2-(TRIBUTYLSTANNYL)PYRIDINE
- CAS No.
- 17997-47-6
- Chemical Name:
- 2-(TRIBUTYLSTANNYL)PYRIDINE
- Synonyms
- tributyl(pyridin-2-yl)stannane;stannyL;2-TRI-N-BUTYLSTANNYLPYRIDINE;2-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE;SKL964;2-(Tri-n-butyL;Tributylpyridyltin;2-PYRIDYLTRIBUTYLTIN;TRIBUTYL(2-PYRIDYL)TIN;2-PYRIDYLTRI-N-BUTYLTIN
- CBNumber:
- CB5256787
- Molecular Formula:
- C17H31NSn
- Molecular Weight:
- 368.14
- MDL Number:
- MFCD00052052
- MOL File:
- 17997-47-6.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-(Tributylstannyl)pyridine 85% | 678333 | 1g | $81.7 |
| 2-(Tributylstannyl)pyridine 85% | 678333 | 5g | $93.6 |
| 2-(Tributylstannyl)pyridine | FT140852 | 10g | $389.4 |
| 2-(Tributylstannyl)pyridine | FT140852 | 25g | $714 |
| 2-(Tributylstannyl)pyridine | FT140852 | 50g | $1038.5 |
| More product size | |||
| Melting point | 132-135 °C |
|---|---|
| Boiling point | 134 °C |
| Density | 1.15 |
| refractive index | 1.5130 |
| Flash point | >110°C |
| storage temp. | -20°C |
| pka | 5.21±0.19(Predicted) |
| form | liquid |
| Specific Gravity | 1.142 |
| color | Clear, yellow |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 479329 |
| Exposure limits |
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
| InChI | 1S/C5H4N.3C4H9.Sn/c1-2-4-6-5-3-1;3*1-3-4-2;/h1-4H;3*1,3-4H2,2H3; |
| InChIKey | GYUURHMITDQTRU-UHFFFAOYSA-N |
| SMILES | CCCC[Sn](CCCC)(CCCC)c1ccccn1 |
| CAS DataBase Reference | 17997-47-6(CAS DataBase Reference) |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() ![]() ![]() GHS02,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H301-H312-H315-H319-H360FD-H372-H410 | |||||||||
| Precautionary statements | P210-P273-P280-P301+P310-P303+P361+P353-P305+P351+P338 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | T,Xi,N | |||||||||
| Risk Statements | 21-25-36/38-48/23/25-50/53-10 | |||||||||
| Safety Statements | 35-36/37/39-45-61-60 | |||||||||
| RIDADR | 2788 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Toxic | |||||||||
| TSCA | No | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29333990 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Acute Tox. 3 Oral Acute Tox. 4 Dermal Aquatic Acute 1 Aquatic Chronic 1 Eye Irrit. 2 Flam. Liq. 3 Repr. 1B Skin Irrit. 2 STOT RE 1 |
|||||||||
| Limited Quantities | 100ml (liquid) or 0.5 Kg (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
2-(TRIBUTYLSTANNYL)PYRIDINE price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 678333 | 2-(Tributylstannyl)pyridine 85% | 17997-47-6 | 1g | $81.7 | 2026-04-30 | Buy |
| Sigma-Aldrich | 678333 | 2-(Tributylstannyl)pyridine 85% | 17997-47-6 | 5g | $93.6 | 2026-04-30 | Buy |
| Biosynth | FT140852 | 2-(Tributylstannyl)pyridine | 17997-47-6 | 10g | $389.4 | 2026-06-04 | Buy |
| Biosynth | FT140852 | 2-(Tributylstannyl)pyridine | 17997-47-6 | 25g | $714 | 2026-06-04 | Buy |
| Biosynth | FT140852 | 2-(Tributylstannyl)pyridine | 17997-47-6 | 50g | $1038.5 | 2026-06-04 | Buy |
2-(TRIBUTYLSTANNYL)PYRIDINE Chemical Properties,Uses,Production
Uses
Building block in an efficient, palladium-catalyzed synthesis of 2-pyridylazaazulene, a bidentate ligand showing pH and cationic-metal dependent emission spectra.
Synthesis
109-04-6
1461-22-9
17997-47-6
General procedure for the preparation of 2-tributylmethyltin alkylpyridine by the reaction of 2-bromopyridine with tributyltin chloride: butyllithium (2.5 M hexane solution, 6.33 mmol) was added dropwise to a solution of freshly distilled 2-bromopyridine (1 g, 6.33 mmol) in tetrahydrofuran (12 mL) at -78 °C and degassed. After stirring for 30 minutes, tributyltin chloride (1.7 mL, 6.33 mmol) was added to the slightly reddish solution and stirring was continued at -78 °C for 1 hour, then brought to room temperature and stirred for 1 hour. Upon completion of the reaction, the reaction was quenched with saturated ammonium chloride solution and extracted with diethyl ether. The organic phase was washed with saturated sodium chloride solution, dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 20/1) to afford the target product 2-tributylmethylstannylpyridine in 94% yield.1H NMR (CDCl3) δ (ppm): 8.73 (dtd, J = 4.9,1.9,1.0,1H,H6), 7.48 (dt, J = 7.4,1.8,1H,H5). 7.39 (dt, J = 7.4,1.6,1H, H3), 7.10 (ddd, J = 6.9,4.9,1.7,1H, H4), 1.70-1.05 (m, 18H, CH2), 0.85 (t, 9H, J = 7.3, CH3).
References
[1] Patent: US2013/296302, 2013, A1. Location in patent: Paragraph 0592
[2] Patent: US2014/194441, 2014, A1. Location in patent: Paragraph 0455
[3] Inorganic Chemistry, 2013, vol. 52, # 9, p. 5570 - 5580
[4] Patent: US9219237, 2015, B1. Location in patent: Page/Page column 11
[5] European Journal of Inorganic Chemistry, 2002, # 3, p. 573 - 579
2-(TRIBUTYLSTANNYL)PYRIDINE Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai UCHEM Inc. | +86-18930848214 +86-021-56762820 | sales@myuchem.com | China | 8898 | 58 |
| Sach biotech Co.,Ltd | +86-15888865902; +86-15888865902 | sales@hzsqchem.com | China | 66 | 58 |
| Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29626 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29766 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| Zhengzhou Alfa Chemical Co.,Ltd | +86-18530059196 | sale04@alfachem.cn | China | 9636 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +86-189 4982 3763 | sales@tnjchem.com | China | 34526 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81139210 +86-17392587031 | 1059@dideu.com | China | 9984 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 17705817739 | info@dycnchem.com | China | 52693 | 58 |
| Zhuoer Chemical Co., Ltd | 02120970332; | sales@zhuoerchem.com | China | 2901 | 58 |
View Lastest Price from 2-(TRIBUTYLSTANNYL)PYRIDINE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-08-19 | 2-Tri-n-butylstannylpyridine
17997-47-6
|
$7.00-120.00 | 5g | 0.98 | 25kg | Shanghai UCHEM Inc. | |
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2025-06-11 | 2-(TRIBUTYLSTANNYL)PYRIDINE
17997-47-6
|
$800.00-1000.00 | 1kg | 98% | 5mt | Sach biotech Co.,Ltd | |
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2019-07-06 | 2-(TRIBUTYLSTANNYL)PYRIDINE
17997-47-6
|
$8.80 | 1KG | 97%-99% | 100kg | Career Henan Chemical Co |
-

- 2-Tri-n-butylstannylpyridine
17997-47-6
- $7.00-120.00
- 0.98
- Shanghai UCHEM Inc.
-

- 2-(TRIBUTYLSTANNYL)PYRIDINE
17997-47-6
- $800.00-1000.00
- 98%
- Sach biotech Co.,Ltd
-

- 2-(TRIBUTYLSTANNYL)PYRIDINE
17997-47-6
- $8.80
- 97%-99%
- Career Henan Chemical Co
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