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N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine

CAS No.
499128-71-1
Chemical Name:
N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine
Synonyms
FPB;fppbj;N-2BP-PBr;Compound bleach;[1,1'-Biphenyl]-4-;N-(4-Bromophenyl-N;N,N-Bis(4-biphenyL;)-N-(4-bromophenyL;N-(4-BroMophenyl)-N,N-;-Biphenyl]-4-amine, N-[1,1'
CBNumber:
CB52582497
Molecular Formula:
C30H22BrN
Molecular Weight:
476.41
MDL Number:
MFCD20261458
MOL File:
499128-71-1.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:50
Product description Number Pack Size Price
N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine >98.0%(HPLC)(N) B4550 5g $40
N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine >98.0%(HPLC)(N) B4550 25g $118
BIS-BIPHENYL-4-YL-(4-BROMOPHENYL)-AMINE 97% 11167 5G $21
BIS-BIPHENYL-4-YL-(4-BROMOPHENYL)-AMINE 97% 11167 25G $51
FPB 355739 48Tests $588
More product size

N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine Properties

Melting point 172-174℃
Boiling point 625.7±55.0 °C(Predicted)
Density 1.296
storage temp. Sealed in dry,Room Temperature
solubility slightly sol. in Tetrahydrofuran
pka -3.76±0.50(Predicted)
form powder to crystal
color White to Almost white

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
HS Code  2921490090

N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B4550 N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine >98.0%(HPLC)(N) 499128-71-1 5g $40 2026-04-30 Buy
TCI Chemical B4550 N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine >98.0%(HPLC)(N) 499128-71-1 25g $118 2026-04-30 Buy
AstaTech 11167 BIS-BIPHENYL-4-YL-(4-BROMOPHENYL)-AMINE 97% 499128-71-1 5G $21 2026-04-30 Buy
AstaTech 11167 BIS-BIPHENYL-4-YL-(4-BROMOPHENYL)-AMINE 97% 499128-71-1 25G $51 2026-04-30 Buy
Usbiological 355739 FPB 499128-71-1 48Tests $588 2021-12-16 Buy
Product number Packaging Price Buy
B4550 5g $40 Buy
B4550 25g $118 Buy
11167 5G $21 Buy
11167 25G $51 Buy
355739 48Tests $588 Buy

N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine Chemical Properties,Uses,Production

Synthesis

1-Bromo-4-iodobenzene

589-87-7

Bis(4-biphenylyl)amine

102113-98-4

N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine

499128-71-1

The general procedure for the synthesis of N-(4-bromophenyl)-N,N-bis(1,1'-biphenyl-4-yl)amine from p-bromoiodobenzene and bis(4-biphenyl)amine was as follows: bis(4-biphenyl)amine (23.7 g, 73.8 mmol) was added to a round-bottomed flask, followed by the addition of p-bromoiodobenzene (20.9 g, 73.8 mmol), sodium tert-butanolate (10.7 g, 111 mmol), p-butylpropanol (0.33 g, 1.47 mmol), and ultrasonically deoxygenated toluene (1.5 L). 111 mmol), palladium acetate (0.33 g, 1.47 mmol), and ultrasonically deoxygenated toluene (1.5 L). The mixture was heated to reflux overnight under nitrogen protection. After completion of the reaction, the reaction solution was cooled and extracted with ethyl acetate and water. The organic layer was separated and dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure to give the crude product. The crude product was purified by column chromatography using silica gel as stationary phase and dichloromethane/hexane as eluent to afford the target product N-(4-bromophenyl)-N,N-bis(1,1'-biphenyl-4-yl)amine (28.8 g, 82% yield).

References

[1] Patent: CN107652189, 2018, A. Location in patent: Paragraph 0068; 0069-0071
[2] Patent: CN107739377, 2018, A. Location in patent: Paragraph 0075-0078
[3] Patent: CN107986975, 2018, A. Location in patent: Paragraph 0074-0075
[4] Patent: CN108148016, 2018, A. Location in patent: Paragraph 0082; 0083; 0084
[5] Patent: EP2292603, 2011, A1. Location in patent: Page/Page column 25

589-87-7
102113-98-4
499128-71-1
Synthesis of N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine from 1-Bromo-4-iodobenzene and Bis(4-biphenylyl)amine
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View Lastest Price from N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N-(4-Bromophenyl)-N,N-bis(1,1'-biphenyl-4-yl)amine pictures 2026-04-30 N-(4-Bromophenyl)-N,N-bis(1,1'-biphenyl-4-yl)amine
499128-71-1
US $56.00-378.00 / g 25g 0.98 10kg Shanghai UCHEM Inc.
N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine  pictures 2025-11-18 N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine
499128-71-1
US $1.10 / g 1g 99.00% 100 Tons Dideu Industries Group Limited
N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine pictures 2025-09-25 N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine
499128-71-1
US $200.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd

N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine Spectrum

N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine N-[1,1'-Biphenyl]-4-yl-N-(4-bromophenyl)-[1,1'-biphenyl]-4-amine N-(4-BroMophenyl)-N,N- N-(4-BroMophenyl)-N , N-bis(1 , l'-biphenyl-yl)aMine N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine [1,1'-Biphenyl]-4-amine,N-[1,1'-biphenyl]-4-yl-N-(4-bromophenyl) N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine(BBAPBr) N-(4-Bromophenyl-N N-2BP-PBr [1,1'-Biphenyl]-4- Compound bleach N-(4-bromophenyl)-4-phenyl-N-(4-phenylphenyl)aniline N-(4-Biphenylyl)-N-(4-bromophenyl)-4-biphenylamine FPB N-([1,1'-bipehenyl]-4-yl)-N-(4-bromophenyl)-[1,1'-biphenyl]-4-amine N,N-Bis(4-biphenylyl)-N-(4-bromophenyl)amine> N,N-Bis(4-biphenyL )-N-(4-bromophenyL 4-Bromo-4',4''-diphenyltriphenylamine N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine ISO 9001:2015 REACH [1,1'-Biphenyl]-4-amine, N-[1,1'-biphenyl]-4-yl-N-(4-bromoph... N-([1,1'-biphenyl]-4-yl)-N-(4-bromophenyl)-[1,1'-biphenyl]-4-amine fppbj N-(4-Bromophenyl)-N,N-bis(biphenyl)amine -Biphenyl]-4-amine, N-[1,1' -biphenyl]-4-yl-N-(4-bromophenyl)- 499128-71-1 C30H22BrN OLED materials,pharm chemical,electronic