1-Bromo-4-iodonaphthalene
- CAS No.
- 63279-58-3
- Chemical Name:
- 1-Bromo-4-iodonaphthalene
- Synonyms
- 1,4-BIN;1-Bromo-4-iodophthalene;-BroMo-4-iodonaphthalene;1-Iodo-4-bromonaphthalene;1-Bromo-4-iodonaphthalene;4-bromo-1-iodonaphthalene;1-Bromo-4-iodonaphthaIene;1-Bromo-4-Iodine Naphthalene;Naphthalene, 1-bromo-4-iodo-;1-Bromo-4-iodonaphthalene 98%
- CBNumber:
- CB72506879
- Molecular Formula:
- C10H6BrI
- Molecular Weight:
- 332.96
- MDL Number:
- MFCD01166242
- MOL File:
- 63279-58-3.mol
- MSDS File:
- SDS
| Melting point | 88-89℃ |
|---|---|
| Boiling point | 357.3±15.0 °C(Predicted) |
| Density | 2.057 |
| storage temp. | 2-8°C(protect from light) |
| form | Solid |
| color | White to Light yellow to Light orange |
| Water Solubility | Slightly soluble in water. (3.6 g/L) (25°C) |
| Sensitive | Light Sensitive |
| InChI | InChI=1S/C10H6BrI/c11-9-5-6-10(12)8-4-2-1-3-7(8)9/h1-6H |
| InChIKey | HQHHKYXPFKHLBF-UHFFFAOYSA-N |
| SMILES | C1(Br)=C2C(C=CC=C2)=C(I)C=C1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| HS Code | 2903.99.8001 | |||||||||
| NFPA 704 |
|
1-Bromo-4-iodonaphthalene price More Price(59)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B4864 | 1-Bromo-4-iodonaphthalene >98.0%(GC) | 63279-58-3 | 1g | $81 | 2026-04-30 | Buy |
| TCI Chemical | B4864 | 1-Bromo-4-iodonaphthalene >98.0%(GC) | 63279-58-3 | 5g | $323 | 2026-04-30 | Buy |
| Usbiological | 266919 | 1-Bromo-4-iodonaphthalene Asreported | 63279-58-3 | 5g | $389 | 2026-06-03 | Buy |
| Usbiological | 266919 | 1-Bromo-4-iodonaphthalene Asreported | 63279-58-3 | 10g | $531 | 2026-06-03 | Buy |
| Usbiological | 266919 | 1-Bromo-4-iodonaphthalene Asreported | 63279-58-3 | 25g | $814 | 2026-06-03 | Buy |
1-Bromo-4-iodonaphthalene Chemical Properties, Uses, Production
Uses
It is used as an OLED material.
Synthesis
2298-07-9
63279-58-3
General procedure for the synthesis of 1-bromo-4-iodonaphthalene from 4-bromo-1-naphthylamine: 1-amino-4-bromonaphthalene (60 g, 0.27 mol) was placed in a single-necked flask and the reaction was carried out under argon protection. Acetonitrile (500 ml) was added as a solvent and the reaction mixture was cooled to 0 °C and kept until 1-amino-4-bromonaphthalene was completely dissolved. Subsequently, boron nitrite (42 g, 49 ml, 0.41 mol) and copper bromide (73 g, 0.32 mol) were added sequentially with continuous stirring for 3 h at room temperature. Upon completion of the reaction, the reaction was terminated by slow addition of 1N HCl aqueous solution (600 ml). The resulting solid product was collected by filtration and washed sequentially with distilled water and ether to remove impurities. Finally, the target compound 1-bromo-4-iodonaphthalene (76 g, 85% yield) was purified by column chromatography.
References
[1] Patent: WO2011/105700, 2011, A1. Location in patent: Page/Page column 23
[2] Patent: US2011/152246, 2011, A1. Location in patent: Page/Page column 121-123
[3] Journal of the Chemical Society, 1885, vol. 47, p. 523
[4] Journal of the Chemical Society, 1895, vol. 67, p. 912
[5] Tetrahedron Letters, 2004, vol. 45, # 42, p. 7883 - 7885
1-Bromo-4-iodonaphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Weishennuo New Material Co., Ltd. | 029-89107144 18792503214 | beryl@weishinuo.com | China | 542 | 58 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Beijing Green Guardee Technology CO,.LTD | 010- 89781189-8112 18511583708 | sales2@greenguardee.com | China | 294 | 56 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 13770331960 | info@chemlin.com.cn | China | 16305 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 | info@spring-chem.com | China | 2068 | 57 |
| T&W GROUP | 021-61551611 13296011611 | contact@trustwe.com | China | 9884 | 58 |
View Latest Price from 1-Bromo-4-iodonaphthalene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-18 | 1-Bromo-4-iodonaphthalene
63279-58-3
|
1KG | 98% | 150KG /month | Shanghai Daken Advanced Materials Co.,Ltd | ||
 |
2026-08-13 | 1-Bromo-4-iodonaphthalene
63279-58-3
|
1KG | 98% | 2000 | Shenzhen Nexcon Pharmatechs Ltd. | ||
 |
2021-07-13 | 1,4-BIN
63279-58-3
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
- 1-Bromo-4-iodonaphthalene
63279-58-3
- $0.00
- 98%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- 1-Bromo-4-iodonaphthalene
63279-58-3
- 98%
- Shenzhen Nexcon Pharmatechs Ltd.
-
- 1,4-BIN
63279-58-3
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
