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Methyl 4-hydroxy-3-methylbenzoate

CAS No.
42113-13-3
Chemical Name:
Methyl 4-hydroxy-3-methylbenzoate
Synonyms
methyl 4-hydoxy-3-methylbenzoate;METHYL 4-HYDROXY-3-METHYLBENZOATE;Methyl 3-methyl-4-hydroxybenzoate;Methyl 4-hydroxy-3-Methylbenzoic acid;3-methyl-4-hydroxybenzoic acid methyl ester
CBNumber:
CB51010654
Molecular Formula:
C9H10O3
Molecular Weight:
166.17
MDL Number:
MFCD06203848
MOL File:
42113-13-3.mol
MSDS File:
SDS
Last updated:2025-09-25 17:15:13
Product description Number Pack Size Price
Methyl4-hydroxy-3-methylbenzoate M323510 500mg $65
Methyl 4-hydroxy-3-methylbenzoate 063755 500mg $16
Methyl4-hydroxy-3-methylbenzoate 98% OR911863 1g $124
Methyl4-hydroxy-3-methylbenzoate J92403 25g $225
Methyl4-hydroxy-3-methylbenzoate 98% OR911863 10g $363
More product size

Methyl 4-hydroxy-3-methylbenzoate Properties

Melting point 124-125℃
Boiling point 282.9±20.0 °C(Predicted)
Density 1.169±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
pka 8.70±0.18(Predicted)
Appearance Light brown to off-white Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P301+P312-P302+P352-P304+P340-P305+P351+P338
HS Code  2918290090

Methyl 4-hydroxy-3-methylbenzoate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M323510 Methyl4-hydroxy-3-methylbenzoate 42113-13-3 500mg $65 2021-12-16 Buy
Matrix Scientific 063755 Methyl 4-hydroxy-3-methylbenzoate 42113-13-3 500mg $16 2021-12-16 Buy
Apolloscientific OR911863 Methyl4-hydroxy-3-methylbenzoate 98% 42113-13-3 1g $124 2021-12-16 Buy
AK Scientific J92403 Methyl4-hydroxy-3-methylbenzoate 42113-13-3 25g $225 2021-12-16 Buy
Apolloscientific OR911863 Methyl4-hydroxy-3-methylbenzoate 98% 42113-13-3 10g $363 2021-12-16 Buy
Product number Packaging Price Buy
M323510 500mg $65 Buy
063755 500mg $16 Buy
OR911863 1g $124 Buy
J92403 25g $225 Buy
OR911863 10g $363 Buy

Methyl 4-hydroxy-3-methylbenzoate Chemical Properties,Uses,Production

Synthesis

Methanol

67-56-1

4-HYDROXY-3-METHYLBENZOIC ACID

499-76-3

Methyl 4-hydroxy-3-methylbenzoate

42113-13-3

General procedure for the synthesis of methyl 3-methyl-4-hydroxybenzoate from methanol and 4-hydroxy-3-methylbenzoic acid: 4-hydroxy-3-methylbenzoic acid (342 g, 2.24 mol) was dissolved in methanol (3.5 L), and the solution was bubbled with hydrogen chloride gas (HCl) for 5 min. Subsequently, the reaction mixture was stirred at room temperature for 12 hours. Upon completion of the reaction, the reaction mixture was concentrated to afford methyl 3-methyl-4-hydroxybenzoate (372 g, quantitative yield). NMR hydrogen spectrum of the product (1H-NMR, CDCl3, δ ppm): 7.82 (1H, single peak), 7.78 (1H, double peak), 6.80 (1H, double peak), 3.86 (3H, single peak), 2.22 (3H, single peak).

References

[1] Patent: WO2003/101978, 2003, A1. Location in patent: Page 170-171
[2] European Journal of Medicinal Chemistry, 2009, vol. 44, # 7, p. 2994 - 3008
[3] Patent: US2006/135484, 2006, A1. Location in patent: Page/Page column 59
[4] Journal of Medicinal Chemistry, 2018, vol. 61, # 7, p. 3059 - 3075
[5] Patent: WO2012/125613, 2012, A1. Location in patent: Page/Page column 146

Methyl 4-hydroxy-3-methylbenzoate Preparation Products And Raw materials

Global( 90)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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ATK CHEMICAL COMPANY LIMITED
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CR Corporation Limited
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Labnetwork lnc.
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View Lastest Price from Methyl 4-hydroxy-3-methylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-HYDROXY-3-METHYL-BENZOIC ACID METHYL ESTER pictures 2020-01-05 4-HYDROXY-3-METHYL-BENZOIC ACID METHYL ESTER
42113-13-3
US $1.00 / KG 1KG 99% 200kg Career Henan Chemical Co

Methyl 4-hydroxy-3-methylbenzoate Spectrum

Methyl 4-hydroxy-3-Methylbenzoic acid Methyl 3-methyl-4-hydroxybenzoate methyl 4-hydoxy-3-methylbenzoate METHYL 4-HYDROXY-3-METHYLBENZOATE 3-methyl-4-hydroxybenzoic acid methyl ester 42113-13-3