(15bS)-9,10,15b,16-Tetrahydro-5,15-dimethoxy-1H,7H-[1,3]benzodioxino[6,5-g][1,3]benzodioxolo[5,6-a]quinolizine
![(15bS)-9,10,15b,16-Tetrahydro-5,15-dimethoxy-1H,7H-[1,3]benzodioxino[6,5-g][1,3]benzodioxolo[5,6-a]quinolizine Structure](CAS/GIF/23943-90-0.gif)
- CAS No.
- 23943-90-0
- Chemical Name:
- (15bS)-9,10,15b,16-Tetrahydro-5,15-dimethoxy-1H,7H-[1,3]benzodioxino[6,5-g][1,3]benzodioxolo[5,6-a]quinolizine
- Synonyms
- Bractavine;Orientalidine;(15bS)-9,10,15b,16-Tetrahydro-5,15-dimethoxy-1H,7H-[1,3]benzodioxino[6,5-g][1,3]benzodioxolo[5,6-a]quinolizine;1H,7H-[1,3]Benzodioxino[6,5-g][1,3]benzodioxolo[5,6-a]quinolizine, 9,10,15b,16-tetrahydro-5,15-dimethoxy-, (15bS)- (9CI)
- CBNumber:
- CB62163525
- Molecular Formula:
- C22H23NO6
- Molecular Weight:
- 397.42
- MDL Number:
- MOL File:
- 23943-90-0.mol
(15bS)-9,10,15b,16-Tetrahydro-5,15-dimethoxy-1H,7H-[1,3]benzodioxino[6,5-g][1,3]benzodioxolo[5,6-a]quinolizine Chemical Properties,Uses,Production
Description
This alkaloid from Papaver orientale forms colourless crystals from AcOEt and has [α] 22 D- 254° ± 4° (c 0.31, MeOH). It forms a methiodide, m.p. 252-3°C, a methine, m.p. 195-7°C and dimethine, m.p. l46-8°C. Exhaustive methylation gives trimethylamine and a nitrogen-free oil as the final products. Oxidation of the alkaloid with chromic acid or KMn04 yields Alkaloid PO-4 (q.v.). When refluxed with 5 per cent H2S04 the base yields formaldehyde which may arise from either the hydrolysis of the methylenedioxy group or, more probably, that of the 1: 3-benzodioxan group.
References
Preininger et al., Collect. Czech. Chern. Cornrnun., 34,875 (1969)
