Methyl 5-Methyl-2-Nitrobenzoate
- CAS No.
- 20587-30-8
- Chemical Name:
- Methyl 5-Methyl-2-Nitrobenzoate
- Synonyms
- Methyl 6-nitro-m-toluate;5-Methyl-2-Nitrobenzoate Methyl;Methyl 5-Methyl-2-Nitrobenzoate;6-Nitro-m-toluic Acid Methyl Ester;Methyl 5-Methyl-2-nitrobenzoate >5-Methyl-2-nitrobenzoic acid methyl ester;Benzoic acid, 5-methyl-2-nitro-, methyl ester;5-methyl-2-nitrobenzoic acid methyl ester 90%;2-(Ethoxycarbonyl)-4-methylnitrobenzene, 3-(Ethoxycarbonyl)-4-nitrotoluene;2-(Methoxycarbonyl)-4-methylnitrobenzene, 3-(Methoxycarbonyl)-4-nitrotoluene
- CBNumber:
- CB51564263
- Molecular Formula:
- C9H9NO4
- Molecular Weight:
- 195.17
- MDL Number:
- MFCD00157275
- MOL File:
- 20587-30-8.mol
| Product description | Number | Pack Size | Price |
| METHYL 5-METHYL-2-NITROBENZOATE AldrichCPR | S914665 | 1 unit | $113 |
| METHYL 5-METHYL-2-NITROBENZOATE Aldrich | S914665 | 250mg | $110 |
| Methyl 5-Methyl-2-nitrobenzoate >98.0%(GC) | M2544 | 5g | $36 |
| Methyl 5-Methyl-2-nitrobenzoate >98.0%(GC) | M2544 | 25g | $119 |
| METHYL 5-METHYL-2-NITROBENZOATE | B451623 | 500mg | $75 |
| More product size | |||
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315-H319-H335 |
| Precautionary statements | P280-P271 |
| HS Code | 2916399090 |
Methyl 5-Methyl-2-Nitrobenzoate price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | S914665 | METHYL 5-METHYL-2-NITROBENZOATE AldrichCPR | 20587-30-8 | 1 unit | $113 | 2025-07-31 | Buy |
| Sigma-Aldrich | S914665 | METHYL 5-METHYL-2-NITROBENZOATE Aldrich | 20587-30-8 | 250mg | $110 | 2024-03-01 | Buy |
| TCI Chemical | M2544 | Methyl 5-Methyl-2-nitrobenzoate >98.0%(GC) | 20587-30-8 | 5g | $36 | 2025-07-31 | Buy |
| TCI Chemical | M2544 | Methyl 5-Methyl-2-nitrobenzoate >98.0%(GC) | 20587-30-8 | 25g | $119 | 2025-07-31 | Buy |
| TRC | B451623 | METHYL 5-METHYL-2-NITROBENZOATE | 20587-30-8 | 500mg | $75 | 2021-12-16 | Buy |
Methyl 5-Methyl-2-Nitrobenzoate Chemical Properties,Uses,Production
Synthesis
67-56-1
3113-72-2
20587-30-8
5-Methyl-2-nitrobenzoic acid (8 g, 44.198 mmol) was dissolved in methanol (80 mL) and the solution was cooled to 0°C. Sulfuric acid (5 mL) was added slowly and dropwise with stirring. Subsequently, the reaction mixture was heated to 90 °C and stirred continuously at this temperature for 16 hours. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent 50% ethyl acetate/hexane). After completion of the reaction, excess methanol was removed by distillation under reduced pressure. The residue was poured into water (150 mL) and extracted with ethyl acetate (150 mL x 2). The organic phases were combined and washed sequentially with saturated sodium bicarbonate solution (50 mL x 2) and brine (20 mL). The organic layer was dried over anhydrous sodium sulfate, filtered and concentrated to afford methyl 5-methyl-2-nitrobenzoate (yield: 8 g, 93%). The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 7.86-7.84 (d, 1H, J = 8Hz), 7.48 (s, 1H), 7.40-7.38 (d, 1H, J = 8Hz), 3.91 (s, 3H), 3.47 (s, 3H).
References
[1] Journal of Heterocyclic Chemistry, 1984, vol. 21, p. 1807 - 1816
[2] Patent: WO2015/38417, 2015, A1. Location in patent: Paragraph 151
[3] Bulletin of the Korean Chemical Society, 2011, vol. 32, # 12, p. 4309 - 4315
[4] Bioorganic and Medicinal Chemistry, 2006, vol. 14, # 7, p. 2209 - 2224
[5] Chemische Berichte, 1909, vol. 42, p. 433
Methyl 5-Methyl-2-Nitrobenzoate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29795 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 11728 | 58 |
| CD Chemical Group Limited | +8615986615575 | info@codchem.com | China | 17259 | 58 |
| Nextpeptide Inc | +86-0571-81612335 +8613336028439 | sales@nextpeptide.com | China | 19908 | 58 |
| GLR Innovations | +91 9891111994 | info@glrgroup.in | India | 4535 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24597 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 | sales@qdrenas.com | China | 1066 | 58 |
View Lastest Price from Methyl 5-Methyl-2-Nitrobenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-01-28 | methyl 5-methyl-2-nitrobenzoate
20587-30-8
|
US $0.00 / kg | 10kg | 99% | 10 tons | Qingdao RENAS Polymer Material Co., Ltd. | |
 |
2020-01-05 | Methyl 5-Methyl-2-Nitrobenzoate
20587-30-8
|
US $1.00 / KG | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- methyl 5-methyl-2-nitrobenzoate
20587-30-8
- US $0.00 / kg
- 99%
- Qingdao RENAS Polymer Material Co., Ltd.
-
- Methyl 5-Methyl-2-Nitrobenzoate
20587-30-8
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
20587-30-8(Methyl 5-Methyl-2-Nitrobenzoate)Related Search:
1of4
