ChemicalBook >> CAS DataBase List >>METHYL 3-HYDROXY-2-NITROBENZOATE

METHYL 3-HYDROXY-2-NITROBENZOATE

CAS No.
89942-77-8
Chemical Name:
METHYL 3-HYDROXY-2-NITROBENZOATE
Synonyms
METHYL 3-HYDROXY-2-NITROBENZOATE;3-Hydroxy-2-nitro-benzoic acid methyl ester;Benzoic acid, 3-hydroxy-2-nitro-, methyl ester;3-hydroxy-2-nitro-Benzoic acid methyl ester (6CI 7CI 9CI ACI);Benzoic acid, 3-hydroxy-2-nitro-, methyl ester (6CI, 7CI, 9CI, ACI);3-(Methoxycarbonyl)-2-nitrophenol, 2-Hydroxy-6-(methoxycarbonyl)nitrobenzene
CBNumber:
CB71484259
Molecular Formula:
C8H7NO5
Molecular Weight:
197.14
MDL Number:
MFCD09951956
MOL File:
89942-77-8.mol
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
Methyl3-hydroxy-2-nitrobenzoate M323383 250mg $55
Methyl3-hydroxy-2-nitrobenzoate M323383 1g $75
Methyl 3-hydroxy-2-nitrobenzoate 4654-1-Y2 1g $130
Methyl 3-hydroxy-2-nitrobenzoate 4654-1-Y2 250mg $40
Methyl 3-hydroxy-2-nitrobenzoate >97% 116393 5g $212
More product size

METHYL 3-HYDROXY-2-NITROBENZOATE Properties

Melting point 108-110℃
Boiling point 310.0±22.0 °C(Predicted)
Density 1.432±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
pka 6.38±0.10(Predicted)
color Off white
InChI InChI=1S/C8H7NO5/c1-14-8(11)5-3-2-4-6(10)7(5)9(12)13/h2-4,10H,1H3
InChIKey FHCNMPYMCKHBTK-UHFFFAOYSA-N
SMILES C(OC)(=O)C1=CC=CC(O)=C1[N+]([O-])=O

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314-H227-H290
Precautionary statements  P501-P210-P234-P264-P280-P370+P378-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P406-P405
HS Code  2918290090

METHYL 3-HYDROXY-2-NITROBENZOATE price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M323383 Methyl3-hydroxy-2-nitrobenzoate 89942-77-8 250mg $55 2021-12-16 Buy
TRC M323383 Methyl3-hydroxy-2-nitrobenzoate 89942-77-8 1g $75 2021-12-16 Buy
SynQuest Laboratories 4654-1-Y2 Methyl 3-hydroxy-2-nitrobenzoate 89942-77-8 1g $130 2021-12-16 Buy
SynQuest Laboratories 4654-1-Y2 Methyl 3-hydroxy-2-nitrobenzoate 89942-77-8 250mg $40 2021-12-16 Buy
Matrix Scientific 116393 Methyl 3-hydroxy-2-nitrobenzoate >97% 89942-77-8 5g $212 2021-12-16 Buy
Product number Packaging Price Buy
M323383 250mg $55 Buy
M323383 1g $75 Buy
4654-1-Y2 1g $130 Buy
4654-1-Y2 250mg $40 Buy
116393 5g $212 Buy

METHYL 3-HYDROXY-2-NITROBENZOATE Chemical Properties,Uses,Production

Synthesis

3-Hydroxy-2-nitrobenzoic acid

602-00-6

METHYL 3-HYDROXY-2-NITROBENZOATE

89942-77-8

Sulfoxide chloride (SOCl2, 0.6 mL) was slowly added dropwise to anhydrous methanol (MeOH, 10 mL) at 0 °C. The reaction mixture was stirred continuously for 0.5 h at this temperature. Subsequently, 3-hydroxy-2-nitrobenzoic acid (0.6 g, 3.2 mmol) was added to the mixture. The reaction system was heated to reflux and maintained for 4 hours. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent ratio of petroleum ether: ethyl acetate = 1:1) to confirm the completion of the reaction. After completion of the reaction, the mixture was concentrated under vacuum to afford the target product methyl 2-nitro-3-hydroxybenzoate (0.63 g, 100% yield) as a brown solid.

References

[1] Patent: WO2007/125405, 2007, A2. Location in patent: Page/Page column 24; 72-73
[2] Nippon Kagaku Zasshi, 1953, vol. 74, p. 251
[3] Chem.Abstr., 1954, p. 3959
[4] Patent: US2002/52397, 2002, A1
[5] Patent: US5756510, 1998, A

METHYL 3-HYDROXY-2-NITROBENZOATE Preparation Products And Raw materials

Global( 80)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3009 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29799 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10035 58
Win-Win chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14360 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739 info@dycnchem.com China 52846 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418684 +8618949823763 sales@tnjchem.com China 25356 58
Aromsyn Co., Ltd.
+86-0571-85585865 +8613336024896 CB@aromsyn.com China 19183 58
Wuhan Konberd Biotech Co., Ltd
+undefined18986093962 admin@konberdbio.com China 1379 58

View Lastest Price from METHYL 3-HYDROXY-2-NITROBENZOATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
methyl 3-hydroxy-2-nitrobenzoate pictures 2025-08-25 methyl 3-hydroxy-2-nitrobenzoate
89942-77-8
US $0.00 / kg 10kg 99% 10 tons Qingdao RENAS Polymer Material Co., Ltd.
METHYL 3-HYDROXY-2-NITROBENZOATE pictures 2020-01-13 METHYL 3-HYDROXY-2-NITROBENZOATE
89942-77-8
US $0.01 / KG 1KG 98%; 99% 500g; 1kg; 25kg Career Henan Chemical Co
METHYL 3-HYDROXY-2-NITROBENZOATE pictures 2019-12-26 METHYL 3-HYDROXY-2-NITROBENZOATE
89942-77-8
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co

METHYL 3-HYDROXY-2-NITROBENZOATE Spectrum

METHYL 3-HYDROXY-2-NITROBENZOATE 3-(Methoxycarbonyl)-2-nitrophenol, 2-Hydroxy-6-(methoxycarbonyl)nitrobenzene 3-Hydroxy-2-nitro-benzoic acid methyl ester Benzoic acid, 3-hydroxy-2-nitro-, methyl ester Benzoic acid, 3-hydroxy-2-nitro-, methyl ester (6CI, 7CI, 9CI, ACI) 3-hydroxy-2-nitro-Benzoic acid methyl ester (6CI 7CI 9CI ACI) 89942-77-8 Aromatic Esters