-9 | 25g | $136 | 2026-04-30 | Buy |
| Sigma-Aldrich | N206 | 2-Naphthaldehyde 98% | 66-99-9 | 100g | $528 | 2026-04-30 | Buy |
| TCI Chemical | N0003 | 2-Naphthaldehyde >98.0%(GC) | 66-99-9 | 5g | $39 | 2026-04-30 | Buy |
| TCI Chemical | N0003 | 2-Naphthaldehyde >98.0%(GC) | 66-99-9 | 25g | $150 | 2026-04-30 | Buy |
2-Naphthaldehyde Chemical Properties,Uses,Production
Chemical Properties
Pink crystalline
Uses
2-Naphthaldehyde aids in stereo-selective formation of bicyclo 2-siloxy-2-alkoxyoxetanes. It is also used as catalytic agent and petrochemical additive.
Uses
2-Naphthaldehyde can be used as a reactant:
- In proline catalyzed aldol reaction.
- In asymmetric three-component Mannich reaction.
- For the synthesis of Hantzsch 1,4-dihydropyridines.13}
- Asymmetric benzoin condensation reaction.
- For the synthesis of pyrazolo[1,2b]phthalazinediones.
- For the synthesis C60 by flash vacuum pyrolysis.
Definition
ChEBI: A naphthaldehyde that is naphthalene substituted by a formyl group at position 2.
Synthesis Reference(s)
Synthesis, p. 470, 1996 DOI: 10.1055/s-1996-4246
Purification Methods
Distil 2-naphthaldehyde with steam then crystallise it from water or EtOH. [Beilstein 7 IV 1288.]
2-Naphthaldehyde Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shandong Xingshun New Material Co., Ltd. | +86-0519-86461196 | gxx@xingshengtech.com | China | 552 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8618531123677 | faithe@yan-xi.com | China | 5853 | 58 |
| Zhejiang Free Trade Zone Violet Trade Co., Ltd. | +8618768051816; +8615858061377 | jenny@zjviolettech.com | China | 113 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-86-13131129325 +8613131129325 | sales1@chuanghaibio.com | China | 5228 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18126 | 58 |
| HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | +86-15350851019; +8615350851019 | admin@86-ss.com | China | 999 | 58 |
| Hebei Zhuanglai Chemical Trading Co Ltd | +86-16264648883 | niki@zlchemi.com | China | 7245 | 58 |
| Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13901 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21587 | 55 |
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View Lastest Price from 2-Naphthaldehyde manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-06-07 | 2-Naphthaldehyde
66-99-9
|
$70.00-110.00 | 1kg | 99% | 5000 | HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | |
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2026-06-05 | 2-Naphthaldehyde
66-99-9
|
1kg | 98%min | 1000kg | WUHAN FORTUNA CHEMICAL CO., LTD | ||
![]() |
2026-05-28 | 2-Naphthaldehyde
66-99-9
|
$2.00-5.00 | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD |
-

- 2-Naphthaldehyde
66-99-9
- $70.00-110.00
- 99%
- HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
-

- 2-Naphthaldehyde
66-99-9
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-

- 2-Naphthaldehyde
66-99-9
- $2.00-5.00
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
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