(3-METHYLISOXAZOL-5-YL)METHANOL
- CAS No.
- 14716-89-3
- Chemical Name:
- (3-METHYLISOXAZOL-5-YL)METHANOL
- Synonyms
- (3-METHYLISOXAZOL-5-YL)METHANO;5-Isoxazolemethanol, 3-methyl-;(3-METHYLISOXAZOL-5-YL)METHANOL;(3-Methyl-5-isoxazolyl)methanol;3-Methyl-5-isoxazoleMethanol, 97%;(3-methyl-1,2-oxazol-5-yl)methanol;5-(Hydroxymethyl)-3-methylisoxazole;5-(Hydroxymethyl)-3-methylisoxazole97%;5-(Hydroxymethyl)-3-methylisoxazole 97%;(3-Methylisoxazol-5-yl)methanol - [M89521]
- CBNumber:
- CB51486774
- Molecular Formula:
- C5H7NO2
- Molecular Weight:
- 113.11
- MDL Number:
- MFCD09859210
- MOL File:
- 14716-89-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 5-(Hydroxymethyl)-3-methylisoxazole 97% | 746088 | 500mg | $123 |
| (3-methylisoxazol-5-yl)methanol | M324563 | 50mg | $45 |
| (3-methylisoxazol-5-yl)methanol | M324563 | 500mg | $285 |
| (3-Methylisoxazol-5-yl)methanol | CS-0047000 | 1g | $290 |
| 5-(Hydroxymethyl)-3-methylisoxazole | OR15967 | 1g | $174 |
| Melting point | 130 °C |
|---|---|
| Boiling point | 211.82°C (rough estimate) |
| Density | 1.1521 g/L at 25℃ |
| refractive index | n/D1.4792 |
| Flash point | >110℃ |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | liquid |
| pka | 13.43±0.10(Predicted) |
| color | Colourless |
| UNSPSC Code | 12352100 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 2934999090 | |||||||||
| NFPA 704 |
|
(3-METHYLISOXAZOL-5-YL)METHANOL price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 746088 | 5-(Hydroxymethyl)-3-methylisoxazole 97% | 14716-89-3 | 500mg | $123 | 2023-01-07 | Buy |
| TRC | M324563 | (3-methylisoxazol-5-yl)methanol | 14716-89-3 | 50mg | $45 | 2021-12-16 | Buy |
| TRC | M324563 | (3-methylisoxazol-5-yl)methanol | 14716-89-3 | 500mg | $285 | 2021-12-16 | Buy |
| ChemScene | CS-0047000 | (3-Methylisoxazol-5-yl)methanol | 14716-89-3 | 1g | $290 | 2021-12-16 | Buy |
| Apolloscientific | OR15967 | 5-(Hydroxymethyl)-3-methylisoxazole | 14716-89-3 | 1g | $174 | 2021-12-16 | Buy |
(3-METHYLISOXAZOL-5-YL)METHANOL Chemical Properties,Uses,Production
Synthesis
4857-42-5
14716-89-3
To a solution of tetrahydrofuran (20 mL) containing 3-methylisoxazole-5-carboxylic acid (3 g, 23.6 mmol) was added lithium aluminum hydride (LiAlH4, 1.8 g, 47.37 mmol) in batches at 0 °C and under nitrogen protection. The reaction mixture was stirred at room temperature for 2 hours before water (2 mL) was slowly added to quench the reaction. Subsequently, the mixture was dried with anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography with the eluent being a petroleum ether solution of 10%-30% ethyl acetate, resulting in 3-methylisoxazole-5-methanol as a colorless oil (1.5 g, 56% yield). Mass spectrum (ES, m/z) [M+H]+ 114.1; 1H NMR (300 MHz, CDCl3) δ 6.09 (s, 1H), 4.74 (s, 2H), 2.30 (s, 3H), 2.10 (brs, 1H).
References
[1] Patent: WO2014/66795, 2014, A1. Location in patent: Paragraph 0175
[2] Patent: WO2016/97870, 2016, A1
[3] ChemMedChem, 2017, vol. 12, # 1, p. 50 - 65
(3-METHYLISOXAZOL-5-YL)METHANOL Preparation Products And Raw materials
(3-METHYLISOXAZOL-5-YL)METHANOL Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30229 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49950 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 43339 | 58 |
| Sichuan Biosynce Pharmatech Co., Ltd. | +8619950309693 | diane@biosynce.com | China | 4871 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501; +undefined18621343501 | product@acmec-e.com | China | 33338 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52924 | 58 | |
| Suzhou ARTK Medchem Co., Ltd. | +86-512-68323658 +86-18168183658 | sales1@artkmedchem.com | China | 39002 | 58 |
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