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Diethylene glycol diethyl ether

CAS No.
112-36-7
Chemical Name:
Diethylene glycol diethyl ether
Synonyms
DIETHYLENE GLYCOL DIETHYL ETHER;DIETHYL CARBITOL;Diethyl carbito;BIS(2-ETHOXYETHYL) ETHER;Diethyldigol;ethyldiglyme;Ethyl diglyme;DIETHYLDIGLYCOL;DIETHOXYDIGLYCOL;DIETHYL CARBITOL(R)
CBNumber:
CB4669548
Molecular Formula:
C8H18O3
Molecular Weight:
162.23
MDL Number:
MFCD00009254
MOL File:
112-36-7.mol
MSDS File:
SDS
Last updated:2026-01-13 11:21:18
Product description Number Pack Size Price
Diethylene glycol diethyl ether reagent grade, ≥98% E4658 1l $249
Diethylene glycol diethyl ether reagent grade, ≥98% E4658 18L $2030
Diethylene glycol diethyl ether for synthesis 8.02932 1L $166
Diethylene glycol diethyl ether for HPLC, ≥99% 308277 1l $238
Diethylene glycol diethyl ether for synthesis 8.02932 250ML $53.1
More product size

Diethylene glycol diethyl ether Properties

Melting point -44.3 °C
Boiling point 180-190 °C(lit.)
Density 0.909 g/mL at 25 °C(lit.)
vapor density 5.6 (vs air)
vapor pressure 0.5 mm Hg ( 20 °C)
refractive index n20/D 1.412(lit.)
Flash point 160 °F
storage temp. Store below +30°C.
solubility Chloroform (Sparingly), Methanol (Slightly)
form Liquid
color Clear
Relative polarity 3.9
explosive limit 6.2%
Water Solubility SOLUBLE
λmax λ: 260 nm Amax: 1.00
λ: 300 nm Amax: 0.10
λ: 320 nm Amax: 0.04
λ: 350-400 nm Amax: 0.01
Merck 14,3118
BRN 1699259
Dielectric constant 5.7000000000000002
Stability Stable. Combustible. Incompatible with strong oxidizing agents. May form peroxides on exposure to air - test for their presence before heating.
Cosmetics Ingredients Functions SOLVENT
InChI 1S/C8H18O3/c1-3-9-5-7-11-8-6-10-4-2/h3-8H2,1-2H3
InChIKey RRQYJINTUHWNHW-UHFFFAOYSA-N
SMILES CCOCCOCCOCC
LogP 0.39 at 25℃
CAS DataBase Reference 112-36-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII ZH086O935Z
NIST Chemistry Reference Ethane, 1,1'-oxybis[2-ethoxy-(112-36-7)
EPA Substance Registry System Diethylene glycol diethyl ether (112-36-7)
UNSPSC Code 12352112
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315
Precautionary statements  P264-P280-P302+P352-P332+P313-P362+P364
Hazard Codes  Xi
Risk Statements  36-19
Safety Statements  26-36
WGK Germany  2
RTECS  KN3160000
Autoignition Temperature 174 °C
TSCA  TSCA listed
HS Code  29091900
Storage Class 10 - Combustible liquids
Hazard Classifications Skin Irrit. 2
Hazardous Substances Data 112-36-7(Hazardous Substances Data)
Toxicity LD50 orally in rats: 4.97 g/kg (Smyth)
NFPA 704
2
1 0

Diethylene glycol diethyl ether price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich E4658 Diethylene glycol diethyl ether reagent grade, ≥98% 112-36-7 1l $249 2025-07-31 Buy
Sigma-Aldrich E4658 Diethylene glycol diethyl ether reagent grade, ≥98% 112-36-7 18L $2030 2025-07-31 Buy
Sigma-Aldrich 8.02932 Diethylene glycol diethyl ether for synthesis 112-36-7 1L $166 2025-07-31 Buy
Sigma-Aldrich 308277 Diethylene glycol diethyl ether for HPLC, ≥99% 112-36-7 1l $238 2025-07-31 Buy
Sigma-Aldrich 8.02932 Diethylene glycol diethyl ether for synthesis 112-36-7 250ML $53.1 2023-06-20 Buy
Product number Packaging Price Buy
E4658 1l $249 Buy
E4658 18L $2030 Buy
8.02932 1L $166 Buy
308277 1l $238 Buy
8.02932 250ML $53.1 Buy

Diethylene glycol diethyl ether Chemical Properties,Uses,Production

Uses

Diethylene Glycol Diethyl Ether is a very useful organic solvent. It has a high boiling point and has been used to study the activities of enzymes in aqueous organic mixtures.

Description

Diethylene glycol diethyl ether, or 2-Ethoxyethyl ether, is an organic solvent used to study the activities of enzymes in aqueous organic mixtures. Diethylene glycol diethyl ether is a solvent for reactions performed at higher temperatures. It is involved in the preparation of nitrocellulose, resins, and adhesives. It is a scrubbing medium to absorb carbonyl sulfide (COS), an impurity in petroleum refineries. It could be used as an absorbent for CO2. This absorbent has a high boiling point (462 K, in SciFinder), indicating that energy for absorbent regeneration and loss were saved. In addition, this absorbent is chemically and thermally stable, non-corrosive, and has low density and viscosity. It is rich in philic-CO2 groups, which makes Diethylene glycol diethyl ether more effective for CO2 capture. Li et al. found that carbonyl and ether groups in the absorbents improved CO2 solubility, and the carbonyl group was more effective than the ether group[1].

Chemical Properties

colourless liquid

Uses

Solvent; high boiling reaction medium.

Definition

ChEBI: A polyether that consists of undecane in which the carbon atoms at positions 3, 6 and 9 are replaced by oxygen atoms.

Preparation

2-Ethoxyethyl ether could be synthesized by reacting 1, 4-dioxane with diethyl ether. ZSM-5-type zeolite was used as the catalyst. This reaction is performed in an autoclave.
2-Ethoxyethyl ether

General Description

Diethylene glycol diethyl ether is a clear colorless viscous liquid.

Air & Water Reactions

Highly flammable. May be sensitive to prolonged exposure to air. Can form explosive peroxides. Vapor-air mixtures are explosive above the flash point. Water soluble.

Reactivity Profile

2-Ethoxyethyl ether is incompatible with strong acids. 2-Ethoxyethyl ether is also incompatible with strong oxidizing agents.

Fire Hazard

2-Ethoxyethyl ether is combustible.

Safety Profile

Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. An eye irritant. Flammable when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

Purification Methods

Dry the ether with MgSO4, then CaH2 or LiAlH4, under N2. If sodium is used, the ether should be redistilled alone to remove any products which may be formed by the action of sodium on the ether. As a preliminary purification, the crude ether (2L) can be refluxed for 12hours with 25mL of conc HCl in 200mL of water, under reduced pressure, with slow passage of N2 to remove aldehydes and other volatile substances. After cooling, add sufficient solid KOH pellets (slowly and with shaking until no more dissolves) to give two liquid phases. The upper of these is decanted, dried with fresh KOH pellets, decanted, then refluxed over, and distilled from sodium. It can be passed through (alkaline) alumina prior to purification. [Beilstein 1 IV 2394.]

References

[1] Yun Li. “Solubilities of CO2 capture absorbents 2-ethoxyethyl ether, 2-butoxyethyl acetate and 2-(2-ethoxyethoxy)ethyl acetate.” Fluid Phase Equilibria 370 (2014): Pages 1-7.

123-91-1
60-29-7
112-36-7
Synthesis of Diethylene glycol diethyl ether from 1,4-Dioxane and Diethyl ether

Diethylene glycol diethyl ether Preparation Products And Raw materials

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View Lastest Price from Diethylene glycol diethyl ether manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diethylene glycol diethyl ether pictures 2026-02-28 Diethylene glycol diethyl ether
112-36-7
US $0.00 / kg 1000kg 99 20mt Yancheng Green Chemicals Co.,Ltd
2-Ethoxyethyl ether pictures 2026-02-28 2-Ethoxyethyl ether
112-36-7
US $0.00 / KG 1000KG 99 20000 Gansu Jinyuantai New Material Co., Ltd.
2-ETHOXYETHYL ETHER pictures 2026-02-28 2-ETHOXYETHYL ETHER
112-36-7
US $1330.00 / kg 900kg 99% 10 tons Anhui Royal Chemical Co., Ltd.
1,1’-oxybis(2-ethoxy-ethan diethyldiethyleneglycol Diethyldigol diethyleneglycoldlethylether Diethylether diethylenglykolu diethyletherdiethylenglykolu Ethane, 1,1'-oxybis*2-ethoxy- Ethane,1,1’-oxybis[2-ethoxy- Ethanol, 2,2'-oxybis-, diethyl ether Ether, bis(2-ethoxyethyl) ether,bis(2-ethoxyethyl) Ethyl diglyme Diethylene glycol diethyl ether, HPLC Grade, 99+% Bis(2-ethoxyethyl) ether: (Diethyl carbitol) 2-Ethoxyethyl ether, Bis(2-ethoxyethyl) ether, Diethyldiglycol 2-Ethoxyethyl ether, 98+%, extra pure 2-Ethoxyethyl ether, extra pure Bis(2-Ethoxyethyl)Ether (Diethylene Glycol Diethyl Ether) DIETHYLENE GLYCOL DIETHYL ERHER(DEDE) DIETHYLENE GLYCOL DIETHYL ETHER FOR SYNT Diethylene glycol diethyl ether for HPLC, >=99% Diethylene glycol diethyl ether reagent grade, >=98% Diethylene glycol diethyl ether Vetec(TM) reagent grade, 98+ % 1,1’-oxybis[2-ethoxy-ethan 1,1’-oxybis[2-ethoxy-Ethane 1-Ethoxy-2-(2-ethoxyethoxy)ethane 1-ethoxy-2-(2-ethoxy-ethoxy)-ethane 1-ethoxy-2-(2-ethoxyethoxy)-ethane 1-Ethoxy-2-(beta-ethoxyethoxy)ethane 2-(2-Ethoxyethoxy)-1-ethoxyethane 2,2’-oxybis-ethanodiethylether 3,6,9-Trioxaundecane 3-Oxapentane-1,5-dioldiethylether Bis(2,2-diethoxyethyl) ether Bis(ethoxyethyl)ether Diethyldiethylene glycol ethyldiglyme 2,2'-oxybisethanol diethyl ether DI(ETHYLENE GLYCOL) DIETHYL ETHER, 98+% DI(ETHYLENE GLYCOL) DIETHYL ETHER, 99+%, HPLC GRADE DiethyleneGlycolDiethylEtherC8H18O3 DiethyleneglycolDiethylEther,~99% DiethyleneGlycolDiethylEther,Certified 2-Ethoxyethyl ether, extra pure, 98+% DIETHOXYDIGLYCOL DIETHYLENE GLYCOL DIETHYL ETHER HALOGEN FREE diethylene glycol diethyl ether, hplc grade 1-ethoxy-2-β-ethoxy-ethoxyethane Diethylene Glycol Diethyl Ether 〔Bis(2-ethoxyethyl) Ether〕 BIS(2-ETHOXYETHYL) ETHER DIETHYL CARBITOL DIETHYL CARBITOL(R) DIETHYLDIGLYCOL DIETHYLENE GLYCOL DIETHYL DIETHYLENE GLYCOL DIETHYL ETHER Diethyl Carbitol (Union Carbide) 2-Ethoxyethyl ether 99% Diethyl carbito