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Bisphenoxyethanolfluorene

CAS No.
117344-32-8
Chemical Name:
Bisphenoxyethanolfluorene
Synonyms
bpef;BK122;LABOTEST-BB LT00112265;Bisphenoxyethanolfuorene;Bisphenoxyethanolfluorene;9-Fluorenbisphenoxyethanol;BISPHENOXY ETHANOL FLUORENONE;9,9-Bis[4-(2-Hydroxyethoxy)Phe;Bisphenoxyethanolfluorene BPEF;TIANFU-CHEM Bisphenoxyethanolfluorene
CBNumber:
CB6747899
Molecular Formula:
C29H26O4
Molecular Weight:
438.51
MDL Number:
MFCD00216628
MOL File:
117344-32-8.mol
MSDS File:
SDS
Last updated:2026-04-14 09:55:04
Product description Number Pack Size Price
4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol) 97% 437921 25g $280
9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene >98.0%(GC) F0447 5g $43
9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene >98.0%(GC) F0447 25g $129
2,2''-(((9H-Fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy))diethanol F591598 500mg $75
Bisphenoxyethanolfluorene FB16420 10g $105
More product size

Bisphenoxyethanolfluorene Properties

Melting point 117-120 °C(lit.)
Boiling point 610.7±55.0 °C(Predicted)
Density 1.248±0.06 g/cm3(Predicted)
storage temp. 2-8°C
Water Solubility Insoluble in water
pka 13.95±0.10(Predicted)
form powder to crystal
color White to Almost white
InChI InChI=1S/C29H26O4/c30-17-19-32-23-13-9-21(10-14-23)29(22-11-15-24(16-12-22)33-20-18-31)27-7-3-1-5-25(27)26-6-2-4-8-28(26)29/h1-16,30-31H,17-20H2
InChIKey NQXNYVAALXGLQT-UHFFFAOYSA-N
SMILES C1(C2=CC=C(OCCO)C=C2)(C2=CC=C(OCCO)C=C2)C2=C(C=CC=C2)C2=C1C=CC=C2
CAS DataBase Reference 117344-32-8(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264b-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P330-P362+P364-P403+P233-P501c
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  37
Safety Statements  26-36
WGK Germany  3
HS Code  29094990
Storage Class 11 - Combustible Solids

Bisphenoxyethanolfluorene price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 437921 4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol) 97% 117344-32-8 25g $280 2023-06-20 Buy
TCI Chemical F0447 9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene >98.0%(GC) 117344-32-8 5g $43 2026-03-19 Buy
TCI Chemical F0447 9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene >98.0%(GC) 117344-32-8 25g $129 2026-03-19 Buy
TRC F591598 2,2''-(((9H-Fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy))diethanol 117344-32-8 500mg $75 2021-12-16 Buy
Biosynth Carbosynth FB16420 Bisphenoxyethanolfluorene 117344-32-8 10g $105 2021-12-16 Buy
Product number Packaging Price Buy
437921 25g $280 Buy
F0447 5g $43 Buy
F0447 25g $129 Buy
F591598 500mg $75 Buy
FB16420 10g $105 Buy

Bisphenoxyethanolfluorene Chemical Properties,Uses,Production

Description

Bisphenoxyethanolfluorene (also name 4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol); BPEF) is a low-mass compound, primarily used in the preparation of polymer resins and films. Research indicates that adding BPEF reduces the orientation birefringence of thermally stretched cellulose acetate propionate (CAP) films.

Chemical Properties

White powder

Uses

4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol) may be used for the following syntheses:

  • poly-(carbotetramethyldisiloxane)s, containing poly[oxy{4,4′-(9-fluorenylidene)bis(2-phenoxyethylene)}oxytetramethyldisiloxane] (a fluorescent aromatic chromophore group)
  • poly[oxy(arylene)oxy(tetramethyldisilylene)]s, containing fluorescent aromatic chromophore groups in the polymer main chain, via melt copolymerization reaction with 1,2-bis(diethylamino)tetramethyldisilane

General Description

4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol) is an aryldiol.

Synthesis

2-Phenoxyethanol

122-99-6

9-Fluorenone

486-25-9

Bisphenoxyethanolfluorene

117344-32-8

The general procedure of Example 12 was as follows:(a) In a glass reactor equipped with a stirrer, a nitrogen introduction tube, a thermometer and a T-tube, 80.0 g (0.444 mol) of 9-fluorenone, 613.5 g (4.44 mol) of 2-phenoxyethanol and 2.0 g of tungstophosphoric acid catalyst [(H3PW12O40).nH2O] were added. (b) The mixture was reacted at 130°C for 4 hours under reduced pressure of 2.0 x 1.03 Pa. Upon completion of the reaction, the amount of polymers in the reaction mixture was 3.9%. To the reaction mixture was added 800.0 g of toluene, neutralized with aqueous sodium hydroxide and washed with water to separate the organic phase. Toluene and excess 2-phenoxyethanol were removed from the organic phase by concentration under reduced pressure. To the concentrate was added 560.0 g of toluene, and the mixture was heated and stirred at 80 °C for 1 hour, then cooled to 70 °C. 0.4 g of 9,9-bis[(4-(2-hydroxyethoxy)phenyl)]fluorene was added as a crystalline species, and the mixture was held at 70°C for 2 hours and then cooled to 20°C. The precipitated crystals were filtered and dried to give 78.0 g of white crystals 9,9-bis[(4-(2-hydroxyethoxy)phenyl)]fluorene (yield: 90.2%, purity: 99.2%). The melting point of the resulting product was 163 °C.

References

[1] Patent: US2012/29244, 2012, A1. Location in patent: Page/Page column 15
[2] Patent: JP6139508, 2017, B2. Location in patent: Paragraph 0024
[3] Patent: EP2123625, 2009, A1. Location in patent: Page/Page column 6
[4] Chemistry Letters, 1998, # 10, p. 1055 - 1056

122-99-6
486-25-9
117344-32-8
Synthesis of Bisphenoxyethanolfluorene from 2-Phenoxyethanol and 9-Fluorenone

Bisphenoxyethanolfluorene Preparation Products And Raw materials

Global( 301)Suppliers
Supplier Tel Email Country ProdList Advantage
Jiangsu Ever Galaxy Chemical Co.,Ltd
+86-0527-81083685; +8618602515822 info@egchemical.com China 79 58
Chengdu Yuanda Chemical Co., Ltd
28-85356300 +8618980937689 sales@ydachem.com CHINA 94 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 8800 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-86-13131129325 +8613131129325 sales1@chuanghaibio.com China 5235 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615531151365 mina@chuanghaibio.com China 18126 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3692 58
HANGZHOU HAILAN CHEMICAL CO.,LTD.
+86-57156122185 +86-15967590394 sales@hailan-chem.com China 400 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 13815 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21592 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60

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View Lastest Price from Bisphenoxyethanolfluorene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bisphenoxyethanolfluorene pictures 2026-04-17 Bisphenoxyethanolfluorene
117344-32-8
US $87.00-1190.00 / kg 1kg 0.98 100kg Shanghai UCHEM Inc.
Bisphenoxyethanolfluorene pictures 2026-04-17 Bisphenoxyethanolfluorene
117344-32-8
US $0.00 / kg 1kg 99.5% 20tons HANGZHOU HAILAN CHEMICAL CO.,LTD.
Bisphenoxyethanolfluorene pictures 2026-04-13 Bisphenoxyethanolfluorene
117344-32-8
US $30.00-65.00 / mg 98.96% 10g TargetMol Chemicals Inc.
9,9 -Bis(4-(2-Hydroxyethoxy) phenyl)Fluorene,4,4' -(9-Fluorenylidene)bis(2-phenoxyethanol) 2,2'-[9H-Fluoren-9-ylidenebis(4,1-phenyleneoxy)]bis[ethanol] 9,9-BIS[4-(2-HYDROXYETHOXY)PHENYL]FLUORENE 4,4'-(9-FLUORENYLIDENE)BIS(2-PHENOXYETHANOL) 9,9-Bis[4-(2-Hydroxyethoxy)Phe BISPHENOXYETHANOLFLUORENE 9,9-BIS[4-(2-HYDROXYETHOXY)PHENYL]FLUORENE Bisphenoxyethanolfluorene LABOTEST-BB LT00112265 2,2'-[9-Fluorenylidenebis(p-phenylenoxy)]diethanol BISPHENOXY ETHANOL FLUORENONE 9-Fluorenbisphenoxyethanol Bisphenoxyethanolfuorene 2,2'-(((9H-Fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy))diethanol Bisphenoxyethanolfluorene BPEF Ethanol,2,2'-[9H-fluoren-9-ylidenebis(4,1-phenyleneoxy)]bis- 9,9-bis [(4-hydroxyethoxy) phenyl] fluorene 9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene> 9, 9-bis [4-(2-hydroxyethyl) phenyl] fluorene 9,9-bis[4-(2-hydroxyethoxy )phenyl]fiuorene TIANFU-CHEM Bisphenoxyethanolfluorene 9,9-Bis(4-(2-Hydroxyethoxy)phenyl) Fluorene (BPEF) Bisphenoxyethanolfluorene, 9,9-bis[4-(2-hydroxyethoxy )phenyl]fiuorene 101-99-bis (4-92 hydroxyethoxy) phenyl) fluorene 4,4'-(9-fluorenylidene)bis(2-phenoxy-ethanol) BK122 4,4'-(9-fluorenylidene)bis(2-phenoxy-ethanol) BPEF Bisphenoxyethanolfluorene, 10 mM in DMSO 9,9-Bis[(4-hydroxyphenoxy)phenyl]fluorene 4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol), CAS 117344-32-8 9,9-bis[4-(2-hydroxyethoxy)phenyl]fluorine bpef 117344-32-8 C29H26O4 Oxygen Compounds Organic Building Blocks Building Blocks Alcohols C9 to C30 Fluorenes & Fluorenones Fluorenes Reagent for High-Performance Polymer Research Fluorenes, etc. (reagent for high-performance polymer research) Alcohols C9 to C30 Oxygen Compounds Fluorenes Fluorenes & Fluorenones Fluorenes, etc. (reagent for high-performance polymer research) Functional Materials Reagent for High-Performance Polymer Research Fluorene series Pharmaceutical intermediates Fine chemical