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(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid

CAS No.
866100-14-3
Chemical Name:
(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid
Synonyms
(9,9-Dimethyl-9H-flu;9,9-dimethyl-2,7-diboronic acid;9,9-Dimethyl-2,7-fluorenediboronicacid;9,9-diMethyl-9H-fluorene-2,7-diyldiboronic acid;(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid;Boronicacid,(9,9-dimethyl-9H-fluorene-2,7-diyl)b;(9,9-diMethyl-9H-fluoren-2,7-diyl)bisboronic acid;(9,9-dimethyl-9H-fluorene-2,7-diyl)bisboronic acid;9,9-Dimethyl-9H-fluoren-2,7-diyl-2,7-diboronic acid;(9,9-DIMETHYL-9H-FLUOROENE-2,7-DIYL)BISBORONIC ACID
CBNumber:
CB6812405
Molecular Formula:
C15H16B2O4
Molecular Weight:
281.91
MDL Number:
MFCD08704228
MOL File:
866100-14-3.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:50

(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Properties

storage temp. Store at room temperature
Appearance White to off-white Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P280-P305+P351+P338
HS Code  2931900090

(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D4701 (9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic Acid (contains varying amounts of Anhydride) 866100-14-3 1G $136 2025-07-31 Buy
TRC D486780 (9,9-Dimethyl-9h-fluorene-2,7-diboronicacid 866100-14-3 250mg $75 2021-12-16 Buy
TRC D486780 (9,9-Dimethyl-9h-fluorene-2,7-diboronicacid 866100-14-3 500mg $115 2021-12-16 Buy
Matrix Scientific 094305 (9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic acid 95+% 866100-14-3 250mg $175 2021-12-16 Buy
ChemScene CS-W000989 9,9-Dimethylfluorene-2,7-diboronicacid 866100-14-3 5g $210 2021-12-16 Buy
Product number Packaging Price Buy
D4701 1G $136 Buy
D486780 250mg $75 Buy
D486780 500mg $115 Buy
094305 250mg $175 Buy
CS-W000989 5g $210 Buy

(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Chemical Properties,Uses,Production

Chemical Properties

Off-white powder

Synthesis

Triisopropyl borate

5419-55-6

2,7-Dibromo-9,9-dimethylfluorene

28320-32-3

(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid

866100-14-3

The general procedure for the synthesis of 9,9-dimethylfluorene-2,7-diboronic acid from triisopropyl borate and 2,7-dibromo-9,9-dimethylfluorene was as follows: 2,7-dibromo-9,9-dimethylfluorene (14.8 g, 42.4 mmol) was placed in a three-necked flask, 100 mL of tetrahydrofuran (THF) was added, and the reaction was cooled under nitrogen protection to -78 °C and maintained for 30 min. Subsequently, 21 mL of n-butyllithium (2.5 M) solution was added slowly and reacted for 1 hour. Next, triisopropyl borate (14 g) was added and the reaction was continued at low temperature for 1 hour, after which it was gradually warmed to room temperature. After completion of the reaction, the pH was adjusted to 4-5 by adding 2 M hydrochloric acid to the reaction mixture. the aqueous layer was extracted with ethyl acetate, the organic layers were combined and dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give Intermediate A1 (9.5 g, 80% yield).

References

[1] Patent: CN106699780, 2017, A. Location in patent: Paragraph 0047; 0048; 0049; 0050
[2] Patent: US8058450, 2011, B2. Location in patent: Page/Page column 43-44
[3] Luminescence, 2015, vol. 30, # 5, p. 549 - 555

(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Preparation Products And Raw materials

Global( 110)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20202 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21622 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29855 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Xiamen AmoyChem Co., Ltd
+86-86-5926051114 +8615060885618 sales@amoychem.com China 6369 58
BAYNOE CHEM CO.,LTD
+86-21-34783353 +8615000719740 baynoe@baynoe.com CHINA 934 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
CHEMSOON CO.,LTD.
+8613761723174 sales01@chemsoon.com China 1211 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58

View Lastest Price from (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid pictures 2025-08-15 (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid
866100-14-3
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid pictures 2025-04-04 (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid
866100-14-3
US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
(9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic acid pictures 2024-01-06 (9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic acid
866100-14-3
US $188.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd

(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Spectrum

BORONIC ACID, (9,9-DIMETHYL-9H-FLUORENE-2,7-DIYL)BIS (9,9-dimethyl-9H-fluorene-2,7-diyl)bisboronic acid Boronicacid,(9,9-dimethyl-9H-fluorene-2,7-diyl)b (9,9-DIMETHYL-9H-FLUOROENE-2,7-DIYL)BISBORONIC ACID (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid BORONIC ACID, (9,9-DIMETHYL-9H-FLUORENE-2,7-DIYL)BIS- (9CI) 9,9-Dimethyl-9H-fluoren-2,7-diyl-2,7-diboronic acid (9,9-Dimethyl-9H-flu 9,9-diMethyl-9H-fluorene-2,7-diyldiboronic acid (9,9-diMethyl-9H-fluoren-2,7-diyl)bisboronic acid BORONIC ACID,B,B'-(9,9-DIMETHYL-9H-FLUORENE-2,7-DIYL)BIS- (9,9-dimethy)-9H-flourene-2,7-diyl)-bisboronic acid (9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic Acid (contains varying amounts of Anhydride) (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid ISO 9001:2015 REACH (9,9-Dimethyl-9h-fluorene-2,7-diboronic acid(contains varying amounts of Anhydride) 9,9-Dimethyl-2,7-fluorenediboronicacid 9,9-dimethyl-2,7-diboronic acid 866100-14-3 C15H16B2O4 OLED materrials OLED materials,pharm chemical,electronic Boron Compounds Electronic Chemicals