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PHENYLMAGNESIUM CHLORIDE

CAS No.
100-59-4
Chemical Name:
PHENYLMAGNESIUM CHLORIDE
Synonyms
Phenylmagnesiu;Chlorphenylmagnesium;chlorophenyl-magnesiu;Phenylchloromagnesium;chlorophenylmagnesium;Magnesium, chlorophenyl-;PHENYLMAGNESIUM CHLORIDE;phenylmagnessium chloride;PhenylMagnesiuM Chloride Phenylmagnesium chloride(2M THF)
CBNumber:
CB5107614
Molecular Formula:
C6H5ClMg
Molecular Weight:
136.86
MDL Number:
MFCD00000464
MOL File:
100-59-4.mol
MSDS File:
SDS
Last updated:2026-01-13 11:20:35
Product description Number Pack Size Price
Phenylmagnesium chloride solution 2.0 M in THF 224448 8l $2710
Phenylmagnesium chloride solution 2.0?M in THF 224448 18L $5190
Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) P1381 250g $130
Phenylmagnesium chloride, 2-3M in THF 93-1269 0.25mole $44
Phenylmagnesium chloride, 2-3M in THF 93-1269 1mole $123
More product size

PHENYLMAGNESIUM CHLORIDE Properties

Melting point 89-90℃
Boiling point 230℃ (8 Torr)
Density 0.98 g/mL at 20 °C
Flash point 1 °F
storage temp. 2-8°C
form solution
Water Solubility It reacts violently with water.
Sensitive Air & Moisture Sensitive
Merck 14,7298
BRN 3587900
InChI InChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChIKey GQONLASZRVFGHI-UHFFFAOYSA-M
SMILES C1([Mg]Cl)C=CC=CC=1
CAS DataBase Reference 100-59-4(CAS DataBase Reference)
FDA UNII 739Y484F5H
EPA Substance Registry System Magnesium, chlorophenyl- (100-59-4)
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H371-H372-H261-H312-H318-H333-H225-H302-H314-H335-H351
Precautionary statements  P223-P303+P361+P353-P501a-P210-P260-P280-P305+P351+P338-P370+P378-P403+P235-P233-P240-P241+P242+P243-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P308+P311-P403+P233-P405-P501
target organs Central nervous system, Respiratory system
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  F,C
Risk Statements  14-19-20/21/22-34-67-65-63-48/20-11-40-37
Safety Statements  26-36/37/39-45-62-33-16
RIDADR  UN 2924 3/PG 2
WGK Germany  2
10
TSCA  TSCA listed
HazardClass  8
PackingGroup  II
HS Code  29319090
Storage Class 3 - Flammable liquids
Hazard Classifications Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Hazardous Substances Data 100-59-4(Hazardous Substances Data)
NFPA 704
3
3 2
W

PHENYLMAGNESIUM CHLORIDE price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 224448 Phenylmagnesium chloride solution 2.0 M in THF 100-59-4 8l $2710 2026-03-19 Buy
Sigma-Aldrich 224448 Phenylmagnesium chloride solution 2.0?M in THF 100-59-4 18L $5190 2026-03-19 Buy
TCI Chemical P1381 Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) 100-59-4 250g $130 2026-03-19 Buy
Strem Chemicals 93-1269 Phenylmagnesium chloride, 2-3M in THF 100-59-4 0.25mole $44 2023-06-20 Buy
Strem Chemicals 93-1269 Phenylmagnesium chloride, 2-3M in THF 100-59-4 1mole $123 2023-06-20 Buy
Product number Packaging Price Buy
224448 8l $2710 Buy
224448 18L $5190 Buy
P1381 250g $130 Buy
93-1269 0.25mole $44 Buy
93-1269 1mole $123 Buy

PHENYLMAGNESIUM CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

yellowish-brown to dark brown solution

Uses

In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of ()-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.

Definition

ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.

General Description

This product has been enhanced for energy efficiency.

reaction suitability

reaction type: Grignard Reaction

108-90-7
100-59-4
Synthesis of PHENYLMAGNESIUM CHLORIDE from Chlorobenzene
Global( 296)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd
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Henan Tianfu Chemical Co.,Ltd.
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Nanjing ChemLin Chemical Industry Co., Ltd.
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SIMAGCHEM CORP
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Career Henan Chemica Co
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Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Apeloa Pharmaceutical Co., Ltd.
+86-0571-87635730 +8613588737631 chem1022@hengdian-group.com China 1478 58

View Lastest Price from PHENYLMAGNESIUM CHLORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
PHENYLMAGNESIUM CHLORIDE pictures 2026-03-20 PHENYLMAGNESIUM CHLORIDE
100-59-4
US $10.00 / KG 100KG 99% 100 mt Hebei Chuanghai Biotechnology Co., Ltd
phenylmagnesium chloride pictures 2023-07-19 phenylmagnesium chloride
100-59-4
US $30.00 / KG 1KG 99% 20 Tons Wuhan wingroup Pharmaceutical Co., Ltd
PHENYLMAGNESIUM CHLORIDE pictures 2021-07-13 PHENYLMAGNESIUM CHLORIDE
100-59-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN Phenylmagnesiumchloride,2-3MinTHF PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN Chlorphenylmagnesium chlorophenyl-magnesiu Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) Magnesium, chlorophenyl- Phenylmagnesium chloride25 wt% solution in tetrahydrofuranAcroSeal§3 Phenylchloromagnesium Phenylmagnesium chloride, 1M in MeTHF PhenylMagnesiuM chloride, 25 wt% solution in tetrahydrofuran, AcroSeal 100ML Phenylmagnesiu Phenylmagnesium chloride solution 2.0 in THF Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran, AcroSeal PhenylMagnesiuM chloride, 25 wt% solution in tetrahydrofuran, AcroSeal 800ML PHENYLMAGNESIUM CHLORIDE chlorophenylmagnesium PHENYLMAGNESIUM CHLORIDE SOLUTION & PHENYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF Phenylmagnesium chloride 1M solution in THF Phenylmagnesium chloride 2M solution in THF Phenylmagnesium chloride 2M solution in DEE Phenylmagnesium chloride 1M solution in CPME PhenylMagnesiuM chloride, 2.0 M solution in THF, J&KSeal PhenylMagnesiuM Chloride  PhenylMagnesiuM chloride, 2M solution in CPME, AcroSeal PhenylMagnesiuM Chloride (27% in Tetrahydrofur PhenylMagnesiuM chloride, 1.0 M solution in THF, SpcSeal PHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURANPHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURANPHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURANPHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURAN Phenylmagnesium chloride solution(2.0 M solution in THF) PhenylMagnesiuM chloride, 2.0 M solution in THF, SpcSeal Phenylmagnesium chloride 1M tetrahydrofuran Phenylmagnesium chloride 2M tetrahydrofuran Phenylmagnesium Chloride, 1.0 M in 2-MeTHF Phenylmagnesium chloride(2M THF) Phenylmagnesium chloride 2.0 M solution in THF Phenyl Magnesium Chloride (2.0 M in THF) Phenyl Magnesium Chloride (1.5 M in THF) Phenylmagnesium chloride (2.0M THF) Phenylmagnesiumchloride 2 % (in THF) Phenylmagnesiumchloride 2 % (in Diethylether) Phenylmagnesium chloride, 2M in THF phenylmagnessium chloride PHENYLMAGNESIUM CHLORIDE(2M chlorophenylmagnesium in THF) Phenylmagnesium chloride 20% in THF / 2.0M in THF 100-59-4 C6H5MgCl C6H5ClMg C6Cl1H5Mg1 Aryl Organometallic Reagents Grignard Reagents & Alkyl Metals Grignard Reagents