4-Bromobenzyl chloride
- CAS No.
- 589-17-3
- Chemical Name:
- 4-Bromobenzyl chloride
- Synonyms
- 1-Bromo-4-(chloromethyl)benzene;P-BROMOBENZYL CHLORIDE;4-BROMOBENZYL CHLORIDE;4-bromo-à-chlorotoluene;4-Bromo-α-chlorotoluene;α-Chloro-4-bromotoluene;4-Bromobenzylchloride,97%;4-Bromobenzyl chloride,98%;4-Bromobenzyl Chloride >4-BROMO-ALPHA-CHLOROTOLUENE
- CBNumber:
- CB6708142
- Molecular Formula:
- C7H6BrCl
- Molecular Weight:
- 205.48
- MDL Number:
- MFCD00040867
- MOL File:
- 589-17-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-Bromobenzyl chloride ≥97.0% (GC) | 726362 | 5g | $36.3 |
| 4-Bromobenzyl chloride ≥97.0% (GC) | 726362 | 25g | $140 |
| 4-Bromobenzyl Chloride | B3042 | 5G | $57 |
| 4-Bromobenzyl Chloride | B3042 | 25G | $165 |
| 4-Bromobenzyl chloride ≥95% | OR9776 | 5g | $21 |
| More product size | |||
| Melting point | 36-40 °C |
|---|---|
| Boiling point | 136-139 °C (27 mmHg) |
| Density | 1.3431 (rough estimate) |
| refractive index | 1.5750 (estimate) |
| Flash point | 106-107°C/10mm |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Powder and Granules |
| color | White |
| Water Solubility | Insoluble in water. |
| Merck | 14,1410 |
| BRN | 6123220 |
| InChI | InChI=1S/C7H6BrCl/c8-7-3-1-6(5-9)2-4-7/h1-4H,5H2 |
| InChIKey | BSIIGUGKOPPTPZ-UHFFFAOYSA-N |
| SMILES | C1(Br)=CC=C(CCl)C=C1 |
| CAS DataBase Reference | 589-17-3(CAS DataBase Reference) |
| FDA UNII | 6WI1338739 |
| NIST Chemistry Reference | Benzene, 1-bromo-4-(chloromethyl)-(589-17-3) |
| UNSPSC Code | 12352100 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P305+P351+P338-P310 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 36/37-34 | |||||||||
| Safety Statements | 45-36/37/39-25-26 | |||||||||
| RIDADR | 3261 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Corrosive/Lachrymator | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29039990 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Skin Corr. 1B | |||||||||
| Limited Quantities | 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
4-Bromobenzyl chloride price More Price(48)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 726362 | 4-Bromobenzyl chloride ≥97.0% (GC) | 589-17-3 | 5g | $36.3 | 2023-06-20 | Buy |
| Sigma-Aldrich | 726362 | 4-Bromobenzyl chloride ≥97.0% (GC) | 589-17-3 | 25g | $140 | 2023-06-20 | Buy |
| TCI Chemical | B3042 | 4-Bromobenzyl Chloride | 589-17-3 | 5G | $57 | 2026-04-30 | Buy |
| TCI Chemical | B3042 | 4-Bromobenzyl Chloride | 589-17-3 | 25G | $165 | 2026-04-30 | Buy |
| Apolloscientific | OR9776 | 4-Bromobenzyl chloride ≥95% | 589-17-3 | 5g | $21 | 2026-06-04 | Buy |
4-Bromobenzyl chloride Chemical Properties,Uses,Production
Chemical Properties
light yellow crystal powder to light yellow liqui
Uses
4-Bromobenzyl chloride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.
Synthesis
873-75-6
589-17-3
General procedure for the synthesis of 4-bromobenzyl chloride from 4-bromobenzyl alcohol: 4-bromobenzyl alcohol (0.6 g, 0.6 mmol) and dichloromethane (5 mL) were added to a round bottom flask. After stirring for 10 min, oxalyl chloride or oxalyl bromide (0.6 mmol) was slowly added. The reaction mixture was magnetically stirred at room temperature. After the gas was released, 4-bromobenzyl alcohol (0.5 mmol) was added and the reaction mixture was heated to reflux. The progress of the reaction was monitored by TLC and after completion of the reaction, the mixture was cooled to room temperature and filtered. The solid on the funnel was washed with dichloromethane (3 x 10 mL), the filtrate was combined and concentrated under reduced pressure. The purity of the resulting 4-bromobenzyl chloride was confirmed by 1H NMR and 13C NMR spectral analysis.
Purification Methods
Crystallise the chloride from EtOH and distil it in a vacuum. [Beilstein 5 IV 832.] LACHRYMATORY.
References
[1] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 1397 - 1405
[2] Organic Letters, 2013, vol. 15, # 1, p. 108 - 111
[3] Organic and Biomolecular Chemistry, 2013, vol. 11, # 24, p. 4016 - 4024
[4] Bulletin of the Korean Chemical Society, 2010, vol. 31, # 11, p. 3434 - 3436
[5] Organic Letters, 2018, vol. 20, # 10, p. 3061 - 3064
4-Bromobenzyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hefei Lbao Physical & Chemical Science Co.,Ltd | +15184799099 | lbaochemicals@gmail.com | China | 670 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-87569266 +86-17392581500 | 1015@dideu.com | China | 3991 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10000 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 9542 | 58 |
View Lastest Price from 4-Bromobenzyl chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-05-18 | 4-Bromobenzyl chloride
589-17-3
|
1kg | 98% | Hefei Lbao Physical & Chemical Science Co.,Ltd | |||
 |
2020-01-03 | 4-Bromobenzyl chloride
589-17-3
|
$1.00 | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- 4-Bromobenzyl chloride
589-17-3
- $0.00
- 98%
- Hefei Lbao Physical & Chemical Science Co.,Ltd
-
- 4-Bromobenzyl chloride
589-17-3
- $1.00
- 99%
- Career Henan Chemical Co
