beta-Bromostyrene
- CAS No.
- 103-64-0
- Chemical Name:
- beta-Bromostyrene
- Synonyms
- [(E)-2-Bromoethenyl]benzene;β-Bromostyrene;1-BROMO-2-PHENYLETHYLENE;(Z)-β-bromostyrene;BROMSTYROL;BROMOSTYROL;Bromstyrole;B-BROMSTYROL;hyacinthbase;styrylbromide
- CBNumber:
- CB5119040
- Molecular Formula:
- C8H7Br
- Molecular Weight:
- 183.05
- MDL Number:
- MFCD00000185
- MOL File:
- 103-64-0.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| β-Bromostyrene 97% | 157449 | 5g | $65.89 |
| beta-Bromostyrene (cis- and trans- mixture) >95.0%(GC) | B0655 | 25g | $71 |
| 2-Bromovinylbenzene | B415360 | 500mg | $45 |
| 2-Bromovinylbenzene | B415360 | 5g | $75 |
| beta-Bromostyrene 98% | OR70303 | 100g | $79 |
| More product size | |||
| Melting point | 7 °C(lit.) |
|---|---|
| Boiling point | 219-221 °C(lit.) |
| Density | 1.427 g/mL at 25 °C(lit.) |
| vapor pressure | 16.4Pa at 25℃ |
| refractive index |
n |
| Flash point | 215 °F |
| storage temp. | 2-8°C |
| solubility | Soluble in alcohol. |
| form | Liquid |
| color | very deep green-yellow |
| Odor | at 1.00 % in dipropylene glycol. strong leafy green hyacinth |
| Odor Type | green |
| Water Solubility | 56.624mg/L at 25℃ |
| BRN | 2038495 |
| LogP | 3.391 at 25℃ |
| CAS DataBase Reference | 103-64-0(CAS DataBase Reference) |
| EWG's Food Scores | 1-3 |
| FDA UNII | 46J0U1IRC9 |
| NIST Chemistry Reference | Benzene, (2-bromoethenyl)-(103-64-0) |
| EPA Substance Registry System | .beta.-Bromostyrene (103-64-0) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H227 | |||||||||
| Precautionary statements | P264-P270-P301+P312+P330-P501-P210e-P280a-P301+P312a-P403+P235-P501a | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22 | |||||||||
| Safety Statements | 23-24/25-36/37 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | WL3850000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29039990 | |||||||||
| Hazardous Substances Data | 103-64-0(Hazardous Substances Data) | |||||||||
| Toxicity | An acute oral LD50 in rats was reported as 1.25 ml/kg(0.82-189 ml/kg). The acute dermal LD50 was reported as > 6 ml/kg in the rabbit | |||||||||
| NFPA 704 |
|
beta-Bromostyrene price More Price(26)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 157449 | β-Bromostyrene 97% | 103-64-0 | 5g | $65.89 | 2025-07-31 | Buy |
| TCI Chemical | B0655 | beta-Bromostyrene (cis- and trans- mixture) >95.0%(GC) | 103-64-0 | 25g | $71 | 2025-07-31 | Buy |
| TRC | B415360 | 2-Bromovinylbenzene | 103-64-0 | 500mg | $45 | 2021-12-16 | Buy |
| TRC | B415360 | 2-Bromovinylbenzene | 103-64-0 | 5g | $75 | 2021-12-16 | Buy |
| Apolloscientific | OR70303 | beta-Bromostyrene 98% | 103-64-0 | 100g | $79 | 2021-12-16 | Buy |
beta-Bromostyrene Chemical Properties,Uses,Production
Chemical Properties
CLEAR YELLOWISH TO BROWN LIQUID
Occurrence
Apparently has not been reported to occur in nature.
Uses
Perfumery.
Uses
Beta-Bromostyrene, cis + trans is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.
Uses
β-Bromostyrene was used in the one-pot method for the preparation of cinnamonitriles. It was also used in the preparation of pure ethyl Z- and E-α,α-difluoro-4-phenyl-3-butenoate and 1,3-diphenyl-1-butene. It may be used in the synthesis of β-tert-butylstyrene via cross coupling reaction with tert-butylmagnesium chloride in the presence of dichloro[1,1′-bis(diphenylphosphino)ferrocene]nickel(II) catalyst. It may also be used to prepare γ-but-2-enolactone by reacting with nickel carbonyl in the presence of alkynes.
Preparation
By the action of aqueous alkali on cinnamic acid dibromide.
General Description
β-Bromostyrene is an α,β-unsaturated aromatic halide. It can be synthesized by catalytic Hunsdiecker reaction (CHR) of cinnamic acid. It is commonly utilized as a precursor for preparing substituted alkenes, corresponding acetylenes and also in the total synthesis of natural compounds and antibiotics.
Flammability and Explosibility
Not classified
beta-Bromostyrene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20174 | 58 |
| Hebei Zhuanglai Chemical Trading Co Ltd | +86-16264648883 | niki@zlchemi.com | China | 7245 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21618 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29850 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2930 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-17392712697 | 1022@dideu.com | China | 3996 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23541 | 58 |
View Lastest Price from beta-Bromostyrene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-09-25 | beta-Bromostyrene
103-64-0
|
US $101.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
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2025-05-23 | beta-Bromostyrene
103-64-0
|
US $45.00 / kg | 1kg | 99% | 20 tons | Hebei Zhuanglai Chemical Trading Co Ltd | |
![]() |
2024-08-05 | beta-Bromostyrene
103-64-0
|
US $0.10 / KG | 1KG | 99.0% | 1000 tons | Shaanxi Dideu Medichem Co. Ltd |
-

- beta-Bromostyrene
103-64-0
- US $101.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-

- beta-Bromostyrene
103-64-0
- US $45.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co Ltd
-

- beta-Bromostyrene
103-64-0
- US $0.10 / KG
- 99.0%
- Shaanxi Dideu Medichem Co. Ltd
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