3-Methylbenzoyl chloride
- CAS No.
- 1711-06-4
- Chemical Name:
- 3-Methylbenzoyl chloride
- Synonyms
- M-TOLUOYL CHLORIDE;m-ToL;Toluoyl chloride;toluoylchloride;3-ToluylChloride;3-toluoylchloride;M-TOLUYL CHLORIDE;3-Toluoyl chloride;meta-toluoyl chloride;m-Toluoyl chloride,99%
- CBNumber:
- CB5344365
- Molecular Formula:
- C8H7ClO
- Molecular Weight:
- 154.59
- MDL Number:
- MFCD00000681
- MOL File:
- 1711-06-4.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| m-Toluoyl chloride 99% | 122254 | 5g | $39.8 |
| m-Toluoyl chloride 99% | 122254 | 100g | $131 |
| m-Toluoyl Chloride >98.0%(GC)(T) | T0309 | 25g | $73 |
| m-Toluoyl Chloride >98.0%(GC)(T) | T0309 | 500g | $210 |
| m-Toluoyl Chloride | TRC-T536255-5G | 5g | $84 |
| More product size | |||
| Melting point | -23°C |
|---|---|
| Boiling point | 86 °C/5 mmHg (lit.) |
| Density | 1.173 g/mL at 25 °C (lit.) |
| refractive index | 1.5475-1.5495 |
| Flash point | 76 °C |
| storage temp. | Inert atmosphere,2-8°C |
| form | Liquid |
| Specific Gravity | 1.17 |
| color | Clear colorless to light brown |
| Water Solubility | Reacts with water. |
| Sensitive | Moisture Sensitive |
| BRN | 878419 |
| InChI | 1S/C8H7ClO/c1-6-3-2-4-7(5-6)8(9)10/h2-5H,1H3 |
| InChIKey | YHOYYHYBFSYOSQ-UHFFFAOYSA-N |
| SMILES | Cc1cccc(c1)C(Cl)=O |
| CAS DataBase Reference | 1711-06-4(CAS DataBase Reference) |
| FDA UNII | W2VJW4350K |
| NIST Chemistry Reference | Benzoyl chloride, 3-methyl-(1711-06-4) |
| EPA Substance Registry System | Benzoyl chloride, 3-methyl- (1711-06-4) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34-36/37 | |||||||||
| Safety Statements | 24/25-45-36/37/39-27-26-23 | |||||||||
| RIDADR | 3265 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | DM6644000 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29163990 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Skin Corr. 1B | |||||||||
| REACH Registrations | Inactive | |||||||||
| Limited Quantities | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
3-Methylbenzoyl chloride price More Price(32)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 122254 | m-Toluoyl chloride 99% | 1711-06-4 | 5g | $39.8 | 2026-04-30 | Buy |
| Sigma-Aldrich | 122254 | m-Toluoyl chloride 99% | 1711-06-4 | 100g | $131 | 2026-04-30 | Buy |
| TCI Chemical | T0309 | m-Toluoyl Chloride >98.0%(GC)(T) | 1711-06-4 | 25g | $73 | 2026-04-30 | Buy |
| TCI Chemical | T0309 | m-Toluoyl Chloride >98.0%(GC)(T) | 1711-06-4 | 500g | $210 | 2023-06-20 | Buy |
| TRC | TRC-T536255-5G | m-Toluoyl Chloride | 1711-06-4 | 5g | $84 | 2026-06-03 | Buy |
3-Methylbenzoyl chloride Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light brown liquid
Uses
m-Toluoyl chloride has been used to derivatize the C1-C4 aliphatic amines for their determination in air by HPLC. It has been used in determination of atmospheric ammonia by denuder-sampling and HPLC-UV detection.
General Description
m-Toluoyl chloride is an efficient derivatization reagent for amines.
Synthesis
99-04-7
1711-06-4
In a 1000 mL three-necked flask equipped with a thermometer, a mechanical stirrer, a reflux condenser tube and an off-gas absorption device, 540.56 g of m-methylbenzoic acid, 573.0 g of thionyl chloride and 1.0 g of N,N-dimethylformamide were added sequentially. The reaction mixture was heated to 90°C and the reaction was continuously stirred at this temperature for 3 hours. Upon completion of the reaction, the system was clear. The excess thionyl chloride was removed by distillation under reduced pressure, and 610.0 g of m-toluoyl chloride was finally obtained, which was determined to have a purity of 98.2% and a yield of 99.3%.
References
[1] Patent: CN107417518, 2017, A. Location in patent: Paragraph 0028
[2] Patent: CN105348085, 2016, A. Location in patent: Paragraph 0026; 0027; 0028; 0029; 0030
[3] Patent: CN107400052, 2017, A. Location in patent: Paragraph 0016
[4] Canadian Journal of Chemistry, 1963, vol. 41, p. 2962 - 2968
[5] Chemische Berichte, 1879, vol. 12, p. 2300
3-Methylbenzoyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Yanxi Chemical Co., Ltd. | +8618531123677 | faithe@yan-xi.com | China | 5853 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-86-13131129325 +8613131129325 | sales1@chuanghaibio.com | China | 5228 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18126 | 58 |
| Hebei Zhuanglai Chemical Trading Co Ltd | +86-16264648883 | niki@zlchemi.com | China | 7245 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21587 | 55 |
| Fluoropharm Co., Ltd. | +86-0571-85586753 +86-13336034509 | sales@fluoropharm.com | China | 1445 | 60 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2988 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8615060885618 | sales@amoychem.com | China | 6366 | 58 |
View Lastest Price from 3-Methylbenzoyl chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-05-28 | 3-Methylbenzoyl chloride
1711-06-4
|
$50.00-100.00 | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | |
 |
2026-04-21 | m-Toluoyl chloride
1711-06-4
|
$32.00-77.00 | ≥95% | 10g | TargetMol Chemicals Inc. | ||
 |
2025-06-27 | 3-Methylbenzoyl chloride
1711-06-4
|
$10.00-30.00 | 50KG | 99% | 500000kg | Hebei Chuanghai Biotechnology Co., Ltd |
-
- 3-Methylbenzoyl chloride
1711-06-4
- $50.00-100.00
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
-
- m-Toluoyl chloride
1711-06-4
- $32.00-77.00
- ≥95%
- TargetMol Chemicals Inc.
-
- 3-Methylbenzoyl chloride
1711-06-4
- $10.00-30.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
