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ISOPROPYLMAGNESIUM BROMIDE

CAS No.
920-39-8
Chemical Name:
ISOPROPYLMAGNESIUM BROMIDE
Synonyms
bromo(1-methylethyl)magnesium;IsopropylMagnesiuM broMide solution;BroMoisopropylMagnesiuM;Isopropylbromomagnesium;2-Propylmagnesium bromide;ISOPROPYLMAGNESIUM BROMIDE;Brom(1-methylethyl)magnesium;iso-Propylmagnesiumbromide(15%inTHF);Isopropylmagnesium bromide(2M 2MeTHF);Isopropylmagnesium bromide, 2. M in THF
CBNumber:
CB5334382
Molecular Formula:
C3H7BrMg
Molecular Weight:
147.3
MDL Number:
MFCD00672110
MOL File:
920-39-8.mol
MSDS File:
SDS
Last updated:2026-01-13 11:22:24
Product description Number Pack Size Price
Isopropylmagnesium bromide solution 0.75 M in THF 775797 4x25ml $97.9
Isopropylmagnesium bromide solution 2.9M in 2- 703567 100ml $180
Isopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L) I0518 250g $133
i-Propylmagnesium bromide, 2.9M (35wt% ±1wt%) in 2-methyltetrahydrofuran 12-0825 0.25mole $157
i-Propylmagnesium bromide, 2.9M (35wt% ±1wt%) in 2-methyltetrahydrofuran 12-0825 1mole $468
More product size

ISOPROPYLMAGNESIUM BROMIDE Properties

Melting point 114-116℃
Boiling point 148-154℃
Density 0.982 g/mL at 25 °C
Flash point -17°C
storage temp. 2-8°C
solubility Miscible with tetrahydorfuran and diethyl ether. Immiscible with hydrocarbons.
form Solution
color Clear dark brown or dark gray
Sensitive Air & Moisture Sensitive
InChI InChI=1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChIKey UCJIVFREPMUZDC-UHFFFAOYSA-M
SMILES C(C)(C)[Mg]Br
EPA Substance Registry System Magnesium, bromo(1-methylethyl)- (920-39-8)
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H225-H261-H302-H314
Precautionary statements  P210-P231+P232-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes  F,C
Risk Statements  11-19-34-14/15-40-37-17-14
Safety Statements  16-26-27-36/37/39-45-43-39-37-36
RIDADR  3399
WGK Germany  2
TSCA  TSCA listed
HazardClass  4.3
PackingGroup  I
HS Code  29319090
Storage Class 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
Water-react 2
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3
3 2
W

ISOPROPYLMAGNESIUM BROMIDE price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 775797 Isopropylmagnesium bromide solution 0.75 M in THF 920-39-8 4x25ml $97.9 2026-03-19 Buy
Sigma-Aldrich 703567 Isopropylmagnesium bromide solution 2.9M in 2- 920-39-8 100ml $180 2026-03-19 Buy
TCI Chemical I0518 Isopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L) 920-39-8 250g $133 2026-03-19 Buy
Strem Chemicals 12-0825 i-Propylmagnesium bromide, 2.9M (35wt% ±1wt%) in 2-methyltetrahydrofuran 920-39-8 0.25mole $157 2024-03-01 Buy
Strem Chemicals 12-0825 i-Propylmagnesium bromide, 2.9M (35wt% ±1wt%) in 2-methyltetrahydrofuran 920-39-8 1mole $468 2024-03-01 Buy
Product number Packaging Price Buy
775797 4x25ml $97.9 Buy
703567 100ml $180 Buy
I0518 250g $133 Buy
12-0825 0.25mole $157 Buy
12-0825 1mole $468 Buy

ISOPROPYLMAGNESIUM BROMIDE Chemical Properties,Uses,Production

Chemical Properties

Clear dark brown or dark gray solution

Uses

Isopropylmagnesium bromide is a Grignard reagent used in organic synthesis, especially for the introduction of iso-propyl group to carbonyl compounds. It is also used as a strong base in aprotic solvent.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

General Description

This product, 2.9 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

reaction suitability

reaction type: Grignard Reaction

Synthesis

Nitrogen was replaced 3 times in a 500L reactor, 25.25kg of magnesium balls (0.8cm) were added, 100L of 2-methyltetrahydro was added and the initiator (2-bromopropane Grignard reagent) was 2kg. furan and initiator (2-bromopropane Grignard reagent) 2kg, heated to 60-65 degrees reflux, slowly at 50-60 degrees dropwise addition of 123kg of 2- bromopropane and 120L of 2-methyltetrahydrofuran mixture, to make a clear and transparent light brown to light gray liquid, dropwise addition is completed . reflux for 2 hours, acid-base titration concentration of 3.02 mol, reduce the temperature to about 10 degrees Celsius, stationary settlement for 24 hours, a small amount of black suspension and precipitate deposited at the bottom of the reactor, and no other solid precipitation, the supernatant pressure into the cylinder.

Global( 264)Suppliers
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ANHUI CHICO CHEMICAL CO., LTD.
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Shaanxi Dideu Medichem Co. Ltd
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Alfa Chemistry
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View Lastest Price from ISOPROPYLMAGNESIUM BROMIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ISOPROPYLMAGNESIUM BROMIDE pictures 2025-12-24 ISOPROPYLMAGNESIUM BROMIDE
920-39-8
US $0.00-0.00 / KG 1KG 99.0% 1000KG Shaanxi Dideu Medichem Co. Ltd
ISOPROPYLMAGNESIUM BROMIDE pictures 2025-12-01 ISOPROPYLMAGNESIUM BROMIDE
920-39-8
US $0.00 / kg 1kg 98% 10000KGS Shaanxi Dideu New Materials Co. Ltd
Bromo(isopropyl)magnesium pictures 2023-07-19 Bromo(isopropyl)magnesium
920-39-8
US $30.00 / KG 1KG 99% 20 Tons Wuhan wingroup Pharmaceutical Co., Ltd
Isopropylbromomagnesium Isopropylmagnesium bromide,3M solution in 2-Methyltetrahydrofuran Isopropylmagnesium bromide [1M solution in THF] Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal§3 Isopropylmagnesium bromide solution 2.9 M in 2-methyltetrahydrofuran Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal BroMoisopropylMagnesiuM IsopropylMagnesiuM broMide, 3M in 2-MeTHF IsopropylMagnesiuM broMide, 3M solution in 2-MeTHF, AcroSeal 2-Propylmagnesium bromide i-Propylmagnesium bromide 1M solution in THF i-Propylmagnesium bromide 2.75M solution in 2-MeTHF Isopropyl magnesium bromide 3M 2- methyltetrahydrofuran i-Propylmagnesium bromide, 2.9M (35wt% ±1wt%) in 2-methyltetrahydrofuran Isopropylmagnesium bromide, 1.0 M in THF i-Propylmagnesium bromide 2M solution in DEE IsopropylMagnesiuM broMide, 2.0 M solution in 2-Me THF, J&KSeal IsopropylMagnesiuM broMide, 1.0 M solution in THF, J&KSeal IsopropylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal IsopropylMagnesiuM broMide, 3.0 M solution in 2-Me THF, J&KSeal ISOPROPYLMAGNESIUM BROMIDE bromo(1-methylethyl)magnesium Isopropylmagnesium Bromide 1.0 M In Tetrahydrofuran Isopropylmagnesium Bromide 2.0 M In Diethyl Ether iso-Propylmagnesiumbromide(15%inTHF) ISOPROPYLMAGNESIUM BROMIDE, 0.8 M in TETRAHYDROFURAN Brom(1-methylethyl)magnesium ISOPROPYLMAGNESIUM BROMIDE: 15% IN TETRAHYDROFURAN Isopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L) Isopropylmagnesium bromide solution 1.0 M in THF IsopropylMagnesiuM broMide, 3.0 M in 2-Methyltetrahydrofuran, SpcSeal Isopropylmagnesium bromide solution( 1.0 M solution in THF) Isopropylmagnesium bromide solution( 3.0 M in 2-Methyltetrahydrofuran) Isopropylmagnesium bromide(2M 2MeTHF) Isopropylmagnesium Bromide DISCONTINUED, offer I920390 Isopropylmagnesium Bromide 1.0M In THF / 2.0M In DEE Isopropylmagnesium bromide, 3M solution in 2-MeTHF, AcroSeal&trade Isopropylmagnesium bromide, 2. M in THF Isopropylmagnesium bromide, 1. M in THF Iso-Propylmagnesium bromide 2% (in THF) Iso-Propylmagnesiumbromide 2% (in Diethylether) Isopropylmagnesium bromide, 2.0 M in THF Isopropyl Magnesium Bromide 3 Molar Solution in Diethyl Ether Iso-Propyl Magnesium Bromide (20% in Diethyl Ether) Isopropylmagnesium bromide solution, CAS 920-39-8 Isopropylmagnesium bromide 1.0M in THF/ 2.0M in Diethylether/ 2.9M in 2-methyl THF IsopropylMagnesiuM broMide solution 920-39-8 CH32CHMgBr C3H7BrMg Classes of Metal Compounds Typical Metal Compounds Mg (Magnesium) Compounds Grignard Reagents Grignard Reagents & Alkyl Metals Grignard Reagents Grignard Reagents & Alkyl Metals Mg (Magnesium) Compounds