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Methyl 2-iodobenzoate

Methyl 2-iodobenzoate structure

CAS No.: 610-97-9

Chemical Name:: Methyl 2-iodobenzoate

Synonyms: IBM;2-Iodobenzoate;2-Iodo Methyl Benzoate;methyl iodobenzoate;2-IODOBENZOIC ACID METHYL ESTER;Methy1;O-Methyl iodide;Methyl 2-iodobenzo;RARECHEM AL BF 0562;Methyl-2-iodbenzoat

CBNumber:: CB5468414

Molecular Formula:: C8H7IO2

Molecular Weight:: 262.04

MDL Number:: MFCD00016351

MOL File:: 610-97-9.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 01:57:01

Product description	Number	Pack Size	Price
Methyl 2-iodobenzoate 97%	532851	50g	$88.5
Methyl 2-iodobenzoate 97%	532851	250g	$185
Methyl 2-Iodobenzoate >98.0%(GC)	I0586	25g	$50
Methyl 2-Iodobenzoate >98.0%(GC)	I0586	250g	$196
Methyl 2-iodobenzoate, min. 98% min.98%	06-0076	25g	$36
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Methyl 2-iodobenzoate Properties

Melting point	64°C
Boiling point	149-150 °C/10 mmHg (lit.)
Density	1.784 g/mL at 25 °C (lit.)
refractive index	n20/D 1.604(lit.)
Flash point	>230 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Chloroform, Ethyl Acetate (Slightly), Methanol
form	Crystalling or Flaky Powder
color	White
Water Solubility	INSOLUBLE
Sensitive	Light Sensitive
BRN	2206859
Stability	Light Sensitive
InChI	1S/C8H7IO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3
InChIKey	BXXLTVBTDZXPTN-UHFFFAOYSA-N
SMILES	COC(=O)c1ccccc1I
CAS DataBase Reference	610-97-9(CAS DataBase Reference)
FDA UNII	HCW7KL2LZN
NIST Chemistry Reference	Methyl-2-iodobenzoate(610-97-9)
EPA Substance Registry System	Benzoic acid, 2-iodo-, methyl ester (610-97-9)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P305+P351+P338-P280a-P304+P340-P405-P501a

PPE

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36-24/25

WGK Germany

TSCA

TSCA listed

HazardClass

IRRITANT

HS Code

29163990

Storage Class

10 - Combustible liquids

REACH Registrations

Inactive

NFPA 704

	0
2		0

Methyl 2-iodobenzoate price More Price(58)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	532851	Methyl 2-iodobenzoate 97%	610-97-9	50g	$88.5	2026-04-30	Buy
Sigma-Aldrich	532851	Methyl 2-iodobenzoate 97%	610-97-9	250g	$185	2023-06-20	Buy
TCI Chemical	I0586	Methyl 2-Iodobenzoate >98.0%(GC)	610-97-9	25g	$50	2026-04-30	Buy
TCI Chemical	I0586	Methyl 2-Iodobenzoate >98.0%(GC)	610-97-9	250g	$196	2026-04-30	Buy
Strem Chemicals	06-0076	Methyl 2-iodobenzoate, min. 98% min.98%	610-97-9	25g	$36	2026-04-30	Buy

Product number	Packaging	Price	Buy
532851	50g	$88.5	Buy
532851	250g	$185	Buy
I0586	25g	$50	Buy
I0586	250g	$196	Buy
06-0076	25g	$36	Buy

Methyl 2-iodobenzoate Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

Methyl 2-iodobenzoate may be used in the preparation of:

N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones
methyl diphenylacetylene-2-carboxylate
methyl 2-heptynylphenylbenzoate
(E)-2-[3-[3-[2-(7-chloro-2-quinolinyl)ethenyl]phenyl]-3-oxopropyl]benzoic acid methyl ester
4-(2-carbomethoxyphenyl)-3-(1-methylethoxy)cyclobut-3-ene-1,2-dione
3-(2-carbomethoxyphenyl)-4-methylcyclobuten-3-ene-1,2-dione 2-(ethylene acetal)

Synthesis Reference(s)

Journal of the American Chemical Society, 93, p. 4845, 1971 DOI: 10.1021/ja00748a030

General Description

Methyl 2-iodobenzoate can be prepared from 2-iodobenzoic acid via esterification. It undergoes cobalt-catalyzed cyclization with aldehydes to form phthalide derivatives. The microbial dihydroxylation of methyl 2-iodobenzoate forms a nonracemic iodocyclohexene carboxylate intermediate. This intermediate forms the precursor for preparing kibdelone C.

Synthesis

67-56-1

88-67-5

610-97-9

To a 200 mL methanol solution of 2-iodobenzoic acid (15 g, 60 mmol) was slowly added 8.8 mL of concentrated sulfuric acid dropwise. The reaction mixture was heated to reflux for 16 hours. Upon completion of the reaction, the mixture was cooled to room temperature and concentrated by rotary evaporator to about 20 mL. Subsequently, the concentrate was partitioned between water (appropriate amount) and dichloromethane (appropriate amount). The aqueous phase was further extracted with dichloromethane (2 × 150 mL). The organic layers were combined and washed sequentially with saturated sodium bicarbonate solution (3 × 100 mL) and water (3 × 100 mL). The organic layers were dried over anhydrous sodium sulfate, filtered and the solvent was evaporated to give methyl 2-iodobenzoate (47) as a light yellow oil (15.4 g, 98% yield).The infrared spectrum of methyl 2-iodobenzoate (47) (KBr, νmax, cm1): 3444, 3057, 2994, 2946, 2894, 2836, 1728, 1579, 1459, 1428, 1290. 1459, 1428, 1290, 1249, 1127, 1100, 1013, 738.

References

[1] Organic and Biomolecular Chemistry, 2018, vol. 16, # 17, p. 3213 - 3219
[2] Organometallics, 2013, vol. 32, # 11, p. 3220 - 3226
[3] European Journal of Medicinal Chemistry, 2013, vol. 69, p. 798 - 816
[4] Synthetic Communications, 2017, vol. 47, # 12, p. 1175 - 1184
[5] Angewandte Chemie - International Edition, 2017, vol. 56, # 39, p. 11995 - 11999

Methyl 2-iodobenzoate synthesis

Synthesis of Methyl 2-iodobenzoate from Methanol and 2-Iodobenzoic acid

Methyl 2-iodobenzoate Preparation Products And Raw materials

Raw materials

2-Iodobenzoic acid Methyl trifluoroacetate METHYL HYDROGEN PHTHALATE Methanol 1-Pentanone, 1-(2-iodophenyl)-

Preparation Products

2-Methoxycarbonylphenylboronic acid METHYL BIPHENYL-2-CARBOXYLATE 4′-Methylbiphenyl-2-carboxylic acid methyl ester 2-Iodobenzyl alcohol 2,2'-IMINODIBENZOIC ACID

[R-(E)]-alpha-[3-[2-(7-Chloro-2-quinolinyl)ethenyl]phenyl]-2-(1-hydroxy-1-methylethyl)benzenepropanol 2-BroMo-5,7-dihydro-7,7-diMethyl-5-phenyl-indeno[2,1-b]carbazole Methyl 2-(trifluoromethyl)benzoate METHYL 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE

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Methyl 2-iodobenzoate Suppliers

Global( 515)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Yanxi Chemical Co., Ltd.	+8618531123677	faithe@yan-xi.com	China	5853	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-86-13131129325 +8613131129325	sales1@chuanghaibio.com	China	5231	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615531151365	mina@chuanghaibio.com	China	18126	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20122	58
Hebei Zhuanglai Chemical Trading Co Ltd	+86-16264648883	niki@zlchemi.com	China	7245	58
Capot Chemical Co.,Ltd.	+8613336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13901	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21587	55
Shanxi Naipu Import and Export Co.,Ltd	+86-13734021967 +8613734021967	kaia@neputrading.com	China	1001	58
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29815	58

Supplier	Advantage
Hebei Yanxi Chemical Co., Ltd.	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Hebei Zhuanglai Chemical Trading Co Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanxi Naipu Import and Export Co.,Ltd	58
career henan chemical co	58

View Lastest Price from Methyl 2-iodobenzoate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-05-28	Methyl 2-Iodobenzoate 610-97-9	$1.00	1KG	99.%	50 ton	Hebei Chuanghai Biotechnology Co,.LTD
2025-12-12	Methyl 2-iodobenzoate 610-97-9	$1.00	1KG	99.5%	50 tons	Shaanxi Dideu Medichem Co. Ltd
2025-09-25	Methyl 2-iodobenzoate 610-97-9	$1.00-200.00	1KG	99%, 99.5% Sublimated		Henan Fengda Chemical Co., Ltd

Methyl 2-Iodobenzoate
610-97-9
$1.00
99.%
Hebei Chuanghai Biotechnology Co,.LTD

Methyl 2-iodobenzoate
610-97-9
$1.00
99.5%
Shaanxi Dideu Medichem Co. Ltd

Methyl 2-iodobenzoate
610-97-9
$1.00-200.00
99%, 99.5% Sublimated
Henan Fengda Chemical Co., Ltd

Methyl 2-iodobenzoate Spectrum

Methyl 2-iodobenzoate(610-97-9)MS Methyl 2-iodobenzoate(610-97-9)¹HNMR Methyl 2-iodobenzoate(610-97-9)IR1

610-97-9(Methyl 2-iodobenzoate)Related Search:

2-Iodobenzoic acid Kresoxim-methyl Methyl acetate 4-Aminobenzoic acid 2-Nitrobenzoic acid

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Bensulfuron methyl Methylparaben Methyl 4-cyanobenzoate Methyl acrylate Methyl 4-bromobenzoate

Methyl 4-(bromomethyl)benzoate Thiophanate-methyl Methyl 3,5-dihydroxybenzoate

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METHYL O-IODOBENZOATE METHYL 2-IODOBENZOATE BENZOIC ACID, 2-IODO-, METHYL ESTER O-IODOBENZOIC ACID METHYL ESTER RARECHEM AL BF 0562 2-iodo-benzoicacimethylester Benzoic acid, o-iodo-, methyl ester 2-Iodobenzoate 2-IODOBENZOIC AICD METHYLESTER Methyl2-Iodobenzoate(2-IodobenzoicAcidMethylEster) 2-IodobenzoicAcidMethylEsterC8H7IO2 4-Methyl 2-Iodobenzoate (2-Iodobenzoic Acid Methyl Ester) C8H7Io2 Methyl2-iodobenzoate,98% Methyl 2-iodobenzoate, 99+% Methy1 Methyl 2-iodobenzoate 98% Methyl 2-iodobenzo Iodine benzoic acid Methyl ester 2-Iodo Methyl Benzoate 2-(Methoxycarbonyl)-1-iodobenzene methyl iodobenzoate O-Methyl iodide Methyl 2-iodobenzoate, 99+% 25ML Methyl 2-iodobenzoate≥ 99% (GC) Methyl2-Iodobenzoate> 610-97-9 Methyl 2-iodobenzoate 2-Iodo Methyl Benzoate OR Methyl-2-Iodobenzoate OR 2- Iodobenzoic acid methyl Ester. Methyl orthoiodobenzoate Methyl-2-lodobenzoate Methyl-2-iodbenzoat Benzoicacid, o-iodo-, methyl e 2-IODOBENZOIC ACID METHYL ESTER IBM 610-97-9 610-87-9 Organic Building Blocks Esters Building Blocks C8 to C9 Carbonyl Compounds Iodine Compounds C8 to C9 Carbonyl Compounds Esters Aromatic Esters Acids & Esters bc0001 610-97-9