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2'-BROMO-4-CHLORO-BIPHENYL

CAS No.
179526-95-5
Chemical Name:
2'-BROMO-4-CHLORO-BIPHENYL
Synonyms
2-Bromo-4’-chlorobiphenyl;2-Bromo-4`-chloro-bipheny;2'-BROMO-4-CHLORO-BIPHENYL;2-Bromo-4'-chloro-1'-biphenyl;2-Bromo-4'-chloro-1,1'-biphenyl;2-bromo-2-(4-chlorophenyl)benzene;1,1'-Biphenyl, 2-bromo-4'-chloro-;1-bromo-2-(4-chlorophenyl)benzene;l-bromo-2-(4-chlorophenyl)benzene;Boronic, B-(4'-chloro[1,1'-biphenyl]-2-yl)-
CBNumber:
CB62500320
Molecular Formula:
C12H8BrCl
Molecular Weight:
267.55
MDL Number:
MFCD18072809
MOL File:
179526-95-5.mol
Last updated:2025-07-24 18:13:40
Product description Number Pack Size Price
2'-Bromo-4-chlorobiphenyl B5253 1G $166
2'-BROMO-4-CHLORO-BIPHENYL 95.00% HCH0143879 5MG $501.04
2'-Bromo-4-chloro-biphenyl Y8035 25g $358
2'-Bromo-4-chloro-biphenyl Y8035 100g $795
2-Bromo-4'-chloro-1,1'-biphenyl 97% CD41001733 10g $376
More product size

2'-BROMO-4-CHLORO-BIPHENYL Properties

Melting point 41 °C
Boiling point 325.5±17.0 °C(Predicted)
Density 1.463
storage temp. Sealed in dry,Room Temperature
form powder to lump
color White to Orange to Green
InChI InChI=1S/C12H8BrCl/c13-12-4-2-1-3-11(12)9-5-7-10(14)8-6-9/h1-8H
InChIKey WSHZWUXRWQVZQP-UHFFFAOYSA-N
SMILES C1(C2=CC=C(Cl)C=C2)=CC=CC=C1Br

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H335-H319-H315
Precautionary statements  P264-P270-P301+P312-P330-P501-P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
HS Code  2903.99.8001

2'-BROMO-4-CHLORO-BIPHENYL price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B5253 2'-Bromo-4-chlorobiphenyl 179526-95-5 1G $166 2025-07-31 Buy
American Custom Chemicals Corporation HCH0143879 2'-BROMO-4-CHLORO-BIPHENYL 95.00% 179526-95-5 5MG $501.04 2021-12-16 Buy
AK Scientific Y8035 2'-Bromo-4-chloro-biphenyl 179526-95-5 25g $358 2021-12-16 Buy
AK Scientific Y8035 2'-Bromo-4-chloro-biphenyl 179526-95-5 100g $795 2021-12-16 Buy
Crysdot CD41001733 2-Bromo-4'-chloro-1,1'-biphenyl 97% 179526-95-5 10g $376 2021-12-16 Buy
Product number Packaging Price Buy
B5253 1G $166 Buy
HCH0143879 5MG $501.04 Buy
Y8035 25g $358 Buy
Y8035 100g $795 Buy
CD41001733 10g $376 Buy

2'-BROMO-4-CHLORO-BIPHENYL Chemical Properties,Uses,Production

Chemical Properties

off-white solid

Synthesis

1-Bromo-2-iodobenzene

583-55-1

4-Chlorophenylboronic acid

1679-18-1

2'-BROMO-4-CHLORO-BIPHENYL

179526-95-5

1-Bromo-2-iodobenzene (30 g, 106 mmol) and 4-chlorophenylboronic acid (16.9 g, 108.6 mmol) were added to an aqueous 2M potassium carbonate solution (100 ml) in dioxane solution. Subsequently, tetrakis(triphenylphosphine)palladium (2.45 g, 2 mol%) was added as a catalyst. The reaction mixture was heated and reacted under stirring for 4 hours. After completion of the reaction, it was cooled to room temperature and the reaction was quenched with potassium carbonate solution followed by separation of the aqueous and organic layers. After the organic layer was concentrated under reduced pressure to remove the solvent, it was purified by column chromatography (eluent: hexane) to afford the target product 2-bromo-4'-chloro-1,1'-biphenyl (A1) as a white solid (25.3 g, 90% yield).

References

[1] Patent: KR2017/41159, 2017, A. Location in patent: Paragraph 0274-0276
[2] Organic Letters, 2015, vol. 17, # 2, p. 386 - 389
[3] Organic Letters, 2013, vol. 15, # 24, p. 6186 - 6189
[4] Advanced Synthesis and Catalysis, 2018, vol. 360, # 16, p. 3049 - 3054
[5] Chemical Communications, 2014, vol. 50, # 17, p. 2193 - 2195

583-55-1
1679-18-1
179526-95-5
Synthesis of 2'-BROMO-4-CHLORO-BIPHENYL from 1-Bromo-2-iodobenzene and 4-Chlorophenylboronic acid

2'-BROMO-4-CHLORO-BIPHENYL Preparation Products And Raw materials

Global( 147)Suppliers
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Zhejiang Free Trade Zone Violet Trade Co., Ltd.
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View Lastest Price from 2'-BROMO-4-CHLORO-BIPHENYL manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromo-4'-chloro-1,1'-biphenyl pictures 2025-09-25 2-Bromo-4'-chloro-1,1'-biphenyl
179526-95-5
US $200.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2-bromo-2-(4-chlorophenyl)benzene pictures 2025-09-15 2-bromo-2-(4-chlorophenyl)benzene
179526-95-5
US $0.00 / KG 10g 99.5% 5TOS Zhejiang Free Trade Zone Violet Trade Co., Ltd.
2'-BROMO-4-CHLORO-BIPHENYL pictures 2025-06-27 2'-BROMO-4-CHLORO-BIPHENYL
179526-95-5
US $30.00-10.00 / KG 50KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd

2'-BROMO-4-CHLORO-BIPHENYL Spectrum

1,1'-Biphenyl, 2-bromo-4'-chloro- 2'-BROMO-4-CHLORO-BIPHENYL 2-Bromo-4'-chloro-1,1'-biphenyl 2-Bromo-4`-chloro-bipheny 1-bromo-2-(4-chlorophenyl)benzene 2-Bromo-4'-chloro-1'-biphenyl 2-bromo-2-(4-chlorophenyl)benzene Boronic, B-(4'-chloro[1,1'-biphenyl]-2-yl)- l-bromo-2-(4-chlorophenyl)benzene 2-Bromo-4’-chlorobiphenyl 179526-95-5 C12H8BrCl