ChemicalBook >> CAS DataBase List >>2-broMo-5-Methylpyridine-1-o×ide

2-broMo-5-Methylpyridine-1-o×ide

CAS No.
19230-58-1
Chemical Name:
2-broMo-5-Methylpyridine-1-o×ide
Synonyms
2-bromo-5-methylpyridine N-oxide;2-broMo-5-Methylpyridine-1-o×ide;Pyridine, 2-broMo-5-Methyl-, 1-oxide;2-bromo-5-methyl-1-oxidopyridin-1-ium;2-Bromo-5-methylpyridin-1-ium-1-olate
CBNumber:
CB52614141
Molecular Formula:
C6H6BrNO
Molecular Weight:
188.02
MDL Number:
MFCD11052562
MOL File:
19230-58-1.mol
MSDS File:
SDS
Last updated:2026-05-28 03:38:44
Product description Number Pack Size Price
2-Bromo-5-methylpyridin-1-ium-1-olate 98% OR307223 250mg $22
2-Bromo-5-methylpyridin-1-ium-1-olate 98% OR307223 1g $49
2-Bromo-5-methylpyridin-1-ium-1-olate 98% OR307223 5g $158
2-Bromo-5-methylpyridin-1-ium-1-olate 98% OR307223 25g $545
2-Bromo-5-methylpyridine 1-oxide 95% AS39992 1g $68
More product size

2-broMo-5-Methylpyridine-1-o×ide Properties

Melting point 246-248 °C
Boiling point 345.7±22.0 °C(Predicted)
Density 1.56±0.1 g/cm3(Predicted)
storage temp. 2-8°C
pka -0.52±0.10(Predicted)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
HS Code  2933399990

2-broMo-5-Methylpyridine-1-o×ide price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR307223 2-Bromo-5-methylpyridin-1-ium-1-olate 98% 19230-58-1 250mg $22 2026-06-04 Buy
Apolloscientific OR307223 2-Bromo-5-methylpyridin-1-ium-1-olate 98% 19230-58-1 1g $49 2026-06-04 Buy
Apolloscientific OR307223 2-Bromo-5-methylpyridin-1-ium-1-olate 98% 19230-58-1 5g $158 2026-06-04 Buy
Apolloscientific OR307223 2-Bromo-5-methylpyridin-1-ium-1-olate 98% 19230-58-1 25g $545 2026-06-04 Buy
Activate Scientific AS39992 2-Bromo-5-methylpyridine 1-oxide 95% 19230-58-1 1g $68 2026-06-04 Buy
Product number Packaging Price Buy
OR307223 250mg $22 Buy
OR307223 1g $49 Buy
OR307223 5g $158 Buy
OR307223 25g $545 Buy
AS39992 1g $68 Buy

2-broMo-5-Methylpyridine-1-o×ide Chemical Properties,Uses,Production

Synthesis

2-Bromo-5-methylpyridine

3510-66-5

2-broMo-5-Methylpyridine-1-o×ide

19230-58-1

The general procedure for the synthesis of 2-bromo-5-methylpyridine nitrogen oxides from 2-bromo-5-methylpyridine was as follows: 2-bromo-5-methylpyridine (4 g, 2.3 mmol) was dissolved in dichloromethane (500 mL) at 0 °C and m-CPBA (52 g, 304 mmol) was added slowly. The reaction mixture was stirred continuously at room temperature for 20 hours. Upon completion of the reaction, the pH was adjusted with saturated K2CO3 solution to about 9. The organic layer was separated and concentrated to give the crude product. The crude product was purified by fast silica gel column chromatography with petroleum ether/ethyl acetate (1:1, v/v) as eluent to afford the target compound 2-bromo-5-methylpyridine 1-oxide (33 g, 75% yield). The structure of the product was confirmed by 1H NMR (CDCl3): δ 8.25 (s, 1H), 8.75 (d, 1H, J = 8.4 Hz), 6.95-6.94 (m, 1H), 2.30 (s, 3H).

References

[1] Patent: WO2011/146287, 2011, A1. Location in patent: Page/Page column 29-30
[2] Patent: WO2017/35353, 2017, A1. Location in patent: Paragraph 0911
[3] Journal of Medicinal Chemistry, 2014, vol. 57, # 16, p. 7126 - 7135
[4] Journal of Organic Chemistry, 2009, vol. 74, # 2, p. 939 - 942

2-broMo-5-Methylpyridine-1-o×ide Preparation Products And Raw materials

Global( 47)Suppliers
Supplier Tel Email Country ProdList Advantage
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
Shanxi Xuanran Import and Export Trade Co., Ltd.
+8617735180244 mike_yan@xuanranglobal.com CHINA 4017 58
CR Corporation Limited
+8613062833949 fred.wen@crcorporation.cn China 8645 58
Jilin Chinese Academy of Sciences-yanshen Technology
+undefined18143011203 info@chemextension.com China 42056 58
Suzhou ARTK Medchem Co., Ltd.
+8618118463618 sales1@artkmedchem.com China 39021 58
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10186 62
Cool Pharm, Ltd 021-60455363 18019463053 sales@coolpharm.com China 7481 58
Shanghai YuanYe Biotechnology Co., Ltd. 021-61312847; 18021002903 3008007409@qq.com China 89686 60
Jinan Kaixi Biotechnology Co., Ltd. 13370511208; 15853141736 461667177@qq.com China 702 55
2-Bromo-5-methylpyridin-1-ium-1-olate Pyridine, 2-broMo-5-Methyl-, 1-oxide 2-bromo-5-methyl-1-oxidopyridin-1-ium 2-broMo-5-Methylpyridine-1-o×ide 2-bromo-5-methylpyridine N-oxide 19230-58-1