ChemicalBook >> CAS DataBase List >>4-Chlorothiophenol
4-Chlorothiophenol
- CAS No.
- 106-54-7
- Chemical Name:
- 4-Chlorothiophenol
- Synonyms
- 4-CHLOROBENZENETHIOL;4-Chloro;PARA-CHLOROTHIOPHENOL;NSC 229564;orothiophenoL;p-Chlorthiofenol;4-CHLOROTHIOPENOL;4-chlorthiophenol;AKOS BBS-00004252;CHLOROTHIOPHENOL-4
- CBNumber:
- CB6130893
- Molecular Formula:
- C6H5ClS
- Molecular Weight:
- 144.62
- MDL Number:
- MFCD00004847
- MOL File:
- 106-54-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-04-24 14:58:38
| Product description | Number | Pack Size | Price |
| 4-Chlorothiophenol 97% | 125237 | 5g | $50.3 |
| 4-Chlorothiophenol 97% | 125237 | 100g | $121 |
| 4-Chlorobenzenethiol >98.0%(GC)(T) | C0129 | 25g | $67 |
| 4-Chlorobenzenethiol >98.0%(GC)(T) | C0129 | 500g | $228 |
| 4-Chlorothiophenol 97% | 125237 | 500g | $485 |
| More product size | |||
| Melting point | 49-51 °C(lit.) |
|---|---|
| Boiling point | 205-207 °C(lit.) |
| Density | 1.1911 |
| refractive index | 1.5480 |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | methanol: soluble |
| pka | pK1:5.9 (25°C) |
| form | Crystalline Solid |
| color | White to almost white |
| Water Solubility | insoluble |
| Sensitive | Stench/Lachrymatory |
| BRN | 605971 |
| InChI | 1S/C6H5ClS/c7-5-1-3-6(8)4-2-5/h1-4,8H |
| InChIKey | VZXOZSQDJJNBRC-UHFFFAOYSA-N |
| SMILES | Sc1ccc(Cl)cc1 |
| CAS DataBase Reference | 106-54-7(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 1O71UA6O72 |
| NIST Chemistry Reference | Benzenethiol, 4-chloro-(106-54-7) |
| EPA Substance Registry System | Benzenethiol, 4-chloro- (106-54-7) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H314 | |||||||||
| Precautionary statements | P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 22-34-36/37-20/21/22 | |||||||||
| Safety Statements | 26-36/37/39-45-27 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | DC1050000 | |||||||||
| F | 9-13-23 | |||||||||
| Hazard Note | Corrosive/Lachrymatory/Stench | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29309090 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Skin Corr. 1B |
|||||||||
| Limited Quantities | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
4-Chlorothiophenol price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 125237 | 4-Chlorothiophenol 97% | 106-54-7 | 5g | $50.3 | 2026-04-30 | Buy |
| Sigma-Aldrich | 125237 | 4-Chlorothiophenol 97% | 106-54-7 | 100g | $121 | 2026-04-30 | Buy |
| TCI Chemical | C0129 | 4-Chlorobenzenethiol >98.0%(GC)(T) | 106-54-7 | 25g | $67 | 2026-04-30 | Buy |
| TCI Chemical | C0129 | 4-Chlorobenzenethiol >98.0%(GC)(T) | 106-54-7 | 500g | $228 | 2026-04-30 | Buy |
| Sigma-Aldrich | 125237 | 4-Chlorothiophenol 97% | 106-54-7 | 500g | $485 | 2026-04-30 | Buy |
4-Chlorothiophenol Chemical Properties,Uses,Production
Chemical Properties
white to almost white crystalline solid
Uses
Oil additives, agricultural chemicals, plasticizers, rubber chemical, dyes, wetting agents, and stabilizers.
Uses
4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups.
Synthesis Reference(s)
The Journal of Organic Chemistry, 27, p. 4455, 1962 DOI: 10.1021/jo01059a081
Synthetic Communications, 18, p. 575, 1988 DOI: 10.1080/00397918808064014
General Description
4-Chlorothiophenol undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides.
Hazard
Toxic by ingestion.
Purification Methods
Recrystallise the thiophenol from aqueous EtOH. The SMe ether has m 129o and the SEt ether has m 64o. [D'Sousa et al. J Org Chem 52 1720 1987, Beilstein 6 H 326, 6 I 149, 6 III 1034.]
4-Chlorothiophenol Preparation Products And Raw materials
Raw materials
Preparation Products
2-CHLORO-9-(3-(DIMETHYLAMINO)PROPYL)-TH&
5-CHLORO-3-METHYLBENZO[B]THIOPHENE-2-SULFONAMIDE
5-CHLORO-3-METHYLBENZO[B]THIOPHENE
5-CHLORO-BENZO[B]THIOPHENE-3-CARBOXYLIC ACID
1-(5-CHLOROBENZO[B]THIOPHEN-3-YL)ETHANONE
CHLOROMETHYL 4-CHLOROPHENYL SULFIDE
CARBOPHENOTHION
2-Chlorothioxanthone
5-CHLOROBENZOTHIOPHENE
(5-CHLORO-1-BENZOTHIOPHEN-3-YL)METHANOL
1of4
Global( 285)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8738 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-86-13131129325 +8613131129325 | sales1@chuanghaibio.com | China | 5235 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29640 | 60 |
| Dalian Richfortune Chemicals Co., Ltd | +86-86-411-84820922 +86-8613904096939 | sales@richfortunechem.com | China | 305 | 57 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21590 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29819 | 58 |
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| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| Nanjing jinheyou Trading Co., Ltd. | 15705188088 | admin@jheyou.com | CHINA | 1268 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
View Lastest Price from 4-Chlorothiophenol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-03-20 | 4-Chlorothiophenol
106-54-7
|
US $10.00 / KG | 1KG | 99% | 100 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-05-26 | 4-Chlorothiophenol
106-54-7
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | |
 |
2019-11-08 | 4-Chlorothiophenol
106-54-7
|
US $0.00 / g | 1g | 98%min | 20kg/month | Nanjing jinheyou Trading Co., Ltd. |
-
- 4-Chlorothiophenol
106-54-7
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- 4-Chlorothiophenol
106-54-7
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
-
- 4-Chlorothiophenol
106-54-7
- US $0.00 / g
- 98%min
- Nanjing jinheyou Trading Co., Ltd.
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