Nonafluorobutane-1-sulfonic acid
- CAS No.
- 375-73-5
- Chemical Name:
- Nonafluorobutane-1-sulfonic acid
- Synonyms
- PERFLUOROBUTANE SULFONIC ACID;NONAFLUORO-1-BUTANESULFONIC ACID;1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonic acid;PERFLUORO-1-BUTANESULFONIC ACID;Perfluorobutane-1-sulphonic acid;NONAFLUOROBUTANESULFONIC ACID;Nonafluorobutanesulphonic acid hydrate;Nonafluorobutanesulphonic acid hydrate 95%;1,1,2,2,3,3,4,4,4-NONAFLUORO-1-BUTANESULFONIC ACID;NonafL
- CBNumber:
- CB6321385
- Molecular Formula:
- C4HF9O3S
- Molecular Weight:
- 300.1
- MDL Number:
- MFCD01320794
- MOL File:
- 375-73-5.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| Nonafluorobutane-1-sulfonic acid 97% | 562629 | 5g | $64.7 |
| Nonafluorobutane-1-sulfonic acid 97% | 562629 | 25g | $306 |
| Nonafluorobutane-1-sulfonic acid certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland | 93634 | 1 unit | $136 |
| Nonafluoro-1-butanesulfonic Acid >98.0%(T) | N0709 | 5g | $63 |
| Nonafluoro-1-butanesulfonic Acid >98.0%(T) | N0709 | 25g | $220 |
| More product size | |||
| Boiling point | 112-114 °C/14 mmHg (lit.) |
|---|---|
| Density | 1.811 g/mL at 25 °C (lit.) |
| vapor pressure | 7Pa at 20℃ |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Soluble in water |
| pka | -3.57±0.50(Predicted) |
| form | clear liquid |
| color | Colorless to Light yellow to Light orange |
| Water Solubility | 1000g/L at 20℃ |
| Henry's Law Constant | 2.0×100 mol/(m3Pa) at 25℃, Plassmann et al. (2011) |
| InChI | InChI=1S/C4HF9O3S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h(H,14,15,16) |
| InChIKey | JGTNAGYHADQMCM-UHFFFAOYSA-N |
| SMILES | C(F)(F)(S(O)(=O)=O)C(F)(F)C(F)(F)C(F)(F)F |
| LogP | -0.34 at 23℃ |
| Substances of Very High Concern (SVHC) Candidate List | Perfluorobutane sulfonic acid (PFBS) and its salts (375-73-5) |
| CAS DataBase Reference | 375-73-5(CAS DataBase Reference) |
| FDA UNII | 1FV02N6NVO |
| EPA Substance Registry System | Perfluorobutanesulfonic acid (375-73-5) |
| UNSPSC Code | 12352100 |
| NACRES | NA.24 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H314 | |||||||||
| Precautionary statements | P270-P280-P301+P312-P301+P330+P331-P303+P361+P353-P305+P351+P338 | |||||||||
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 14-22-34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3265 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | EK5930000 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | CORROSIVE | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29049090 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Dam. 1 Skin Corr. 1B |
|||||||||
| Hazardous Substances Data | 375-73-5(Hazardous Substances Data) | |||||||||
| Toxicity | LD50 orl-rat: 430 mg/kg ATDAEI 15(Suppl 1),S105,1996 | |||||||||
| REACH Registrations | Active | |||||||||
| NFPA 704 |
|
Nonafluorobutane-1-sulfonic acid price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 562629 | Nonafluorobutane-1-sulfonic acid 97% | 375-73-5 | 5g | $64.7 | 2026-04-30 | Buy |
| Sigma-Aldrich | 562629 | Nonafluorobutane-1-sulfonic acid 97% | 375-73-5 | 25g | $306 | 2026-04-30 | Buy |
| Sigma-Aldrich | 93634 | Nonafluorobutane-1-sulfonic acid certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland | 375-73-5 | 1 unit | $136 | 2025-07-31 | Buy |
| TCI Chemical | N0709 | Nonafluoro-1-butanesulfonic Acid >98.0%(T) | 375-73-5 | 5g | $63 | 2026-04-30 | Buy |
| TCI Chemical | N0709 | Nonafluoro-1-butanesulfonic Acid >98.0%(T) | 375-73-5 | 25g | $220 | 2026-04-30 | Buy |
Nonafluorobutane-1-sulfonic acid Chemical Properties,Uses,Production
Chemical Properties
Nonafluorobutane-1-sulfonic acid is a colorless liquid. Perfluoro butyl sulfonate has the ability to react violently with water, so preventing exposure tomoisture should be a priority. It may also be incompatible with strong oxidizers. Upon decomposition, PFBS can form carbon oxides, sulfur oxides, and hydrogen fluoride.
Uses
Perfluoro butyl sulfonate (PFBS, nonafluoro-1-butanesulfonic acid, perfluorobutane sulfonic acid, 1-perfluorobutane sulfonic acid) is a four-carbon compound in the perfluoroalkyl family of chemicals. It can be found in stain repellents used for carpets and furniture. A specific form of the chemical, potassium perfluorobutane sulfonate, is being used as a flame retardant in place of brominated retardants. Perfluoro butyl sulfonate is being used as a substitute for other perfluoroalkyl compounds because it is not believed to bioaccumulate in the environment.
Nonafluorobutane-1-sulfonic acid can be considered as a superacid, which can be synthesized by reacting 1-iodononafluorobutane with sodium dithionite in the presence of sodium bicarbonate in acetonitrile/water.
Nonafluorobutane-1-sulfonic acid may be used as catalyst in the synthesis of 6-chloro-6H-dibenz[c,e][1,2]oxaphosphorin and N-benzylpyridin-2-amine.
Uses
Nonafluorobutane-1-sulfonic acid may be used as catalyst in the synthesis of 6-chloro-6H-dibenz[c,e][1,2]oxaphosphorin and N-benzylpyridin-2-amine.
Definition
ChEBI: A perfluoroalkanesulfonic acid that is butane-1-sulfonic acid in which all of the hydrogens of the butyl group have been replaced by fluorines.
General Description
Nonafluorobutane-1-sulfonic acid can be considered as a superacid, which can be synthesized by reacting 1-iodononafluorobutane with sodium dithionite in the presence of sodium bicarbonate in acetonitrile/water.
Safety Profile
A poison by ingestion.When heated to decomposition it emits toxic vapors of SOx and Clí.
Synthesis
Anhydrous sulfuric acid (37 g, 360 moles) was placed in a glass round-bottomed flask equipped with a magnetic stir bar, a reflux condenser, a thermometer, and a solid dispenser. Perfluorobutane sulfonate sodium salt (C4F9SO3Na, 35 g, 109 mmol) was placed in the dispenser and added to the acid for 10 minutes. No exothermic reaction was observed. The mixture was stirred at 120°C for 30 minutes at 1,000 rpm. 19F-NMR followed the progress of the reaction. Once the complete conversion of acid was observed, the internal temperature was raised to 140°C, and a vacuum (0.8 mbar residual pressure) was applied to the reaction mixture to distill Nonafluorobutane-1-sulfonic acid as a clear liquid.
Environmental Fate
Perfluoro butyl sulfonate is embedded into the carpet and furniture to offer protection against stains and spills. It is also applied to various household products as it may play a role in the retarding of flames during a fire. Over time as furniture, carpet, and other household products begin to degrade, the chemical may be introduced into the indoor environment in house dust. Perfluoro butyl sulfonate, along with other perfluoroalkyl compounds, has been detected in house dust samples indicating a potential route for exposure for occupants (Strynar and Lindstrom, 2008). Frequent vacuuming and dust removal can prevent buildup of the contaminant in household dust and the indoor environment. Perfluoro butyl sulfonate can also be found in water systems as a result of human waste streams. Samples of tap water collected in China, Japan, India, the United States, and Canada, all contained detectable levels of PFBS (Mak et al., 2009). While the chemical has been detected in both the indoor environment and drinking water, the lack of toxicological data related to PFBS makes it hard to determine what levels of exposure are acceptable.
Nonafluorobutane-1-sulfonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| JIANGXI TIME PHARMACEUTICAL CO.,LTD | +86-0794-7183888 +86-13155888520 | sales@groupchem.com | China | 27 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-173 9270 1263 | 1057@dideu.com | China | 3957 | 58 |
| Kindchem(Nanjing)Co.,Ltd | +86-025-025-85281586 18651653755 | sales@kindchem.cn | China | 1226 | 58 |
| Shandong Deshang Chemical Co., Ltd. | +86-0531-8875-2665 +86-13153039501 | info@deshangchem.com | China | 661 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21585 | 55 |
| Fluoropharm Co., Ltd. | +86-0571-85586753 +86-13336034509 | sales@fluoropharm.com | China | 1445 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29812 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5906 | 58 |
| BOC Sciences | +1-631-485-4226 | inquiry@bocsci.com | United States | 19936 | 58 |
| Changzhou Carman Chemical Co., Ltd. | 15061933924 | CHINA | 514 | 58 |
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View Lastest Price from Nonafluorobutane-1-sulfonic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-07-31 | Nonafluorobutane-1-sulfonic acid
375-73-5
|
1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | ||
 |
2025-04-10 | CHLUMOFIUOR? Perfluorobutanesulfonic acid
375-73-5
|
1kg | 99% | 20 tons | Changyi Longchang Bio-Chemical Co., LTD | ||
 |
2025-04-04 | Nonafluorobutane-1-sulfonic acid
375-73-5
|
1KG | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd.
|
-
- Nonafluorobutane-1-sulfonic acid
375-73-5
- $0.00
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- CHLUMOFIUOR? Perfluorobutanesulfonic acid
375-73-5
- $0.00
- 99%
- Changyi Longchang Bio-Chemical Co., LTD
-
- Nonafluorobutane-1-sulfonic acid
375-73-5
- 98%
- Henan Aochuang Chemical Co.,Ltd.
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