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1-Naphthaldehyde

CAS No.
66-77-3
Chemical Name:
1-Naphthaldehyde
Synonyms
naphthalene-1-carbaldehyde;naphthal;alpha-Naphthal;NAPHTHALENE-1-ALDEHYDE;1-Naphthalenecarboxaldehyde;alpha-Naphthylcarboxaldehyde;Naphthalene-1-carboxaldehyde;1-NAPHTHYLALDEHYDE;ALPHA-NAPHTHALDEHYDE;alpha-Naphthylaldehyde
CBNumber:
CB6423090
Molecular Formula:
C11H8O
Molecular Weight:
156.18
MDL Number:
MFCD00004003
MOL File:
66-77-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 05:20:59
Product description Number Pack Size Price
1-Naphthaldehyde 95% N109 2g $56
1-Naphthaldehyde 95% N109 100g $73.1
1-Naphthaldehyde 95% N109 500g $275
1-Naphthaldehyde >95.0%(GC) N0002 25mL $39
1-Naphthaldehyde >95.0%(GC) N0002 100mL $88
More product size

1-Naphthaldehyde Properties

Melting point 1-2 °C (lit.)
Boiling point 160-161 °C/15 mmHg (lit.)
Density 1.15 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
refractive index n20/D 1.652(lit.)
Flash point >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility <1g/l
form Liquid
Specific Gravity 1.15
color Clear yellow to dark yellow-brown
PH 7 (< 1g/l, H2O, 20℃)
Water Solubility Soluble in ethanol, ether, acetone, benzene. Insoluble in water.
Sensitive Air Sensitive
BRN 386082
InChI 1S/C11H8O/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-8H
InChIKey SQAINHDHICKHLX-UHFFFAOYSA-N
SMILES [H]C(=O)c1cccc2ccccc12
CAS DataBase Reference 66-77-3(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII H3I0B5F8SX
NIST Chemistry Reference 1-Naphthalenecarboxaldehyde(66-77-3)
EPA Substance Registry System 1-Naphthaldehyde (66-77-3)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P501
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  37/39-26-24/25-36/37-23-36-16
RIDADR  3082
WGK Germany  3
RTECS  QJ0190000
TSCA  TSCA listed
PackingGroup  III
HS Code  29122900
Storage Class 10 - Combustible liquids
Hazard Classifications Acute Tox. 4 Oral
NFPA 704
0
1 0

1-Naphthaldehyde price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich N109 1-Naphthaldehyde 95% 66-77-3 2g $56 2026-04-30 Buy
Sigma-Aldrich N109 1-Naphthaldehyde 95% 66-77-3 100g $73.1 2026-04-30 Buy
Sigma-Aldrich N109 1-Naphthaldehyde 95% 66-77-3 500g $275 2026-04-30 Buy
TCI Chemical N0002 1-Naphthaldehyde >95.0%(GC) 66-77-3 25mL $39 2026-04-30 Buy
TCI Chemical N0002 1-Naphthaldehyde >95.0%(GC) 66-77-3 100mL $88 2026-04-30 Buy
Product number Packaging Price Buy
N109 2g $56 Buy
N109 100g $73.1 Buy
N109 500g $275 Buy
N0002 25mL $39 Buy
N0002 100mL $88 Buy

1-Naphthaldehyde Chemical Properties,Uses,Production

Applications

1-Naphthaldehyde is used as a reagent in the synthesis of phosphors without rare-earth elements for eco-energy lighting based LEDs. It is also used in the synthesis of 1-Naphthoic Acid and 1-Naphthalenemethanol.
1-Naphthaldehyde

Appearance

Clear Colorless to Pale Yellow Oil

Dangerous Goods Info

Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package

Chemical Properties

Yellow liquid

Uses

1-Naphthaldehyde is used in the synthesis of single-crystalline homochiral porous metal-organic frameworks (MOFs). It is also a starting material for the Canizzaro reaction to produce 1-Naphthoic acid and 1-Naphthalenemethanol.

Uses

1-Naphthaldehyde can be used to synthesize:

  • (S)-1-α-naphthyl-1-ethanol
  • N-(4-aryl)-N-(α-naphthyliden)amines
  • N-aryl-N-[1-(1-naphthyl)but-3-enyl]amines
  • naphthalene-1-carboxylic acid methyl ester

Definition

ChEBI: A naphthaldehyde with a formyl group at position 1.

Synthesis Reference(s)

Tetrahedron, 41, p. 5703, 1985 DOI: 10.1016/S0040-4020(01)91375-4

Purification Methods

Distil 1-naphthaldehyde with steam, extract the distillate into Et2O, dry (Na2SO4), filter, evaporate the filtrate and distil the residue in a vacuum. [Beilstein 7 IV 1286.]

Global( 463)Suppliers
Supplier Tel Email Country ProdList Advantage
Xiamen AmoyChem Co., Ltd
+86-86-5926051114 +8615060885618 sales@amoychem.com China 6366 58
Shandong Xingshun New Material Co., Ltd.
+86-0519-86461196 gxx@xingshengtech.com China 552 58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 16513 58
Wuhan Fortuna Chemical Co., Ltd
+86-27-59207850 info@fortunachem.com China 5983 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615531151365 mina@chuanghaibio.com China 18126 58
Wuhan Fortuna Chemical Co.,Ltd
+86-2759207851; +8618007136271 hk@fortunachem.com China 6008 58
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+8613336195806 sales@capot.com China 29640 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 13901 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21588 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60

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View Lastest Price from 1-Naphthaldehyde manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Naphthaldehyde pictures 2026-05-29 1-Naphthaldehyde
66-77-3
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1-Naphthaldehyde pictures 2026-05-29 1-Naphthaldehyde
66-77-3
US $0.00-0.00 / KG 1KG 99% 20TONS Wuhan Fortuna Chemical Co.,Ltd
naphthal pictures 2026-04-17 naphthal
66-77-3
US $50.00-10.00 / kg 1kg 99%,Electronic grade(Single metal impurity≤ 100ppb) or pharmaceutical grade 1000kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
  • naphthal pictures
  • naphthal
    66-77-3
  • US $50.00-10.00 / kg
  • 99%,Electronic grade(Single metal impurity≤ 100ppb) or pharmaceutical grade
  • ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
alpha-Naphthylaldehyde -Naphthaldehdye ALPHA-NAPHTHALDEHYDE AKOS BBS-00003152 1-NAPHTHALDEHYDE 1-NAPHTHALENECARBALDEHYDE 1-NAPHTHYLALDEHYDE 1-FORMYLNAPHTHALENE NAPHTHALENE-A-ALDEHYDE NAPHTHALENE-1-ALDEHYDE 1-Naphthaldehdye 1-naphthaldehyde (alpha) A-NAPHTHALDEHYDE 1-NAPHTHALDEHYDE 97+% 1-Naphthaldehyde,97.7% 1-naphthaldehyde-Naphthaldehdye I-Naphthaldehyd 21) 1-NAPHTHALDEHYDE 1-Naphthaldehyde(alpha)Naphthaldehdye 1-ANPHTHALDEHYDE 1-Naphthaldehyde, 95% 100GR 1-Naphthaldehyde, 95% 500GR 1-Naphthaldehyde,95% 1-Naphthaldehyde 95% 1-Naphthaldehyde, 98%+ Naphthalene-1- α-Naphthaldehyde 1-Naphthalenecarboxaldehyde 1-phthaldehyde 1-Naphthaldehyde> 1-Naphthylcarboxaldehyde 1- naphthalene formaldehyde 1-Naphthalenecarboxaldehyde (9CI, ACI) 1-Naphthaladehyde 1 – NAPTHALDEHYDE 1-Naphthaldehyde in isooctane Pyrithiobac Impurity 2 alpha-Naphthaldehyde, 99% 1-Naphthalenecarboxaldehyde alpha-Naphthal alpha-Naphthylcarboxaldehyde naphthalene-1-carbaldehyde naphthal Naphthalene-1-carboxaldehyde 66-77-3 C10H7CHO ALDEHYDE Organic Building Blocks Building Blocks Aldehydes C10 to C21 Carbonyl Compounds Naphthalene series bc0001