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4-Bromo-2-chloroaniline

CAS No.
38762-41-3
Chemical Name:
4-Bromo-2-chloroaniline
Synonyms
Benzenamine, 4-bromo-2-chloro-;4-Bromo-2-chloroanil;-Bromo-2-chloroaniline;4-BROMO-2-CHLOROANILINE;4-Bromo-2-chloroanilinev;4-Bromo-2-chloroaniline >4-Bromo-2-chloroaniline 98%;4-Bromo-2-chloroaniline,99%;4-Bromo-2-chloro-phenylamine;4-BROMO-2-CHLOROANILINE, 98+%
CBNumber:
CB7218516
Molecular Formula:
C6H5BrClN
Molecular Weight:
206.47
MDL Number:
MFCD00007660
MOL File:
38762-41-3.mol
MSDS File:
SDS
Last updated:2026-01-27 18:41:44
Product description Number Pack Size Price
4-Bromo-2-chloroaniline >98.0%(GC) B1993 5g $31
4-Bromo-2-chloroaniline >98.0%(GC) B1993 25g $104
4-Bromo-2-chloroaniline B699468 50mg $45
4-Bromo-2-chloroaniline 98% OR0849 25g $22
4-Bromo-2-chloroaniline 98.0% 3630-D-X8 25g $24
More product size

4-Bromo-2-chloroaniline Properties

Melting point 70-72 °C (lit.)
Boiling point 241.8±20.0 °C(Predicted)
Density 1.6567 (rough estimate)
refractive index 1.5400 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka 1.95±0.10(Predicted)
form Crystalline Powder
color Slightly yellow to light brown
BRN 3117740
InChI InChI=1S/C6H5BrClN/c7-4-1-2-6(9)5(8)3-4/h1-3H,9H2
InChIKey INMZDDDQLHKGPF-UHFFFAOYSA-N
SMILES C1(N)=CC=C(Br)C=C1Cl
CAS DataBase Reference 38762-41-3(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS06
Signal word  Warning
Hazard statements  H315-H319-H302+H312+H332-H302-H311-H332
Precautionary statements  P280-P280h-P302+P352-P309-P310-P261-P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,T,Xi
Risk Statements  20/21/22-20/21
Safety Statements  36-23
WGK Germany  3
Hazard Note  Toxic
HazardClass  IRRITANT
HS Code  29214200
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
NFPA 704
0
2 0

4-Bromo-2-chloroaniline price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B1993 4-Bromo-2-chloroaniline >98.0%(GC) 38762-41-3 5g $31 2026-03-19 Buy
TCI Chemical B1993 4-Bromo-2-chloroaniline >98.0%(GC) 38762-41-3 25g $104 2026-03-19 Buy
TRC B699468 4-Bromo-2-chloroaniline 38762-41-3 50mg $45 2021-12-16 Buy
Apolloscientific OR0849 4-Bromo-2-chloroaniline 98% 38762-41-3 25g $22 2021-12-16 Buy
SynQuest Laboratories 3630-D-X8 4-Bromo-2-chloroaniline 98.0% 38762-41-3 25g $24 2021-12-16 Buy
Product number Packaging Price Buy
B1993 5g $31 Buy
B1993 25g $104 Buy
B699468 50mg $45 Buy
OR0849 25g $22 Buy
3630-D-X8 25g $24 Buy

4-Bromo-2-chloroaniline Chemical Properties,Uses,Production

Chemical Properties

SLIGHTLY YELLOW TO LIGHT BROWN CRYSTALLINE POWDER

Uses

4-Bromo-2-chloroaniline was used in the peparation of 3,4-dichloro-α-trichloromethylbenzyl alcohol.

Synthesis

2-Chloroaniline

95-51-2

4-Bromo-2-chloroaniline

38762-41-3

The general procedure for the synthesis of 4-bromo-2-chloroaniline from o-chloroaniline was as follows: 254 mg (2 mmol) of o-chloroaniline and 143 mg (1.2 mmol) of potassium bromide were dissolved in 10 mL of a solvent mixture of acetic acid (AcOH) and water (9:1, v/v), and the solution was subsequently transferred to a 50 mL three-neck flask. The reaction temperature was controlled by magnetic stirring at 25°C for 1 h in a thermostatic water bath with continuous stirring. Within the first 15 min of the start of the reaction, 1.8 g (1.8 mmol) of ZnAl-BrO3-LDHs was slowly added.After completion of the reaction, the reaction mixture was extracted with dichloromethane (2 × 10 mL) and the organic phases were combined. Two silica gels (200-300 mesh) were added to the combined organic phases, and the dichloromethane was subsequently removed by distillation under reduced pressure. Finally, purification was carried out using column chromatography (eluent was a solvent mixture of petroleum ether and ethyl acetate in a 10:1 ratio, v/v) to give 321 mg of gray solid product in 78% yield.

References

[1] Tetrahedron Letters, 2005, vol. 46, # 51, p. 8959 - 8963
[2] Russian Journal of Applied Chemistry, 2009, vol. 82, # 9, p. 1570 - 1576
[3] Chinese Chemical Letters, 2012, vol. 23, # 4, p. 387 - 390
[4] Monatshefte fur Chemie, 2013, vol. 144, # 2, p. 179 - 181
[5] Journal of the Iranian Chemical Society, 2012, vol. 9, # 3, p. 321 - 326

103-84-4
38762-41-3
Synthesis of 4-Bromo-2-chloroaniline from Acetanilide
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View Lastest Price from 4-Bromo-2-chloroaniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Bromo-2-chloroaniline pictures 2026-04-27 4-Bromo-2-chloroaniline
38762-41-3
US $0.00 / KG 500KG 99% 20TON Linyi Changqing Chemical Co., LTD
4-Bromo-2-chloroaniline pictures 2025-12-01 4-Bromo-2-chloroaniline
38762-41-3
US $0.00-0.00 / KG 1KG 98.0% 10000KGS Shaanxi Dideu New Materials Co. Ltd
4-Bromo-2-chloroaniline  pictures 2025-11-18 4-Bromo-2-chloroaniline
38762-41-3
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
4-BROMO-2-CHLOROANILINE 4-Bromo-2-chloroaniline 98% 4-BROMO-2-CHLOROANILINE, 98+% 4-Bromo-2-chloroanil 4-Bromo-2-chloro-phenylamine Benzenamine, 4-bromo-2-chloro- 1-Amino-4-bromo-2-chlorobenzene 4-Bromo-2-chloroaniline,99% 4-Bromo-2-chloroanilinev 4-Bromo-2-chloroaniline > 4-Bromo-2-chloroaniline ISO 9001:2015 REACH -Bromo-2-chloroaniline 4-Bromo-2-Chloro Aniline (BCBN3) 38762-41-3 C2 to C6 Building Blocks Amines Nitrogen Compounds Organic Building Blocks Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks C2 to C6 Nitrogen Compounds Anilines, Aromatic Amines and Nitro Compounds Benzene series Anilines, Amides & Amines Bromine Compounds Chlorine Compounds Amines blocks Bromides C6