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2-(TRIBUTYLSTANNYL)PYRIDINE

CAS No.
17997-47-6
Chemical Name:
2-(TRIBUTYLSTANNYL)PYRIDINE
Synonyms
tributyl(pyridin-2-yl)stannane;stannyL;2-TRI-N-BUTYLSTANNYLPYRIDINE;2-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE;SKL964;2-(Tri-n-butyL;Tributylpyridyltin;2-PYRIDYLTRIBUTYLTIN;TRIBUTYL(2-PYRIDYL)TIN;2-PYRIDYLTRI-N-BUTYLTIN
CBNumber:
CB5256787
Molecular Formula:
C17H31NSn
Molecular Weight:
368.14
MDL Number:
MFCD00052052
MOL File:
17997-47-6.mol
MSDS File:
SDS
Last updated:2026-05-28 03:05:06
Product description Number Pack Size Price
2-(Tributylstannyl)pyridine 85% 678333 1g $81.7
2-(Tributylstannyl)pyridine 85% 678333 5g $93.6
2-(Tributylstannyl)pyridine FT140852 10g $389.4
2-(Tributylstannyl)pyridine FT140852 25g $714
2-(Tributylstannyl)pyridine FT140852 50g $1038.5
More product size

2-(TRIBUTYLSTANNYL)PYRIDINE Properties

Melting point 132-135 °C
Boiling point 134 °C
Density 1.15
refractive index 1.5130
Flash point >110°C
storage temp. -20°C
pka 5.21±0.19(Predicted)
form liquid
Specific Gravity 1.142
color Clear, yellow
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 479329
Exposure limits ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
InChI 1S/C5H4N.3C4H9.Sn/c1-2-4-6-5-3-1;3*1-3-4-2;/h1-4H;3*1,3-4H2,2H3;
InChIKey GYUURHMITDQTRU-UHFFFAOYSA-N
SMILES CCCC[Sn](CCCC)(CCCC)c1ccccn1
CAS DataBase Reference 17997-47-6(CAS DataBase Reference)
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS02,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H226-H301-H312-H315-H319-H360FD-H372-H410
Precautionary statements  P210-P273-P280-P301+P310-P303+P361+P353-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  T,Xi,N
Risk Statements  21-25-36/38-48/23/25-50/53-10
Safety Statements  35-36/37/39-45-61-60
RIDADR  2788
WGK Germany  3
Hazard Note  Toxic
TSCA  No
HazardClass  6.1
PackingGroup  III
HS Code  29333990
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Flam. Liq. 3
Repr. 1B
Skin Irrit. 2
STOT RE 1
Limited Quantities 100ml (liquid) or 0.5 Kg (solid)
Excepted Quantities Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)
NFPA 704
2
3 0

2-(TRIBUTYLSTANNYL)PYRIDINE price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 678333 2-(Tributylstannyl)pyridine 85% 17997-47-6 1g $81.7 2026-04-30 Buy
Sigma-Aldrich 678333 2-(Tributylstannyl)pyridine 85% 17997-47-6 5g $93.6 2026-04-30 Buy
Biosynth FT140852 2-(Tributylstannyl)pyridine 17997-47-6 10g $389.4 2026-06-04 Buy
Biosynth FT140852 2-(Tributylstannyl)pyridine 17997-47-6 25g $714 2026-06-04 Buy
Biosynth FT140852 2-(Tributylstannyl)pyridine 17997-47-6 50g $1038.5 2026-06-04 Buy
Product number Packaging Price Buy
678333 1g $81.7 Buy
678333 5g $93.6 Buy
FT140852 10g $389.4 Buy
FT140852 25g $714 Buy
FT140852 50g $1038.5 Buy

2-(TRIBUTYLSTANNYL)PYRIDINE Chemical Properties,Uses,Production

Uses

Building block in an efficient, palladium-catalyzed synthesis of 2-pyridylazaazulene, a bidentate ligand showing pH and cationic-metal dependent emission spectra.

Synthesis

2-Bromopyridine

109-04-6

Tributyltin chloride

1461-22-9

2-(TRIBUTYLSTANNYL)PYRIDINE

17997-47-6

General procedure for the preparation of 2-tributylmethyltin alkylpyridine by the reaction of 2-bromopyridine with tributyltin chloride: butyllithium (2.5 M hexane solution, 6.33 mmol) was added dropwise to a solution of freshly distilled 2-bromopyridine (1 g, 6.33 mmol) in tetrahydrofuran (12 mL) at -78 °C and degassed. After stirring for 30 minutes, tributyltin chloride (1.7 mL, 6.33 mmol) was added to the slightly reddish solution and stirring was continued at -78 °C for 1 hour, then brought to room temperature and stirred for 1 hour. Upon completion of the reaction, the reaction was quenched with saturated ammonium chloride solution and extracted with diethyl ether. The organic phase was washed with saturated sodium chloride solution, dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 20/1) to afford the target product 2-tributylmethylstannylpyridine in 94% yield.1H NMR (CDCl3) δ (ppm): 8.73 (dtd, J = 4.9,1.9,1.0,1H,H6), 7.48 (dt, J = 7.4,1.8,1H,H5). 7.39 (dt, J = 7.4,1.6,1H, H3), 7.10 (ddd, J = 6.9,4.9,1.7,1H, H4), 1.70-1.05 (m, 18H, CH2), 0.85 (t, 9H, J = 7.3, CH3).

References

[1] Patent: US2013/296302, 2013, A1. Location in patent: Paragraph 0592
[2] Patent: US2014/194441, 2014, A1. Location in patent: Paragraph 0455
[3] Inorganic Chemistry, 2013, vol. 52, # 9, p. 5570 - 5580
[4] Patent: US9219237, 2015, B1. Location in patent: Page/Page column 11
[5] European Journal of Inorganic Chemistry, 2002, # 3, p. 573 - 579

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View Lastest Price from 2-(TRIBUTYLSTANNYL)PYRIDINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Tri-n-butylstannylpyridine pictures 2026-08-19 2-Tri-n-butylstannylpyridine
17997-47-6
$7.00-120.00 5g 0.98 25kg Shanghai UCHEM Inc.
2-(TRIBUTYLSTANNYL)PYRIDINE pictures 2025-06-11 2-(TRIBUTYLSTANNYL)PYRIDINE
17997-47-6
$800.00-1000.00 1kg 98% 5mt Sach biotech Co.,Ltd
2-(TRIBUTYLSTANNYL)PYRIDINE pictures 2019-07-06 2-(TRIBUTYLSTANNYL)PYRIDINE
17997-47-6
$8.80 1KG 97%-99% 100kg Career Henan Chemical Co
TRI-N-BUTYL(2-PYRIDYL)TIN TRIBUTYL(2-PYRIDYL)TIN 2-(Tributylstannyl)pyridine 85% (Pyridin-2-yl)(tributyl)tin, (Pyridin-2-yl)tributylstannane 2-(Tri-n-butyL stannyL 2-(TRIBUTYLSTANNYL)PYRIDINE 2-PYRIDINETRIBUTYLSTANNANE 2-PYRIDYLTRI-N-BUTYLTIN 2-PYRIDYLTRIBUTYLTIN 2-(Tributylstannyl)pyridine 85-95% 2-TRI-N-BUTYLSTANNYLPYRIDINE, TECH. 80% 2-(1,1,1-Tributylstannyl)pyridine , Tech., Tech 2-(1,1,1-Tributylstannyl)pyridine, TECH Tributylpyridyltin 2-(Tributylstannyl)pyridine 85 (2-Pyridyl)tri-N-butyltine 2-PYRIDYLTRI-n-BUTYLTIN 95% 2-(Tributylstannanyl)pyridine 2-(Tributyltin)pyridine 2-Pyridyltributylstannane Tris(but-1-yl)(pyridin-2-yl)tin, (Pyridin-2-yl)tributylstannane Pyridine,2-(tributylstannyl)- 2-Pyridyltributyltin 2-(Tributylstannyl)pyridine 2-(1,1,1-Tributylstannyl)pyridine, technical (2-Pyridinyl)tributylstannane tributyl(2-pyridyl)stannane 2-(TRIBUTYLSTANNYL)PYRIDINE ISO 9001:2015 REACH SKL964 (Tributylstannyl)pyridine 2-Tributylstannyl pyridine,97%min 2-(Tributylstannyl)pyridine - [T2792] 2-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE 2-TRI-N-BUTYLSTANNYLPYRIDINE tributyl(pyridin-2-yl)stannane 17997-47-6 C17H31NSn C5H4NSnCH23CH33 Typical Metal Compounds Classes of Metal Compounds Sn (Tin) Compounds Organometallic Reagents Organotins Organotin Organometallic Reagents Organotin Organotins Pyridines Organostannes Pyridine Tributylstanny Classes of Metal Compounds Sn (Tin) Compounds Typical Metal Compounds organic tin