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(Bromomethyl)cyclobutane

CAS No.
17247-58-4
Chemical Name:
(Bromomethyl)cyclobutane
Synonyms
CYCLOBUTYLMETHYL BROMIDE;(Bromomethyl)cyclobu;(Bromomethyl)codobutane;(BROMOMETHYL)CYCLOBUTANE;(Bromomethyl)cyclobutene;Cyclobuty-1-Methyl broMide;Cyclobutane, (bromomethyl)-;(Bromomethyl)cyclobutane>(BROMOMETHYL)CYCLOBUTANE 99%;(Bromomethyl)cyclobutane,99%
CBNumber:
CB5357637
Molecular Formula:
C5H9Br
Molecular Weight:
149.03
MDL Number:
MFCD00040960
MOL File:
17247-58-4.mol
MSDS File:
SDS
Last updated:2026-05-12 09:14:19
Product description Number Pack Size Price
(Bromomethyl)cyclobutane 97% 441171 5ml $134
(Bromomethyl)cyclobutane 97% 441171 25ml $409
(Bromomethyl)cyclobutane >98.0%(GC) B3679 5g $76
(Bromomethyl)cyclobutane >98.0%(GC) B3679 25g $251
(Bromomethyl)cyclobutane B697133 25g $275
More product size

(Bromomethyl)cyclobutane Properties

Boiling point 123-124 °C(lit.)
Density 1.326 g/mL at 25 °C(lit.)
refractive index n20/D 1.48(lit.)
Flash point 97 °F
storage temp. Inert atmosphere,2-8°C
form Liquid
color Clear colorless
Specific Gravity 1.326
Water Solubility 80mg/L at 20℃
InChI InChI=1S/C5H9Br/c6-4-5-2-1-3-5/h5H,1-4H2
InChIKey FLHFTXCMKFVKRP-UHFFFAOYSA-N
SMILES C1(CBr)CCC1
CAS DataBase Reference 17247-58-4(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210-P233-P240-P241-P242-P243
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  16-26-36
RIDADR  UN 1993 3/PG 3
WGK Germany  3
HazardClass  3
PackingGroup  III
HS Code  29038900
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 3
REACH Registrations Inactive
Limited Quantities 5.0 L (1.3 gallons) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
3
2 0

(Bromomethyl)cyclobutane price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 441171 (Bromomethyl)cyclobutane 97% 17247-58-4 5ml $134 2026-04-30 Buy
Sigma-Aldrich 441171 (Bromomethyl)cyclobutane 97% 17247-58-4 25ml $409 2026-04-30 Buy
TCI Chemical B3679 (Bromomethyl)cyclobutane >98.0%(GC) 17247-58-4 5g $76 2026-04-30 Buy
TCI Chemical B3679 (Bromomethyl)cyclobutane >98.0%(GC) 17247-58-4 25g $251 2026-04-30 Buy
TRC B697133 (Bromomethyl)cyclobutane 17247-58-4 25g $275 2021-12-16 Buy
Product number Packaging Price Buy
441171 5ml $134 Buy
441171 25ml $409 Buy
B3679 5g $76 Buy
B3679 25g $251 Buy
B697133 25g $275 Buy

(Bromomethyl)cyclobutane Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

(Bromomethyl)cyclobutane may be used in the synthesis of racemic 3-cyclobutylalanine and 17-(cyclobutylmethyl)morphinan-3-ol (butorphan).

Preparation

The preparation of (Bromomethyl)cyclobutane is as follows:Into a clean, dry reactor equipped with a stirrer and under nitrogen are successively loaded 5.4 kg of DMF (5.1 eqV) and then 4.53 kg of triphenylphosphite. 2.34 kg of bromine is then introduced while maintaining the temperature at less than 12°C. The stirring speed is regulated according to the fluidity of the reaction medium.10065] The set point of the jacket is then adjusted to -12°C. and then 1.120 kg of cyclobutylmethanol is introduced in such a way as not to exceed a temperature of -5° C. At the end of the addition the whole is allowed to return slowly to room temperature. After distillation and washing, the final product 2b (mass 1.529 kg) having a GC relative purity of 98.3% is obtained with a yield of 78%.17247-58-4(1).png

General Description

(Bromomethyl)cyclobutane (bromomethyl-cyclobutane) is an aryl fluorinated building block. Its reaction with various hydroxychromen-4-one derivatives in the presence of anhydrous K2CO3/dry acetone and Bu4N+I- (PTC) has been investigated.

4415-82-1
17247-58-4
Synthesis of (Bromomethyl)cyclobutane from Cyclobutanemethanol
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View Lastest Price from (Bromomethyl)cyclobutane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Bromomethyl)cyclobutane pictures 2025-09-25 (Bromomethyl)cyclobutane
17247-58-4
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
(Bromomethyl)cyclobutane pictures 2023-10-08 (Bromomethyl)cyclobutane
17247-58-4
US $30.00 / L 1L 99% 20T Firsky International Trade (Wuhan) Co., Ltd
(Bromomethyl)cyclobutane pictures 2023-07-19 (Bromomethyl)cyclobutane
17247-58-4
US $30.00 / KG 1KG 99% 20 Tons Wuhan wingroup Pharmaceutical Co., Ltd
CYCLOBUTYLMETHYL BROMIDE (BROMOMETHYL)CYCLOBUTANE (Bromomethyl)codobutane Cyclobutane, (bromomethyl)- (BROMOMETHYL)CYCLOBUTANE 99% (Bromomethyl)cyclobu Cyclobuty-1-Methyl broMide CYCLOBUTYL METHYL BROMIDE FOR SYNTHESIS (Bromomethyl)cyclobutane, 98.5% (Bromomethyl)cyclobutane,99% (Bromomethyl)cyclobutaneCyclobutylmethyl bromide (Bromomethyl)cyclobutane> (Bromomethyl)cyclobutane ISO 9001:2015 REACH (Bromomethyl)cyclobutene 17247-58-4 C4H7CH2Br HALOGEN Halogenated Hydrocarbons Organic Building Blocks Building Blocks Alkyl Cycloalkanes