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Tetrahydrofurfuryl acrylate

CAS No.
2399-48-6
Chemical Name:
Tetrahydrofurfuryl acrylate
Synonyms
Oxolan-2-ylmethyl prop-2-enoate;sr285;viscoat150;sartomer302;sartomer285;kayaradtc101;Photomer 4142;lightacrylatethf-a;LABOTEST-BB LT00159260;CHLUMICRYL THFA Monomer
CBNumber:
CB5311527
Molecular Formula:
C8H12O3
Molecular Weight:
156.18
MDL Number:
MFCD00014516
MOL File:
2399-48-6.mol
MSDS File:
SDS
Last updated:2026-01-27 10:33:46
Product description Number Pack Size Price
Tetrahydrofurfuryl acrylate 408271 100ml $85.9
Tetrahydrofurfuryl Acrylate (bio-based carbon from plant ca. 62%) (stabilized with MEHQ) min. 98.0 % T4402 25G $28
Tetrahydrofurfuryl Acrylate (bio-based carbon from plant ca. 62%) (stabilized with MEHQ) min. 98.0 % T4402 500G $75
Tetrahydrofurfuryl Acrylate (stabilized with MEHQ) >98.0%(GC) T2239 25g $37
Tetrahydrofurfuryl Acrylate (stabilized with MEHQ) >98.0%(GC) T2239 500g $141
More product size

Tetrahydrofurfuryl acrylate Properties

Boiling point 87 °C/9 mmHg (lit.)
Density 1.064 g/mL at 25 °C (lit.)
vapor pressure 1.19hPa at 25℃
refractive index n20/D 1.46(lit.)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Soluble in water
form clear liquid
color Colorless to Almost colorless
optical activity 0.1982° (C=0.82 g/100ml, CHCL3)
Viscosity 6 cp (25C)
Water Solubility 79.1g/L at 20.9℃
BRN 113115
Cosmetics Ingredients Functions VISCOSITY CONTROLLING
InChI 1S/C8H12O3/c1-2-8(9)11-6-7-4-3-5-10-7/h2,7H,1,3-6H2
InChIKey YNXCGLKMOXLBOD-UHFFFAOYSA-N
SMILES C=CC(=O)OCC1CCCO1
LogP 0.81 at 21.7℃
CAS DataBase Reference 2399-48-6(CAS DataBase Reference)
FDA UNII KC4X335T45
EPA Substance Registry System Tetrahydrofurfuryl acrylate (2399-48-6)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/38
Safety Statements  26
RIDADR  3334
WGK Germany  3
RTECS  UD3670893
TSCA  TSCA listed
HazardClass  9
HS Code  29321900
Storage Class 10 - Combustible liquids
Hazard Classifications Aquatic Chronic 3
Eye Irrit. 2
Skin Irrit. 2
NFPA 704
2
3 0

Tetrahydrofurfuryl acrylate price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 408271 Tetrahydrofurfuryl acrylate 2399-48-6 100ml $85.9 2026-03-19 Buy
TCI Chemical T4402 Tetrahydrofurfuryl Acrylate (bio-based carbon from plant ca. 62%) (stabilized with MEHQ) min. 98.0 % 2399-48-6 25G $28 2026-03-19 Buy
TCI Chemical T4402 Tetrahydrofurfuryl Acrylate (bio-based carbon from plant ca. 62%) (stabilized with MEHQ) min. 98.0 % 2399-48-6 500G $75 2026-03-19 Buy
TCI Chemical T2239 Tetrahydrofurfuryl Acrylate (stabilized with MEHQ) >98.0%(GC) 2399-48-6 25g $37 2026-03-19 Buy
TCI Chemical T2239 Tetrahydrofurfuryl Acrylate (stabilized with MEHQ) >98.0%(GC) 2399-48-6 500g $141 2026-03-19 Buy
Product number Packaging Price Buy
408271 100ml $85.9 Buy
T4402 25G $28 Buy
T4402 500G $75 Buy
T2239 25g $37 Buy
T2239 500g $141 Buy

Tetrahydrofurfuryl acrylate Chemical Properties,Uses,Production

Chemical Properties

Tetrahydrofurfuryl acrylate (TFA) is an important special acrylate, the cyclic ether group in its molecule is more active than the straight chain ether group, and the hydrogen on the α-position carbon of the ether bond also has a certain degree of activity, and this special structure gives its subsequent products special properties.

Uses

Tetrahydrofurfuryl acrylate may be used as an acrylic matrix for silver nanoparticles/polymer nanocomposites . It can form copolymers with butadiene. Prior to transfer printing, cellulosic and proteinic fibers are grafted with THFA.

Uses

Tetrahydrofurfuryl acrylate (THFA) can be used to prepare bio-based photopolymers. A series of thermostable shape memory photopolymers were synthesised from a mixture of two bio-based monomers, THFA and tridecyl methacrylate, with the addition of a small amount of 1,3-benzodithiol. Ethyl phenylphosphonate (2,4,6 trimethylbenzoyl) was used as a photoinitiator. The biorenewable carbon content of these photopolymers ranged from (63.7-74.9) %. The increase in THFA content in the photocured resins increased the light curing rate, increased the stiffness, and improved the mechanical and thermal properties of the obtained polymers. The developed bio-based photopolymers could replace petroleum-derived thermostable shape memory polymer analogues in a wide range of applications[1].

Hazard

A moderate skin irritant.

Synthesis

100 mL of homemade solid acid catalyst was loaded into the reaction tube of the distillation unit, and the top and bottom of the catalyst bed were filled with quartz sand as the heat preservation and support layer. Take acrylic acid and tetrahydrofurfuryl alcohol in the ratio of 1.2:1, dilute it with two times the mass of toluene, add 0.01% of hydroquinone as a polymerization inhibitor into the dilution solution, stir until the hydroquinone is completely dissolved, and put it aside. Set the temperature of preheater of the reaction distillation device at 85, set the temperature of the catalyst bed at 85 at the upper port and 110 at the lower port, set the system pressure at 80k Pa. The above raw material solution is continuously fed into the reactor at a certain flow rate, and then arrives at the top of the reactor after being preheated by the preheater, and then the esterification reaction is carried out naturally in the catalyst bed. After the crude product is concentrated, the residual solvent and excess acrylic acid are evaporated to obtain the finished product of tetrahydrofurfuryl acrylate, which is a transparent and colorless liquid.

Safety

Tetrahydrofurfuryl acrylate is a contact irritant affecting the skin, eyes, and mucous membranes and may cause sensitization through skin contact in certain individuals. If swallowed, it causes irritation of the gastrointestinal tract, causing nausea and vomiting.

References

[1] JUSTINAS JARAS; Jolita O; Aukse Navaruckiene. Thermoresponsive Shape-Memory Biobased Photopolymers of Tetrahydrofurfuryl Acrylate and Tridecyl Methacrylate.[J]. Materials, 2023. DOI:10.3390/ma16062156.

97-99-4
140-88-5
2399-48-6
Synthesis of Tetrahydrofurfuryl acrylate from Tetrahydrofurfuryl alcohol and Ethyl acrylate

Tetrahydrofurfuryl acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 300)Suppliers
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Qingdao RENAS Polymer Material Co., Ltd.
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Tetrahydrofurfuryl acrylate pictures 2026-04-17 Tetrahydrofurfuryl acrylate
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US $3.00-9.00 / KG 0.1KG 99% g-kg-tons, free sample is available ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Tetrahydrofurfuryl acrylate pictures 2026-04-16 Tetrahydrofurfuryl acrylate
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US $0.00 / kg 1kg 98% Customise Hefei Lbao Physical & Chemical Science Co.,Ltd
Tetrahydrofurfuryl acrylate pictures 2026-03-20 Tetrahydrofurfuryl acrylate
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US $10.00 / KG 1KG 99% 5tons Hebei Chuanghai Biotechnology Co., Ltd
sartomer285 sartomer302 sr285 viscoat150 TETRAHYDROFURFURYL ACRYLATE Tetrahydrofurfurylacrylate,tech.90%,stab.with500ppmhydroquinone 2-Propenoic acid, tetrahydrofurfuryl este TETRAHYDROFURFURYL ACRYLATE: TECH., 90%, STABILIZED WITH 500PPM HYDROQUINONE Tetrahydrofurfuryl Acrylate (stabilized with MEHQ) Photomer 4142 ACRYLIC ACID TETRAHYDROFURFURYL ESTER LABOTEST-BB LT00159260 (tetrahydro-2-furanyl)methyl2-propenoate 2-Propenoicacid,(tetrahydro-2-furanyl)methylester 2-Propenoicacid,tetrahydrofurfurylester kayaradtc101 lightacrylatethf-a Oxolan-2-ylmethyl prop-2-enoate Acrylic acid (tetrahydrofuran-2-yl)methyl ester Acrylic acid tetrahydrofuran-2-ylmethyl ester Propenoic acid tetrahydrofuran-2-ylmethyl ester Tetrahydrofuran-2-methanol acrylate Tetrahydrofurfruyl Acrylate tetrahydrofurfryl acrylate Tetrahydrofurfuryl acrylate, 98+% Tetrahydrofurfuryl Acrylate  Tetrahydrofurfuryl acrylate, stabilized with 500ppm hydroquinone Tetrahydrofurfuryl acrylate, 98%, stabilized with MEHQ (tetrahydrofuran-2-yl)Methyl acrylate etrahydrofurfuryl acrylate Tetrahydrofurfuryl acrylate, tech. 90%, stab. with 500ppm hy Tetrahydrofuran acrylate Tetrahydro-2-furanylmethyl acrylate Sinomer? THFA Monomer / Tetrahydrofurfuryl acrylate (Tetrahydrofuran-2-yl)methyl acrylate,98% (stabilized with MEHQ) CHLUMICRYL THFA Monomer THFATetrahydrofurfuryl acrylate 2399-48-6 23994-86-1 5393-98-8 CH2CHCOOCH2C4H7O Furans Heterocyclic Building Blocks Building Blocks AcrylateSelf Assembly&Contact Printing Fluorine-Containing Monomers for 157 nm UV Lithography Resist PolymersBuilding Blocks Acrylic Monomers Furans Heterocyclic Building Blocks Lithography Monomers Monomers