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Ethyl p-nitrobenzoate

CAS No.
99-77-4
Chemical Name:
Ethyl p-nitrobenzoate
Synonyms
ETHYL 4-NITROBENZOATE;PNBA-ME;4-(ethoxycarbonyl)nitrobenzene;AKOS B029802;Benzocaine Impurity;RARECHEM AL BI 0193;Ethyl p-nitrobenzoat;ETHYL P-NITROBENZOATE;Ethyl4-Nitrobenzoate>4-Nitrobenzoicacidester
CBNumber:
CB5339776
Molecular Formula:
C9H9NO4
Molecular Weight:
195.17
MDL Number:
MFCD00007351
MOL File:
99-77-4.mol
MSDS File:
SDS
Last updated:2026-05-28 05:24:10

Ethyl p-nitrobenzoate Properties

Melting point 55-59 °C (lit.)
Boiling point 182 °C
Density 1.3544 (rough estimate)
refractive index 1.5700 (estimate)
storage temp. 2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Crystalline Powder
color Yellow
Merck 14,3832
BRN 1912879
InChI InChI=1S/C9H9NO4/c1-2-14-9(11)7-3-5-8(6-4-7)10(12)13/h3-6H,2H2,1H3
InChIKey PHWSCBWNPZDYRI-UHFFFAOYSA-N
SMILES C(OCC)(=O)C1=CC=C([N+]([O-])=O)C=C1
CAS DataBase Reference 99-77-4(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 1OCH6Y8NAR
NIST Chemistry Reference Ethyl 4-nitrobenzoate(99-77-4)
EPA Substance Registry System Ethyl 4-nitrobenzoate (99-77-4)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H303
Precautionary statements  P270-P301+P312-P403-P501c
PPE Eyeshields, Gloves, type N95 (US)
Risk Statements  33
Safety Statements  22-24/25
WGK Germany  3
RTECS  DH5600000
TSCA  TSCA listed
HS Code  29163990
Storage Class 11 - Combustible Solids
NFPA 704
1
1 0

Ethyl p-nitrobenzoate price More Price(49)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich PHR2225 Ethyl 4-Nitrobenzoate Pharmaceutical Secondary Standard; Certified Reference Material 99-77-4 100MG $417 2026-04-30 Buy
Sigma-Aldrich 72940 Ethyl 4-nitrobenzoate ≥98.0% (GC) 99-77-4 100g $61.7 2026-04-30 Buy
Sigma-Aldrich 1265300 Ethyl 4-nitrobenzoate United States Pharmacopeia (USP) Reference Standard 99-77-4 40mg $1270 2026-04-30 Buy
TCI Chemical N0485 Ethyl 4-Nitrobenzoate >98.0%(GC) 99-77-4 25g $40 2026-04-30 Buy
Usbiological 275564 Ethyl 4-nitrobenzoate Asreported 99-77-4 250g $240 2026-06-03 Buy
Product number Packaging Price Buy
PHR2225 100MG $417 Buy
72940 100g $61.7 Buy
1265300 40mg $1270 Buy
N0485 25g $40 Buy
275564 250g $240 Buy

Ethyl p-nitrobenzoate Chemical Properties,Uses,Production

Chemical Properties

yellow crystalline powder

Uses

Ethyl 4-Nitrobenzoate is used in preparation of p-dimethylaminobenzoate compounds.

General Description

Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards

Purification Methods

Dissolve it in Et2O and wash it with aqueous alkali, then the ether is evaporated and the solid recrystallised from EtOH. [Beilstein 13 H 3787, 13 IV 1074.]

Global( 283)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Hike Biological Technology.,ltd 025-52110956 17372769668 sophia@njhkchem.com China 35 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TAIYUAN RHF CO.,LTD. +86 351 7031519 sales@RHFChem.com China 2334 56
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10174 62

View Lastest Price from Ethyl p-nitrobenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl p-nitrobenzoate pictures 2026-09-13 Ethyl p-nitrobenzoate
99-77-4
$1.00 300g 99.8% 20 TONS .GZ HONESTCHEM CO.,LTD
Ethyl p-nitrobenzoate pictures 2026-09-02 Ethyl p-nitrobenzoate
99-77-4
$1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
Ethyl 4-nitrobenzoate pictures 2023-02-13 Ethyl 4-nitrobenzoate
99-77-4
$35.00 1kg 99% 50MT Hebei baicao biology science and technology co., ltd
4-(ethoxycarbonyl)nitrobenzene 4-nitro-benzoicaciethylester Benzoic acid, 4-nitro-, ethyl ester Benzoic acid, p-nitro-, ethyl ester Ethyl nitrobenzoate, para ester Ethyl para-nitrobenzoate p-nitro-benzoicaciethylester RARECHEM AL BI 0193 P-NITROBENZOIC ACID ETHYL ESTER Benzocaine Impurity (4-bromo-3,5-dimethyl-1-pyrazolyl)methanol 4-NITROBENZOIC ACID ETHYL ESTER AKOS B029802 PNBA-ME 4-Nitrobenzenecarboxylic acid ethyl ester 4-Nitrobenzoic acid O-ethyl ester Ethyl 4-nitrobenzoate,99% Ethyl p-nitrobenzoat Ethyl 4-nitrobenzoate >=98.0% (GC) ETHYL P-NITROBENZOATE Ethyl4-Nitrobenzoate> Benzocaine Impurity (Ethyl p-Nitrobenzoate) Benzocaine Impurity 4 (Ethyl p-Nitrobenzoate) Ethyl p-nitrobenzoate ISO 9001:2015 REACH 4-Nitrobenzoicacidester ETHYL 4-NITROBENZOATE 99-77-4 O2NC6H4CO2C2H5 Organic Building Blocks Esters Building Blocks Carbonyl Compounds C8 to C9 FINE Chemical & INTERMEDIATES Aromatic Esters C8 to C9 Carbonyl Compounds Esters