10-Phenyl-10H-phenothiazine
- CAS No.
- 7152-42-3
- Chemical Name:
- 10-Phenyl-10H-phenothiazine
- Synonyms
- 10-Phenylphenothiazine;10-phenyl-10H-phenothiazin;10-Phenyl-10H-phenothiazine;10-phenyl-10H-phenethiazine;10H-Phenothiazine, 10-phenyl-;10-Phenylphenothiazine dication;10H-Phenothiazine, 10-phenyl- (9CI)
- CBNumber:
- CB72220427
- Molecular Formula:
- C18H13NS
- Molecular Weight:
- 275.37
- MDL Number:
- MFCD00156238
- MOL File:
- 7152-42-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 10-Phenylphenothiazine ≥95% | 903167 | 100MG | $107 |
| 10-Phenylphenothiazine ≥95% | 903167 | 250MG | $254 |
| 10-Phenylphenothiazine | P2470 | 1G | $144 |
| 10-Phenylphenothiazine | P2470 | 5G | $719 |
| 10-Phenyl-10H-phenothiazine 98% | AS143035 | 1g | $90 |
| More product size | |||
| Melting point | 94 °C |
|---|---|
| Boiling point | 411.2±15.0 °C(Predicted) |
| Density | 1.247±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | soluble in Acetone |
| form | powder to crystal |
| pka | -3.48±0.20(Predicted) |
| color | White to Orange to Green |
| InChI | InChI=1S/C18H13NS/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13H |
| InChIKey | WSEFYHOJDVVORU-UHFFFAOYSA-N |
| SMILES | C1=C2C(SC3=C(N2C2=CC=CC=C2)C=CC=C3)=CC=C1 |
| FDA UNII | BII1EYP5EW |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| WGK Germany | WGK 3 |
| HS Code | 2934.30.5000 |
| Storage Class | 11 - Combustible Solids |
10-Phenyl-10H-phenothiazine price More Price(34)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 903167 | 10-Phenylphenothiazine ≥95% | 7152-42-3 | 100MG | $107 | 2026-04-30 | Buy |
| Sigma-Aldrich | 903167 | 10-Phenylphenothiazine ≥95% | 7152-42-3 | 250MG | $254 | 2026-04-30 | Buy |
| TCI Chemical | P2470 | 10-Phenylphenothiazine | 7152-42-3 | 1G | $144 | 2026-04-30 | Buy |
| TCI Chemical | P2470 | 10-Phenylphenothiazine | 7152-42-3 | 5G | $719 | 2026-04-30 | Buy |
| Activate Scientific | AS143035 | 10-Phenyl-10H-phenothiazine 98% | 7152-42-3 | 1g | $90 | 2026-06-04 | Buy |
10-Phenyl-10H-phenothiazine Chemical Properties,Uses,Production
Chemical Properties
light yellow powder
Uses
An organic photo-catalyst used in synthesis of small molecules as well as polymerization reactions.
reaction suitability
reagent type: catalyst
reaction type: Photocatalysis
Synthesis
92-84-2
591-50-4
7152-42-3
Phenothiazine (500 mg, 2.50 mmol) was dissolved in anhydrous toluene (5 mL) under nitrogen protection, and iodobenzene (310 mg, 2.2 mmol), sodium tert-butanolate (0.5 mL), and tris(dibenzylideneacetone)dipalladium (Pd2(dba)3, 46 mg, 0.05 mmol) were added in sequence. The reaction mixture was transferred to a sealed tube and the reaction was stirred at 160 °C for 16 hours. After completion of the reaction, it was cooled to room temperature. The organic layer was separated and the aqueous layer was extracted with dichloromethane (2 x 15 mL). The organic phases were combined, dried over anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate= 20:1) to afford 10-phenylphenothiazine (600 mg, 87.3%) as a white solid with a melting point of 205 °C. Nuclear magnetic resonance hydrogen spectrum (1H-NMR, 300 MHz, acetone-d6): δ 7.70 (t, J = 7.5 Hz, 2H), 7.57 (t, J = 7.2 Hz, 1H), 7.44 (d, J = 7.8 Hz, 2H), 7.06 (d, J = 7.5 Hz, 2H), 6.92 (t, J = 7.2 Hz, 2H), 6.89 (t , J = 7.2 Hz, 2H), 6.23 (d, J = 8.1 Hz, 2H). Nuclear magnetic resonance carbon spectrum (13C NMR, 100 MHz, acetone-d6): δ 144.98, 141.82, 131.64, 131.37, 129.07, 127.31, 123.37, 120.90, 116.96. The electrospray high-resolution mass spectrometry (ESI-HRMS) m/z calculated value of C18H14NS ([M + H] +) was 276.0841 and the measured value was 276.0842.
References
[1] Chinese Chemical Letters, 2015, vol. 26, # 8, p. 951 - 954
[2] Bulletin of the Korean Chemical Society, 2013, vol. 34, # 1, p. 107 - 111
[3] Patent: CN104478870, 2016, B. Location in patent: Paragraph 0052; 0053; 0054
[4] Journal of Materials Chemistry A, 2017, vol. 5, # 16, p. 7586 - 7594
[5] Applied Organometallic Chemistry, 2017, vol. 31, # 11,
10-Phenyl-10H-phenothiazine Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14034 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32997 | 60 |
| Jurong Coupling Biotechnology Co., Ltd. | 13656108824 | coupling278191416@hotmail.com | CHINA | 184 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +86-18530059196 | sale04@alfachem.cn | China | 9636 | 58 |
| Shanxi Xuanran Import and Export Trade Co., Ltd. | +8617735180244 | mike_yan@xuanranglobal.com | CHINA | 4011 | 58 |
| Nextpeptide Inc | +86-0571-81612335 +8613336028439 | sales@nextpeptide.com | China | 19904 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501 | product@acmec-e.com | China | 33301 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 54746 | 58 | |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40048 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
