1-Bromo-4-iodonaphthalene
- CAS No.
- 63279-58-3
- Chemical Name:
- 1-Bromo-4-iodonaphthalene
- Synonyms
- 1,4-BIN;1-Bromo-4-iodophthalene;-BroMo-4-iodonaphthalene;1-Iodo-4-bromonaphthalene;1-Bromo-4-iodonaphthalene;4-bromo-1-iodonaphthalene;1-Bromo-4-iodonaphthaIene;1-Bromo-4-Iodine Naphthalene;Naphthalene, 1-bromo-4-iodo-;1-Bromo-4-iodonaphthalene 98%
- CBNumber:
- CB72506879
- Molecular Formula:
- C10H6BrI
- Molecular Weight:
- 332.96
- MDL Number:
- MFCD01166242
- MOL File:
- 63279-58-3.mol
| Melting point | 88-89℃ |
|---|---|
| Boiling point | 357.3±15.0 °C(Predicted) |
| Density | 2.057 |
| storage temp. | 2-8°C(protect from light) |
| form | Solid |
| color | White to Light yellow to Light orange |
| Water Solubility | Slightly soluble in water. (3.6 g/L) (25°C) |
| Sensitive | Light Sensitive |
| InChI | InChI=1S/C10H6BrI/c11-9-5-6-10(12)8-4-2-1-3-7(8)9/h1-6H |
| InChIKey | HQHHKYXPFKHLBF-UHFFFAOYSA-N |
| SMILES | C1(Br)=C2C(C=CC=C2)=C(I)C=C1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| HS Code | 2903.99.8001 | |||||||||
| NFPA 704 |
|
1-Bromo-4-iodonaphthalene price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B4864 | 1-Bromo-4-iodonaphthalene >98.0%(GC) | 63279-58-3 | 1g | $73 | 2025-07-31 | Buy |
| TCI Chemical | B4864 | 1-Bromo-4-iodonaphthalene >98.0%(GC) | 63279-58-3 | 5g | $290 | 2025-07-31 | Buy |
| TRC | B686818 | 1-Bromo-4-iodonaphthalene | 63279-58-3 | 30mg | $45 | 2021-12-16 | Buy |
| TRC | B686818 | 1-Bromo-4-iodonaphthalene | 63279-58-3 | 60mg | $60 | 2021-12-16 | Buy |
| TRC | B686818 | 1-Bromo-4-iodonaphthalene | 63279-58-3 | 300mg | $75 | 2021-12-16 | Buy |
1-Bromo-4-iodonaphthalene Chemical Properties,Uses,Production
Uses
It is used as an OLED material.
Synthesis
2298-07-9
63279-58-3
General procedure for the synthesis of 1-bromo-4-iodonaphthalene from 4-bromo-1-naphthylamine: 1-amino-4-bromonaphthalene (60 g, 0.27 mol) was placed in a single-necked flask and the reaction was carried out under argon protection. Acetonitrile (500 ml) was added as a solvent and the reaction mixture was cooled to 0 °C and kept until 1-amino-4-bromonaphthalene was completely dissolved. Subsequently, boron nitrite (42 g, 49 ml, 0.41 mol) and copper bromide (73 g, 0.32 mol) were added sequentially with continuous stirring for 3 h at room temperature. Upon completion of the reaction, the reaction was terminated by slow addition of 1N HCl aqueous solution (600 ml). The resulting solid product was collected by filtration and washed sequentially with distilled water and ether to remove impurities. Finally, the target compound 1-bromo-4-iodonaphthalene (76 g, 85% yield) was purified by column chromatography.
References
[1] Patent: WO2011/105700, 2011, A1. Location in patent: Page/Page column 23
[2] Patent: US2011/152246, 2011, A1. Location in patent: Page/Page column 121-123
[3] Journal of the Chemical Society, 1885, vol. 47, p. 523
[4] Journal of the Chemical Society, 1895, vol. 67, p. 912
[5] Tetrahedron Letters, 2004, vol. 45, # 42, p. 7883 - 7885
1-Bromo-4-iodonaphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | +8613336195806 | sales@capot.com | China | 29734 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13090 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Beijing Green Guardee Technology Co., Ltd | 86-010-69706062 | sales2@greenguardee.com | CHINA | 650 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29852 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| BAYNOE CHEM CO.,LTD | +86-21-34783353 +8615000719740 | baynoe@baynoe.com | CHINA | 934 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
View Lastest Price from 1-Bromo-4-iodonaphthalene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-09-23 | 1-Bromo-4-iodonaphthalene
63279-58-3
|
US $0.00-0.00 / KG | 1KG | 98% | 2000 | Shenzhen Nexcon Pharmatechs Ltd. | |
 |
2025-07-02 | 1-Bromo-4-iodonaphthalene
63279-58-3
|
US $0.00 / KG | 1KG | 98% | 150KG /month | Shanghai Daken Advanced Materials Co.,Ltd | |
 |
2021-07-13 | 1,4-BIN
63279-58-3
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
-
- 1-Bromo-4-iodonaphthalene
63279-58-3
- US $0.00-0.00 / KG
- 98%
- Shenzhen Nexcon Pharmatechs Ltd.
-
- 1-Bromo-4-iodonaphthalene
63279-58-3
- US $0.00 / KG
- 98%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- 1,4-BIN
63279-58-3
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
