Lithium tetrafluoroborate
- CAS No.
- 14283-07-9
- Chemical Name:
- Lithium tetrafluoroborate
- Synonyms
- LITHIUM BOROFLUORIDE;LiBF4;LiBF4.4H2O;ithium tetrafL;lithiumfluoborate;lithium fluoroborate;Lithium boridefluoride;LITHIUM TETRAFLUOROBORATE;tetrafluoro-borate lithium;Borate,tetrafluoro-,lithium
- CBNumber:
- CB6122283
- Molecular Formula:
- BF4Li
- Molecular Weight:
- 93.75
- MDL Number:
- MFCD00011087
- MOL File:
- 14283-07-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| Lithium tetrafluoroborate Technipur?, ultra dry, powder, 99.99% trace metals basis | 935913 | 250G | $2570 |
| Lithium tetrafluoroborate Technipur?, ultra dry, powder, 99.99% trace metals basis | 935913 | 500G | $4060 |
| Lithium tetrafluoroborate Technipur?, ultra dry, powder, 99.99% trace metals basis | 935913 | 2KG | $14970 |
| Lithium tetrafluoroborate ≥98%, acid <200 ppm, anhydrous | 901695 | 10G | $265 |
| Lithium tetrafluoroborate ≥98%, acid <200 ppm, anhydrous | 901695 | 50G | $819 |
| More product size | |||
| Melting point | 293-300 °C (dec.) (lit.) |
|---|---|
| Density | 0.852 g/mL at 25 °C |
| vapor pressure | 10Pa at 20℃ |
| Flash point | 6 °C |
| storage temp. | Store below +30°C. |
| solubility | soluble in Acetonitrile, DMSO |
| form | powder |
| Specific Gravity | 0.852 |
| color | White to off-white |
| PH | 2.88 |
| Water Solubility | SOLUBLE |
| Sensitive | Hygroscopic |
| Merck | 14,5543 |
| Exposure limits |
ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3 |
| Stability | Stable. Incompatible with glass, acids, strong bases. Contact with acids releases toxic gas. Moisture-sensitive. |
| Major Application | battery manufacturing |
| InChI | 1S/BF4.Li/c2-1(3,4)5;/q-1;+1 |
| InChIKey | UFXJWFBILHTTET-UHFFFAOYSA-N |
| SMILES | [Li+].F[B-](F)(F)F |
| CAS DataBase Reference | 14283-07-9(CAS DataBase Reference) |
| FDA UNII | AF751CNK2N |
| EPA Substance Registry System | Borate(1-), tetrafluoro-, lithium (14283-07-9) |
| UNSPSC Code | 12352302 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H314-H341 | |||||||||
| Precautionary statements | P260-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | C,T,F,Xn | |||||||||
| Risk Statements | 20/21/22-31-34-36/37/38-23/24/25-11-36/38 | |||||||||
| Safety Statements | 22-26-27-36/37/39-45-25-16-36/37 | |||||||||
| RIDADR | UN 3260 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| Hazard Note | Corrosive/Hygroscopic | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28269090 | |||||||||
| Storage Class | 8B - Non-combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Dam. 1 Muta. 2 Skin Corr. 1B |
|||||||||
| Toxicity | LD50 orally in Rabbit: 1638 mg/kg LD50 dermal Rat > 2000 mg/kg | |||||||||
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
Lithium tetrafluoroborate price More Price(53)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 935913 | Lithium tetrafluoroborate Technipur?, ultra dry, powder, 99.99% trace metals basis | 14283-07-9 | 250G | $2570 | 2026-03-19 | Buy |
| Sigma-Aldrich | 935913 | Lithium tetrafluoroborate Technipur?, ultra dry, powder, 99.99% trace metals basis | 14283-07-9 | 500G | $4060 | 2026-03-19 | Buy |
| Sigma-Aldrich | 935913 | Lithium tetrafluoroborate Technipur?, ultra dry, powder, 99.99% trace metals basis | 14283-07-9 | 2KG | $14970 | 2026-03-19 | Buy |
| Sigma-Aldrich | 901695 | Lithium tetrafluoroborate ≥98%, acid <200 ppm, anhydrous | 14283-07-9 | 10G | $265 | 2026-03-19 | Buy |
| Sigma-Aldrich | 901695 | Lithium tetrafluoroborate ≥98%, acid <200 ppm, anhydrous | 14283-07-9 | 50G | $819 | 2026-03-19 | Buy |
Lithium tetrafluoroborate Chemical Properties,Uses,Production
Description
Lithium tetrafluoroborate, (LiBF4), lithium hexafluorophosphate, (LiPF6), lithium hexafluoroarsenate, (LiAsF6), lithium trifluoromethane sulfonate, (LiSO3CF3), are the electrolyte salts of the 21st Century. The performance of lithium ion cells, primary and secondary lithium cells depends on the purity of these compounds. Several hundred tons of these materials have been produced and many more tons -- and perhaps thousands of tons w will be required in the near future. One of the largest automotive producers predicts that there may be a market for 10-15 million pounds of these salts. The demand for Lithium ion primary cells is also very huge in electronics, computers, communication systems and military applications.
Preparation
Lithium tetrafluoroborate, LiBF4, is prepared by dissolving LiF in AHF and then BF3 gas is passed until precipitation is complete. After the reaction is over, excess HF is decanted and LiBF4 is dried under nitrogen until HF and H20 contents are reduced below 100 ppm level. Reaction is carried out in Teflon(R), polyethylene or polypropylene lined reactors to avoid metallic contamination.
Chemical Properties
white powder
Uses
Catalyst in organic synthesis; electrolyte for lithium ion batteries.
Uses
Lithium tetrafluoroborate is a mild Lewis acid for Diels-Alder reactions. Catalyst for mild and efficient aminolysis of oxiranes. It is a reagent used in the preparation of rechargeable lithium-ion batteries.
Uses
Lithium tetrafluoroborate (LiBF4) finds application as electrolyte material in lithium ion batteries (LIBs). However, the presence of trace amount of water in LiBF4 causes its hydrolysis which leads to HF generation and destruction of the battery electrodes. Our LiBF4 contains < 100 ppm of water and is well suited for applications in LIBs.
General Description
This product has been enhanced for energy efficiency.
Flammability and Explosibility
Not classified
Purification Methods
Dissolve it in THF just below its solubility, filter from insoluble material and evaporate it to dryness in a vacuum below 50o. Wash the residue with dry Et2O, and pass dry N2 gas over the solid and finally heat it in an oven at 80-90o. Its solubility in Et2O is 1.3g in 100mL at 25o; in THF it is 71g in 100mL at 25o. It is hygroscopic and is an IRRITANT. [Elliott et al. J Am Chem Soc 74 5211 1952, 75 1753 1953.]
Lithium tetrafluoroborate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| changzhou huayang technology co., ltd | +8615250961469 | 2571773637@qq.com | China | 9653 | 58 |
| Shijiazhuang Jianxin Biotechnology Co., LTD | +undefined-86-1906231316-9 +undefined86-19062313169 | liyingjian1997@gmail.com | China | 712 | 58 |
| Fujian Sanming Fengyuan New Material Technology Co., Ltd | +86-18806082718 +86-15080556561 | sales2@fengyuangroup.com | China | 39 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8618531123677 | faithe@yan-xi.com | China | 5853 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-86-13131129325 +8613131129325 | sales1@chuanghaibio.com | China | 5235 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3692 | 58 |
| Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 880 | 50 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13815 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21592 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
Related articles
- Lithium Tetrafluoroborate: Applications in the Development of Lithium Batteries and its Toxicity
- Lithium tetrafluoroborate (LiBF4) is widely used as an electrolyte for primary and secondary batteries.
- Dec 10，2024
View Lastest Price from Lithium tetrafluoroborate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-04-24 | Lithium tetrafluoroborate
14283-07-9
|
US $1.00 / kg | 1kg | 99.8% | 500000 | HANGZHOU HAILAN CHEMICAL CO.,LTD. | |
 |
2026-04-24 | Lithium tetrafluoroborate
14283-07-9
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2026-04-24 | Lithium tetrafluoroborate
14283-07-9
|
US $0.00 / KG | 1KG | 0.99 | 2 tons/year | Fujian Sanming Fengyuan New Material Technology Co., Ltd |
-
- Lithium tetrafluoroborate
14283-07-9
- US $1.00 / kg
- 99.8%
- HANGZHOU HAILAN CHEMICAL CO.,LTD.
-
- Lithium tetrafluoroborate
14283-07-9
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Lithium tetrafluoroborate
14283-07-9
- US $0.00 / KG
- 0.99
- Fujian Sanming Fengyuan New Material Technology Co., Ltd
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